Co3O4 Catalysts on CeO2-ZrO2 Supports and Co3O4-CeO2 Catalysts on Al2O3/SiO2 Supports for the Oxidation of Propylene
Different compositions of Co3O4 catalysts on CeO2-ZrO2 solid solution (Ce0.9Zr0.1O2 and Ce0.8Zr0.2O2) have been studied for the oxidation of propylene. The optional amount of Co3O4 active phase on CeO2-ZrO2 support of 30 wt% was found. The mixed Co3O4-CeO2-ZrO2 with the same composition of the optim...
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Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
Wiley
2015-01-01
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Series: | Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2015/912905 |
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Summary: | Different compositions of Co3O4 catalysts on CeO2-ZrO2 solid solution (Ce0.9Zr0.1O2 and Ce0.8Zr0.2O2) have been studied for the oxidation of propylene. The optional amount of Co3O4 active phase on CeO2-ZrO2 support of 30 wt% was found. The mixed Co3O4-CeO2-ZrO2 with the same composition of the optimal supported ones showed approximately the same activity, which was not higher than the activity of the mixed Co3O4-CeO2 catalyst. Catalytic activities of mixed Co3O4-CeO2 with different loading contents supported on high surface area supports (Al2O3, SiO2) were then measured. The optimal composition of active phase was still 30 wt% but the minimum temperature of the highest activity increased to above 300°C due to the inert nature influence of the support. |
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ISSN: | 2090-9063 2090-9071 |