A catalyst-coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysers

Abstract Alkaline water electrolysers are ideal for gigawatt-scale hydrogen production due to the usage of non-precious metal and low-cost raw materials. However, their performances are modest with the separated electrode and diaphragm structure which can date back to more than 100 years ago. Here w...

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Main Authors: Zhuang Xu, Yanying Liu, Xiaobo Cheng, Yunshan Shang, Yongtao Wang, Jing Wang, Wenshi Li, Guangli He
Format: Article
Language:English
Published: Nature Portfolio 2025-01-01
Series:Communications Engineering
Online Access:https://doi.org/10.1038/s44172-025-00344-2
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author Zhuang Xu
Yanying Liu
Xiaobo Cheng
Yunshan Shang
Yongtao Wang
Jing Wang
Wenshi Li
Guangli He
author_facet Zhuang Xu
Yanying Liu
Xiaobo Cheng
Yunshan Shang
Yongtao Wang
Jing Wang
Wenshi Li
Guangli He
author_sort Zhuang Xu
collection DOAJ
description Abstract Alkaline water electrolysers are ideal for gigawatt-scale hydrogen production due to the usage of non-precious metal and low-cost raw materials. However, their performances are modest with the separated electrode and diaphragm structure which can date back to more than 100 years ago. Here we report a catalyst-coated diaphragm assembly to improve the performance of alkaline water electrolysers. The transport resistance of OH- ions is reduced and the electrochemical surface area of catalysts is enlarged by more than forty fold, representing more than 40% increase in hydrogen production rate or as much as 16% reduction in energy consumption. The electrolyser with our catalyst-coated diaphragm assembly delivers current densities as high as 1 A cm−2 at 1.8 V or 2 A cm−2 at 2 V and shows good stability after more than 1000 hours of operation. Therefore, the catalyst-coated diaphragm assembly route is promising for the development of high-performance and efficient alkaline water electrolysers.
format Article
id doaj-art-fa3d66a6fa204118bfff463d4c492468
institution Kabale University
issn 2731-3395
language English
publishDate 2025-01-01
publisher Nature Portfolio
record_format Article
series Communications Engineering
spelling doaj-art-fa3d66a6fa204118bfff463d4c4924682025-01-26T12:36:01ZengNature PortfolioCommunications Engineering2731-33952025-01-01411910.1038/s44172-025-00344-2A catalyst-coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysersZhuang Xu0Yanying Liu1Xiaobo Cheng2Yunshan Shang3Yongtao Wang4Jing Wang5Wenshi Li6Guangli He7Hydrogen and Ammonium Energy R&D Center, National Institute of Clean-and-Low-Carbon EnergyHydrogen and Ammonium Energy R&D Center, National Institute of Clean-and-Low-Carbon EnergyHydrogen and Ammonium Energy R&D Center, National Institute of Clean-and-Low-Carbon EnergyHydrogen and Ammonium Energy R&D Center, National Institute of Clean-and-Low-Carbon EnergyHydrogen and Ammonium Energy R&D Center, National Institute of Clean-and-Low-Carbon EnergyHydrogen and Ammonium Energy R&D Center, National Institute of Clean-and-Low-Carbon EnergyHydrogen and Ammonium Energy R&D Center, National Institute of Clean-and-Low-Carbon EnergyHydrogen and Ammonium Energy R&D Center, National Institute of Clean-and-Low-Carbon EnergyAbstract Alkaline water electrolysers are ideal for gigawatt-scale hydrogen production due to the usage of non-precious metal and low-cost raw materials. However, their performances are modest with the separated electrode and diaphragm structure which can date back to more than 100 years ago. Here we report a catalyst-coated diaphragm assembly to improve the performance of alkaline water electrolysers. The transport resistance of OH- ions is reduced and the electrochemical surface area of catalysts is enlarged by more than forty fold, representing more than 40% increase in hydrogen production rate or as much as 16% reduction in energy consumption. The electrolyser with our catalyst-coated diaphragm assembly delivers current densities as high as 1 A cm−2 at 1.8 V or 2 A cm−2 at 2 V and shows good stability after more than 1000 hours of operation. Therefore, the catalyst-coated diaphragm assembly route is promising for the development of high-performance and efficient alkaline water electrolysers.https://doi.org/10.1038/s44172-025-00344-2
spellingShingle Zhuang Xu
Yanying Liu
Xiaobo Cheng
Yunshan Shang
Yongtao Wang
Jing Wang
Wenshi Li
Guangli He
A catalyst-coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysers
Communications Engineering
title A catalyst-coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysers
title_full A catalyst-coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysers
title_fullStr A catalyst-coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysers
title_full_unstemmed A catalyst-coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysers
title_short A catalyst-coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysers
title_sort catalyst coated diaphragm assembly to improve the performance and energy efficiency of alkaline water electrolysers
url https://doi.org/10.1038/s44172-025-00344-2
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