Effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attack

Abstract Geopolymer cement stands as an alternative to Portland cement to reduce the impacts associated with its production. This material is also affected by ions that can damage its mechanical properties and reduce its durability. Therefore, this research aims to evaluate metakaolin geopolymer co...

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Main Authors: Amanda Venancio Trisotto, Tassiane Apolinário de Oliveira, Maytê Dionísio Marçon, Neusa Aparecida Munhak Beltrame, Ronaldo Alves de Medeiros-Junior
Format: Article
Language:English
Published: Instituto Brasileiro do Concreto (IBRACON) 2025-01-01
Series:Revista IBRACON de Estruturas e Materiais
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Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952025000100207&lng=en&tlng=en
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author Amanda Venancio Trisotto
Tassiane Apolinário de Oliveira
Maytê Dionísio Marçon
Neusa Aparecida Munhak Beltrame
Ronaldo Alves de Medeiros-Junior
author_facet Amanda Venancio Trisotto
Tassiane Apolinário de Oliveira
Maytê Dionísio Marçon
Neusa Aparecida Munhak Beltrame
Ronaldo Alves de Medeiros-Junior
author_sort Amanda Venancio Trisotto
collection DOAJ
description Abstract Geopolymer cement stands as an alternative to Portland cement to reduce the impacts associated with its production. This material is also affected by ions that can damage its mechanical properties and reduce its durability. Therefore, this research aims to evaluate metakaolin geopolymer concretes attacked by sulfates, both sodium and magnesium. The samples were made by varying the sodium oxide (Na2O) content in the activators on the metakaolin, the curing type, and the water/metakaolin ratio. The specimens were exposed to sodium sulfate, magnesium sulfate, and reference solutions (water) for 10 weeks. The analyses were performed using water absorption (by capillarity and immersion) and compressive strength tests. The results showed that sodium sulfate attack was more aggressive than magnesium sulfate in geopolymer concretes, 91.67% of the samples submitted to sodium sulfate degraded during absorptions tests while 8.33% were degraded by magnesium sulfate. A sodium content of 22% in metakaolin achieved greater resistance to magnesium sulfate attack and curing by carbonation did not improve the properties of the mixtures.
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spelling doaj-art-fd37e9ffa5e141babee70464e43dee962025-01-21T07:38:37ZengInstituto Brasileiro do Concreto (IBRACON)Revista IBRACON de Estruturas e Materiais1983-41952025-01-0118110.1590/s1983-41952025000800007Effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attackAmanda Venancio Trisottohttps://orcid.org/0009-0007-2528-9698Tassiane Apolinário de Oliveirahttps://orcid.org/0000-0002-7269-9186Maytê Dionísio Marçonhttps://orcid.org/0009-0006-0279-4184Neusa Aparecida Munhak Beltramehttps://orcid.org/0000-0001-7240-4344Ronaldo Alves de Medeiros-Juniorhttps://orcid.org/0000-0003-4879-4869 Abstract Geopolymer cement stands as an alternative to Portland cement to reduce the impacts associated with its production. This material is also affected by ions that can damage its mechanical properties and reduce its durability. Therefore, this research aims to evaluate metakaolin geopolymer concretes attacked by sulfates, both sodium and magnesium. The samples were made by varying the sodium oxide (Na2O) content in the activators on the metakaolin, the curing type, and the water/metakaolin ratio. The specimens were exposed to sodium sulfate, magnesium sulfate, and reference solutions (water) for 10 weeks. The analyses were performed using water absorption (by capillarity and immersion) and compressive strength tests. The results showed that sodium sulfate attack was more aggressive than magnesium sulfate in geopolymer concretes, 91.67% of the samples submitted to sodium sulfate degraded during absorptions tests while 8.33% were degraded by magnesium sulfate. A sodium content of 22% in metakaolin achieved greater resistance to magnesium sulfate attack and curing by carbonation did not improve the properties of the mixtures.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952025000100207&lng=en&tlng=ensulfate attackgeopolymerpermeabilitycarbonation curing
spellingShingle Amanda Venancio Trisotto
Tassiane Apolinário de Oliveira
Maytê Dionísio Marçon
Neusa Aparecida Munhak Beltrame
Ronaldo Alves de Medeiros-Junior
Effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attack
Revista IBRACON de Estruturas e Materiais
sulfate attack
geopolymer
permeability
carbonation curing
title Effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attack
title_full Effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attack
title_fullStr Effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attack
title_full_unstemmed Effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attack
title_short Effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attack
title_sort effect of carbonation curing and sodium content on geopolymer subjected to sodium and magnesium sulfate attack
topic sulfate attack
geopolymer
permeability
carbonation curing
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952025000100207&lng=en&tlng=en
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