Synthesis, spectroscopy, and photophysical properties of newly magnesium (II) phthalocyanine
2(3),9(10),16(17),23(24)-tetrakis-2,6-dimethoxyphenoxy substituted magnesium (II) phthalocyanine, which has very good solubility in polar and non-polar solvents and does not aggregate, was synthesized. Its structure was characterized by spectroscopic methods such as elemental analysis, UV-vis, FT-IR...
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Kyrgyz Turkish Manas University
2021-04-01
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| Series: | MANAS: Journal of Engineering |
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| Online Access: | https://dergipark.org.tr/en/download/article-file/1594002 |
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| author | Mehmet Pişkin Ömer Faruk Öztürk Zafer Odabaş |
| author_facet | Mehmet Pişkin Ömer Faruk Öztürk Zafer Odabaş |
| author_sort | Mehmet Pişkin |
| collection | DOAJ |
| description | 2(3),9(10),16(17),23(24)-tetrakis-2,6-dimethoxyphenoxy substituted magnesium (II) phthalocyanine, which has very good solubility in polar and non-polar solvents and does not aggregate, was synthesized. Its structure was characterized by spectroscopic methods such as elemental analysis, UV-vis, FT-IR, MALDI-TOF mass and 1H NMR. It has very good solubility in polar aprotic solvents such as dimethyl sulfoxide, N, N- Dimethylformamide, tetrahydrofuran, dichloromethane, and non-polar solvents such as toluene, chloroform. Its aggregation properties have been studied both in the solvents mentioned above and in N, N- Dimethylformamide at different concentrations. Its photophysical properties were determined in N, N-dimethyl formamide. The effects of the nature and presence of 2,6-dimethoxyphenoxy group, which is an antioxidant derivative, on the phthalocyanine skeleton on the spectroscopic and photophysical properties were investigated by comparing it with unsubstituted magnesium (II) phthalocyanine. It can be a good nominee for various technological applications in that it does not aggregate and has good solubility in polar and non-polar solvents, as well as better and favorable fluorescence properties than its analog in the previous study. |
| format | Article |
| id | doaj-art-fc750663fc3f4e63bfa12f1a901e92df |
| institution | Kabale University |
| issn | 1694-7398 |
| language | English |
| publishDate | 2021-04-01 |
| publisher | Kyrgyz Turkish Manas University |
| record_format | Article |
| series | MANAS: Journal of Engineering |
| spelling | doaj-art-fc750663fc3f4e63bfa12f1a901e92df2025-02-03T12:07:27ZengKyrgyz Turkish Manas UniversityMANAS: Journal of Engineering1694-73982021-04-019Special 1586410.51354/mjen.8847561437Synthesis, spectroscopy, and photophysical properties of newly magnesium (II) phthalocyanineMehmet Pişkin0https://orcid.org/0000-0002-4572-4905Ömer Faruk Öztürk1https://orcid.org/0000-0002-4545-7149Zafer Odabaş2https://orcid.org/0000-0002-0647-0404Çanakkale Onsekiz Mart Üniversitesi, Çanakkale Teknik Bilimler Meslek YüksekokuluCanakkale Onsekiz Mart University, Faculty of Arts and Sciences, Department of ChemistryMarmara University, Faculty of Arts and Sciences, Department of Chemistry2(3),9(10),16(17),23(24)-tetrakis-2,6-dimethoxyphenoxy substituted magnesium (II) phthalocyanine, which has very good solubility in polar and non-polar solvents and does not aggregate, was synthesized. Its structure was characterized by spectroscopic methods such as elemental analysis, UV-vis, FT-IR, MALDI-TOF mass and 1H NMR. It has very good solubility in polar aprotic solvents such as dimethyl sulfoxide, N, N- Dimethylformamide, tetrahydrofuran, dichloromethane, and non-polar solvents such as toluene, chloroform. Its aggregation properties have been studied both in the solvents mentioned above and in N, N- Dimethylformamide at different concentrations. Its photophysical properties were determined in N, N-dimethyl formamide. The effects of the nature and presence of 2,6-dimethoxyphenoxy group, which is an antioxidant derivative, on the phthalocyanine skeleton on the spectroscopic and photophysical properties were investigated by comparing it with unsubstituted magnesium (II) phthalocyanine. It can be a good nominee for various technological applications in that it does not aggregate and has good solubility in polar and non-polar solvents, as well as better and favorable fluorescence properties than its analog in the previous study.https://dergipark.org.tr/en/download/article-file/1594002phthalocyaninemagnesium (ii)2,3-dimethoxyphenolspectroscopicphotophysical |
| spellingShingle | Mehmet Pişkin Ömer Faruk Öztürk Zafer Odabaş Synthesis, spectroscopy, and photophysical properties of newly magnesium (II) phthalocyanine MANAS: Journal of Engineering phthalocyanine magnesium (ii) 2,3-dimethoxyphenol spectroscopic photophysical |
| title | Synthesis, spectroscopy, and photophysical properties of newly magnesium (II) phthalocyanine |
| title_full | Synthesis, spectroscopy, and photophysical properties of newly magnesium (II) phthalocyanine |
| title_fullStr | Synthesis, spectroscopy, and photophysical properties of newly magnesium (II) phthalocyanine |
| title_full_unstemmed | Synthesis, spectroscopy, and photophysical properties of newly magnesium (II) phthalocyanine |
| title_short | Synthesis, spectroscopy, and photophysical properties of newly magnesium (II) phthalocyanine |
| title_sort | synthesis spectroscopy and photophysical properties of newly magnesium ii phthalocyanine |
| topic | phthalocyanine magnesium (ii) 2,3-dimethoxyphenol spectroscopic photophysical |
| url | https://dergipark.org.tr/en/download/article-file/1594002 |
| work_keys_str_mv | AT mehmetpiskin synthesisspectroscopyandphotophysicalpropertiesofnewlymagnesiumiiphthalocyanine AT omerfarukozturk synthesisspectroscopyandphotophysicalpropertiesofnewlymagnesiumiiphthalocyanine AT zaferodabas synthesisspectroscopyandphotophysicalpropertiesofnewlymagnesiumiiphthalocyanine |