Dual-stage corrosion mechanisms and antibacterial enhancement of Cu-Sn-P alloys with Si and Al microalloying in simulated body fluid
The effects of P, Si and Al elements on the microstructure, corrosion properties and antibacterial properties of copper-tin alloys were studied. The addition of Si and Al elements reduced the layer fault energy of Cu-Sn-P alloy, refined grain and increased twins. Cu-Sn-P-Si and Cu-Sn-P-Al alloys wer...
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Elsevier
2025-03-01
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Online Access: | http://www.sciencedirect.com/science/article/pii/S0264127525000553 |
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author | Lin Su Wenbin Liu Yangfan Liu Yanbin Jiang Yanggang Wang Zhou Li Kaiyu You ChuYu Wang Gengyan Liu |
author_facet | Lin Su Wenbin Liu Yangfan Liu Yanbin Jiang Yanggang Wang Zhou Li Kaiyu You ChuYu Wang Gengyan Liu |
author_sort | Lin Su |
collection | DOAJ |
description | The effects of P, Si and Al elements on the microstructure, corrosion properties and antibacterial properties of copper-tin alloys were studied. The addition of Si and Al elements reduced the layer fault energy of Cu-Sn-P alloy, refined grain and increased twins. Cu-Sn-P-Si and Cu-Sn-P-Al alloys were prone to grain boundary stripping corrosion and twin corrosion, which promoted the release of copper ions and improved the antibacterial properties. Cu-Sn-P-Al alloy had the best antibacterial activity. These results provide theoretical guidance for the development of new antibacterial copper alloy materials by microalloying the corrosion and ion release behavior of copper alloys. |
format | Article |
id | doaj-art-fa42ed250c0b4462aece81a7f50d9026 |
institution | Kabale University |
issn | 0264-1275 |
language | English |
publishDate | 2025-03-01 |
publisher | Elsevier |
record_format | Article |
series | Materials & Design |
spelling | doaj-art-fa42ed250c0b4462aece81a7f50d90262025-01-31T05:10:03ZengElsevierMaterials & Design0264-12752025-03-01251113635Dual-stage corrosion mechanisms and antibacterial enhancement of Cu-Sn-P alloys with Si and Al microalloying in simulated body fluidLin Su0Wenbin Liu1Yangfan Liu2Yanbin Jiang3Yanggang Wang4Zhou Li5Kaiyu You6ChuYu Wang7Gengyan Liu8School of Materials Science and Engineering, Central South University, Changsha 410083, ChinaDepartment of Orthopaedics, The Third Xiangya Hospital, Central South University, 138 Tongzipo Road, Changsha 410008, China; Hunan Engineering Research Center of Biomedical Metal and Ceramic Implants, Changsha, ChinaSchool of Materials Science and Engineering, Central South University, Changsha 410083, ChinaSchool of Materials Science and Engineering, Central South University, Changsha 410083, China; State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, China; Corresponding authors at: School of Materials Science and Engineering, Central South University, Changsha 410083, China (Y. Jiang).School of Materials Science and Engineering, Central South University, Changsha 410083, ChinaSchool of Materials Science and Engineering, Central South University, Changsha 410083, China; State Key Lab for Powder Metallurgy, Central South University, Changsha 410083, ChinaSchool of Materials Science and Engineering, Central South University, Changsha 410083, ChinaSchool of Materials Science and Engineering, Central South University, Changsha 410083, ChinaDepartment of Orthopaedics, The Third Xiangya Hospital, Central South University, 138 Tongzipo Road, Changsha 410008, China; Corresponding authors at: School of Materials Science and Engineering, Central South University, Changsha 410083, China (Y. Jiang).The effects of P, Si and Al elements on the microstructure, corrosion properties and antibacterial properties of copper-tin alloys were studied. The addition of Si and Al elements reduced the layer fault energy of Cu-Sn-P alloy, refined grain and increased twins. Cu-Sn-P-Si and Cu-Sn-P-Al alloys were prone to grain boundary stripping corrosion and twin corrosion, which promoted the release of copper ions and improved the antibacterial properties. Cu-Sn-P-Al alloy had the best antibacterial activity. These results provide theoretical guidance for the development of new antibacterial copper alloy materials by microalloying the corrosion and ion release behavior of copper alloys.http://www.sciencedirect.com/science/article/pii/S0264127525000553Cu-Sn alloyGrain refinementCorrosion behaviorAntibacterial performance |
spellingShingle | Lin Su Wenbin Liu Yangfan Liu Yanbin Jiang Yanggang Wang Zhou Li Kaiyu You ChuYu Wang Gengyan Liu Dual-stage corrosion mechanisms and antibacterial enhancement of Cu-Sn-P alloys with Si and Al microalloying in simulated body fluid Materials & Design Cu-Sn alloy Grain refinement Corrosion behavior Antibacterial performance |
title | Dual-stage corrosion mechanisms and antibacterial enhancement of Cu-Sn-P alloys with Si and Al microalloying in simulated body fluid |
title_full | Dual-stage corrosion mechanisms and antibacterial enhancement of Cu-Sn-P alloys with Si and Al microalloying in simulated body fluid |
title_fullStr | Dual-stage corrosion mechanisms and antibacterial enhancement of Cu-Sn-P alloys with Si and Al microalloying in simulated body fluid |
title_full_unstemmed | Dual-stage corrosion mechanisms and antibacterial enhancement of Cu-Sn-P alloys with Si and Al microalloying in simulated body fluid |
title_short | Dual-stage corrosion mechanisms and antibacterial enhancement of Cu-Sn-P alloys with Si and Al microalloying in simulated body fluid |
title_sort | dual stage corrosion mechanisms and antibacterial enhancement of cu sn p alloys with si and al microalloying in simulated body fluid |
topic | Cu-Sn alloy Grain refinement Corrosion behavior Antibacterial performance |
url | http://www.sciencedirect.com/science/article/pii/S0264127525000553 |
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