Magnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach
Abstract In this project, a new heterogeneous polymeric ionic liquid catalyst based on vinylimidazole, stabilized on magnetic nanoparticles )Fe3O4@Al2O3@[PBVIm]HSO4) was prepared. Then the desired catalyst was identified by TGA, FT-IR, VSM, and TEM techniques. The efficiency of this catalyst was mea...
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Nature Portfolio
2025-01-01
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| Series: | Scientific Reports |
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| Online Access: | https://doi.org/10.1038/s41598-025-86751-z |
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| author | Behrooz Maleki Reza Sandaroos Fahimeh Yousefi Milad Ghani Sahar Peiman |
| author_facet | Behrooz Maleki Reza Sandaroos Fahimeh Yousefi Milad Ghani Sahar Peiman |
| author_sort | Behrooz Maleki |
| collection | DOAJ |
| description | Abstract In this project, a new heterogeneous polymeric ionic liquid catalyst based on vinylimidazole, stabilized on magnetic nanoparticles )Fe3O4@Al2O3@[PBVIm]HSO4) was prepared. Then the desired catalyst was identified by TGA, FT-IR, VSM, and TEM techniques. The efficiency of this catalyst was measured in the synthesis of chromene, xanthene, and dihydropyrimidinone. Moreover, the capability of the prepared sorbent for the extraction and determination of BPA (bisphenol A) was studied. Under the optimum conditions, the linearity range of the technique was between 0.5 and 100 µg L−1 with the coefficient of determination (r2) of 0.9948. Relative standard deviations for intra- and inter-day precision for the BPA (bisphenol A) at 20 µg L−1 were in the range of 3.1–3.9% and 3.7–4.2%, respectively. The limit of detection and limit of quantification were 0.07 and 0.48 µg L−1 respectively. Excellent efficiency, compatibility with environmental conditions, and easy recycling of the catalyst are among the most important features of the synthetic catalyst. |
| format | Article |
| id | doaj-art-f9d705a2b2c94b83b1af2a1411eb0273 |
| institution | Kabale University |
| issn | 2045-2322 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj-art-f9d705a2b2c94b83b1af2a1411eb02732025-01-26T12:26:19ZengNature PortfolioScientific Reports2045-23222025-01-0115111710.1038/s41598-025-86751-zMagnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approachBehrooz Maleki0Reza Sandaroos1Fahimeh Yousefi2Milad Ghani3Sahar Peiman4Department of Organic Chemistry, Faculty of Chemistry, University of MazandaranDepartment of Chemistry, Faculty of Sciences, University of BirjandDepartment of Chemistry, Faculty of Sciences, University of BirjandDepartment of Analytical Chemistry, Faculty of Chemistry, University of MazandaranDepartment of Organic Chemistry, Faculty of Chemistry, University of MazandaranAbstract In this project, a new heterogeneous polymeric ionic liquid catalyst based on vinylimidazole, stabilized on magnetic nanoparticles )Fe3O4@Al2O3@[PBVIm]HSO4) was prepared. Then the desired catalyst was identified by TGA, FT-IR, VSM, and TEM techniques. The efficiency of this catalyst was measured in the synthesis of chromene, xanthene, and dihydropyrimidinone. Moreover, the capability of the prepared sorbent for the extraction and determination of BPA (bisphenol A) was studied. Under the optimum conditions, the linearity range of the technique was between 0.5 and 100 µg L−1 with the coefficient of determination (r2) of 0.9948. Relative standard deviations for intra- and inter-day precision for the BPA (bisphenol A) at 20 µg L−1 were in the range of 3.1–3.9% and 3.7–4.2%, respectively. The limit of detection and limit of quantification were 0.07 and 0.48 µg L−1 respectively. Excellent efficiency, compatibility with environmental conditions, and easy recycling of the catalyst are among the most important features of the synthetic catalyst.https://doi.org/10.1038/s41598-025-86751-zMagnetic nanoparticlesIonic liquidsHeterocyclic compoundsMagnetic solid phase extractionBisphenol A |
| spellingShingle | Behrooz Maleki Reza Sandaroos Fahimeh Yousefi Milad Ghani Sahar Peiman Magnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach Scientific Reports Magnetic nanoparticles Ionic liquids Heterocyclic compounds Magnetic solid phase extraction Bisphenol A |
| title | Magnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach |
| title_full | Magnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach |
| title_fullStr | Magnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach |
| title_full_unstemmed | Magnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach |
| title_short | Magnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach |
| title_sort | magnetic polymeric ionic liquid for both catalysis application and magnetic solid phase extraction approach |
| topic | Magnetic nanoparticles Ionic liquids Heterocyclic compounds Magnetic solid phase extraction Bisphenol A |
| url | https://doi.org/10.1038/s41598-025-86751-z |
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