Synthesis and Characterization of a New N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)

Synthesis and characterization of a new N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its metal complexes with Co(II), Ni(II) and Cu(II) metal ions. The ligand synthesis and characterization is reported for first time. The compl...

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Main Authors: Dilip C. Sawant, A. Venkatchallam, R. G. Deshmukh
Format: Article
Language:English
Published: Wiley 2010-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2010/525197
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author Dilip C. Sawant
A. Venkatchallam
R. G. Deshmukh
author_facet Dilip C. Sawant
A. Venkatchallam
R. G. Deshmukh
author_sort Dilip C. Sawant
collection DOAJ
description Synthesis and characterization of a new N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its metal complexes with Co(II), Ni(II) and Cu(II) metal ions. The ligand synthesis and characterization is reported for first time. The complexes of divalent metal ions were synthesized in 1:2 molar proportion using ethanol as solvent. The ligands as well as its metal complexes were characterized using various physicochemical techniques such as elemental analysis, spectral and magnetic measurements and electrical conductivity measurements in case of the metal complexes only. The data for the metal complexes reveals that they may be represented by ML2. The metal complexes show interesting features of coordination structure.
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institution Kabale University
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series E-Journal of Chemistry
spelling doaj-art-fdff2c8b9041453897fff1d4380d721b2025-02-03T06:12:09ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-017240941810.1155/2010/525197Synthesis and Characterization of a New N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)Dilip C. Sawant0A. Venkatchallam1R. G. Deshmukh2Department of P.G. Studies & Research in Chemistry, Bhavan’s College, Andheri (W), Mumbai- 58, IndiaDepartment of P.G. Studies & Research in Chemistry, Bhavan’s College, Andheri (W), Mumbai- 58, IndiaDepartment of P.G. Studies & Research in Chemistry, Bhavan’s College, Andheri (W), Mumbai- 58, IndiaSynthesis and characterization of a new N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its metal complexes with Co(II), Ni(II) and Cu(II) metal ions. The ligand synthesis and characterization is reported for first time. The complexes of divalent metal ions were synthesized in 1:2 molar proportion using ethanol as solvent. The ligands as well as its metal complexes were characterized using various physicochemical techniques such as elemental analysis, spectral and magnetic measurements and electrical conductivity measurements in case of the metal complexes only. The data for the metal complexes reveals that they may be represented by ML2. The metal complexes show interesting features of coordination structure.http://dx.doi.org/10.1155/2010/525197
spellingShingle Dilip C. Sawant
A. Venkatchallam
R. G. Deshmukh
Synthesis and Characterization of a New N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)
E-Journal of Chemistry
title Synthesis and Characterization of a New N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)
title_full Synthesis and Characterization of a New N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)
title_fullStr Synthesis and Characterization of a New N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)
title_full_unstemmed Synthesis and Characterization of a New N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)
title_short Synthesis and Characterization of a New N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)
title_sort synthesis and characterization of a new n 1z 2e 2 hydroxyimino 1 phenylpropylidene n 1e phenylmethylene thiocarbonohydrazide and its complexes with co ii ni ii and cu ii
url http://dx.doi.org/10.1155/2010/525197
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AT avenkatchallam synthesisandcharacterizationofanewn1z2e2hydroxyimino1phenylpropylidenen1ephenylmethylenethiocarbonohydrazideanditscomplexeswithcoiiniiiandcuii
AT rgdeshmukh synthesisandcharacterizationofanewn1z2e2hydroxyimino1phenylpropylidenen1ephenylmethylenethiocarbonohydrazideanditscomplexeswithcoiiniiiandcuii