Phase Transition, Magnetocaloric Effect, and Critical Behavior of Room Temperature Magnetic Refrigerant Material Mn5Ge2.7Zn0.3

Mn5Ge2.7Zn0.3 alloy was successfully prepared by using the arc-melting method, and its phase transition, magnetocaloric effect, and critical behavior were studied. The thermomagnetic curve determined that the Curie temperature of the sample was 297.2 K, the isothermal magnetization curve found that...

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Main Author: XU Tongjie, LIU Zhenhua, JIN Huaiyu, LIU Jie, JIANG Xiuli, LI Zhe, LIU Yongsheng
Format: Article
Language:zho
Published: Editorial Office of Journal of Shanghai Jiao Tong University 2025-01-01
Series:Shanghai Jiaotong Daxue xuebao
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Online Access:https://xuebao.sjtu.edu.cn/article/2025/1006-2467/1006-2467-59-1-131.shtml
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author XU Tongjie, LIU Zhenhua, JIN Huaiyu, LIU Jie, JIANG Xiuli, LI Zhe, LIU Yongsheng
author_facet XU Tongjie, LIU Zhenhua, JIN Huaiyu, LIU Jie, JIANG Xiuli, LI Zhe, LIU Yongsheng
author_sort XU Tongjie, LIU Zhenhua, JIN Huaiyu, LIU Jie, JIANG Xiuli, LI Zhe, LIU Yongsheng
collection DOAJ
description Mn5Ge2.7Zn0.3 alloy was successfully prepared by using the arc-melting method, and its phase transition, magnetocaloric effect, and critical behavior were studied. The thermomagnetic curve determined that the Curie temperature of the sample was 297.2 K, the isothermal magnetization curve found that the sample had no thermal hysteresis. The sample underwent a second-order phase transition through the M2-H/M plot and Banerjee’s criterion, and the isothermal entropy change of the sample was further calculated according to Maxwell’s equation, and the power-law relationship of field-entropy and the normalization curve also verified the fact of the second-order phase transition. The critical index was solved by the modified Arrott plot(MAP) method, the Kouvel-Fisher(KF) method and the critical isothermal (CI) method, and the accuracy of the critical index was verified by Widom scaling ansatz and scaling laws. Finally, the Arrott-Noaks equation was used to further analyze the critical behavior of the sample, and the normalization slope and magnetic interaction distance were analyzed to confirm the complexity of the magnetic interaction inside the sample.
format Article
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issn 1006-2467
language zho
publishDate 2025-01-01
publisher Editorial Office of Journal of Shanghai Jiao Tong University
record_format Article
series Shanghai Jiaotong Daxue xuebao
spelling doaj-art-fa8d65ff1f3740f4b1c44318b687a0ec2025-02-06T09:45:28ZzhoEditorial Office of Journal of Shanghai Jiao Tong UniversityShanghai Jiaotong Daxue xuebao1006-24672025-01-0159113113810.16183/j.cnki.jsjtu.2023.112Phase Transition, Magnetocaloric Effect, and Critical Behavior of Room Temperature Magnetic Refrigerant Material Mn5Ge2.7Zn0.3XU Tongjie, LIU Zhenhua, JIN Huaiyu, LIU Jie, JIANG Xiuli, LI Zhe, LIU Yongsheng01. College of Mathematics and Physics, Shanghai University of Electric Power, Shanghai 200090, China;2. Center for Magnetic Materials and Devices, Qujing Normal University, Qujing 655011, Yunnan, ChinaMn5Ge2.7Zn0.3 alloy was successfully prepared by using the arc-melting method, and its phase transition, magnetocaloric effect, and critical behavior were studied. The thermomagnetic curve determined that the Curie temperature of the sample was 297.2 K, the isothermal magnetization curve found that the sample had no thermal hysteresis. The sample underwent a second-order phase transition through the M2-H/M plot and Banerjee’s criterion, and the isothermal entropy change of the sample was further calculated according to Maxwell’s equation, and the power-law relationship of field-entropy and the normalization curve also verified the fact of the second-order phase transition. The critical index was solved by the modified Arrott plot(MAP) method, the Kouvel-Fisher(KF) method and the critical isothermal (CI) method, and the accuracy of the critical index was verified by Widom scaling ansatz and scaling laws. Finally, the Arrott-Noaks equation was used to further analyze the critical behavior of the sample, and the normalization slope and magnetic interaction distance were analyzed to confirm the complexity of the magnetic interaction inside the sample.https://xuebao.sjtu.edu.cn/article/2025/1006-2467/1006-2467-59-1-131.shtmlmn<sub>5</sub>ge<sub>3</sub> based alloyssecond-order phase transitionmagnetocaloric effectcritical behaviorinteraction
spellingShingle XU Tongjie, LIU Zhenhua, JIN Huaiyu, LIU Jie, JIANG Xiuli, LI Zhe, LIU Yongsheng
Phase Transition, Magnetocaloric Effect, and Critical Behavior of Room Temperature Magnetic Refrigerant Material Mn5Ge2.7Zn0.3
Shanghai Jiaotong Daxue xuebao
mn<sub>5</sub>ge<sub>3</sub> based alloys
second-order phase transition
magnetocaloric effect
critical behavior
interaction
title Phase Transition, Magnetocaloric Effect, and Critical Behavior of Room Temperature Magnetic Refrigerant Material Mn5Ge2.7Zn0.3
title_full Phase Transition, Magnetocaloric Effect, and Critical Behavior of Room Temperature Magnetic Refrigerant Material Mn5Ge2.7Zn0.3
title_fullStr Phase Transition, Magnetocaloric Effect, and Critical Behavior of Room Temperature Magnetic Refrigerant Material Mn5Ge2.7Zn0.3
title_full_unstemmed Phase Transition, Magnetocaloric Effect, and Critical Behavior of Room Temperature Magnetic Refrigerant Material Mn5Ge2.7Zn0.3
title_short Phase Transition, Magnetocaloric Effect, and Critical Behavior of Room Temperature Magnetic Refrigerant Material Mn5Ge2.7Zn0.3
title_sort phase transition magnetocaloric effect and critical behavior of room temperature magnetic refrigerant material mn5ge2 7zn0 3
topic mn<sub>5</sub>ge<sub>3</sub> based alloys
second-order phase transition
magnetocaloric effect
critical behavior
interaction
url https://xuebao.sjtu.edu.cn/article/2025/1006-2467/1006-2467-59-1-131.shtml
work_keys_str_mv AT xutongjieliuzhenhuajinhuaiyuliujiejiangxiulilizheliuyongsheng phasetransitionmagnetocaloriceffectandcriticalbehaviorofroomtemperaturemagneticrefrigerantmaterialmn5ge27zn03