Effect of Thickness on Structural and Optical Properties of Tetra-tert- butyl-2, 3-naphthalocyanine Thin Films
Amorphous tetra-tert-butyl-2, 3-naphthalocyanine thin films have been deposited using physical vapor deposition technique under a varied thickness by adjusting the coating time. By analyzing the x-ray diffraction, the structure of as deposited films is found to be non-crystalline. Different optical...
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2011-01-01
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Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2011/752982 |
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author | I. Dhanya C S Menon |
author_facet | I. Dhanya C S Menon |
author_sort | I. Dhanya |
collection | DOAJ |
description | Amorphous tetra-tert-butyl-2, 3-naphthalocyanine thin films have been deposited using physical vapor deposition technique under a varied thickness by adjusting the coating time. By analyzing the x-ray diffraction, the structure of as deposited films is found to be non-crystalline. Different optical properties of these thin films have been investigated by means of optical absorption and reflection spectra. Various optical constants like band gap energy, Eg the width of band tails of localized states into the gap, EU and steepness parameter, β gets calculated and the variation of different optical parameters like refractive index, extinction coefficient, dielectric constants, optical conductivity and surface and volume energy losses with photon energy are estimated. |
format | Article |
id | doaj-art-f8e6f9419eda4f19801fa7ad8352dcdc |
institution | Kabale University |
issn | 0973-4945 2090-9810 |
language | English |
publishDate | 2011-01-01 |
publisher | Wiley |
record_format | Article |
series | E-Journal of Chemistry |
spelling | doaj-art-f8e6f9419eda4f19801fa7ad8352dcdc2025-02-03T01:07:50ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01841686169510.1155/2011/752982Effect of Thickness on Structural and Optical Properties of Tetra-tert- butyl-2, 3-naphthalocyanine Thin FilmsI. Dhanya0C S Menon1School of Pure and Applied Physics, Mahatma Gandhi UniversityPriyadarshini Hills, Kottayam, Kerala, 686 560, IndiaSchool of Pure and Applied Physics, Mahatma Gandhi UniversityPriyadarshini Hills, Kottayam, Kerala, 686 560, IndiaAmorphous tetra-tert-butyl-2, 3-naphthalocyanine thin films have been deposited using physical vapor deposition technique under a varied thickness by adjusting the coating time. By analyzing the x-ray diffraction, the structure of as deposited films is found to be non-crystalline. Different optical properties of these thin films have been investigated by means of optical absorption and reflection spectra. Various optical constants like band gap energy, Eg the width of band tails of localized states into the gap, EU and steepness parameter, β gets calculated and the variation of different optical parameters like refractive index, extinction coefficient, dielectric constants, optical conductivity and surface and volume energy losses with photon energy are estimated.http://dx.doi.org/10.1155/2011/752982 |
spellingShingle | I. Dhanya C S Menon Effect of Thickness on Structural and Optical Properties of Tetra-tert- butyl-2, 3-naphthalocyanine Thin Films E-Journal of Chemistry |
title | Effect of Thickness on Structural and Optical Properties of Tetra-tert- butyl-2, 3-naphthalocyanine Thin Films |
title_full | Effect of Thickness on Structural and Optical Properties of Tetra-tert- butyl-2, 3-naphthalocyanine Thin Films |
title_fullStr | Effect of Thickness on Structural and Optical Properties of Tetra-tert- butyl-2, 3-naphthalocyanine Thin Films |
title_full_unstemmed | Effect of Thickness on Structural and Optical Properties of Tetra-tert- butyl-2, 3-naphthalocyanine Thin Films |
title_short | Effect of Thickness on Structural and Optical Properties of Tetra-tert- butyl-2, 3-naphthalocyanine Thin Films |
title_sort | effect of thickness on structural and optical properties of tetra tert butyl 2 3 naphthalocyanine thin films |
url | http://dx.doi.org/10.1155/2011/752982 |
work_keys_str_mv | AT idhanya effectofthicknessonstructuralandopticalpropertiesoftetratertbutyl23naphthalocyaninethinfilms AT csmenon effectofthicknessonstructuralandopticalpropertiesoftetratertbutyl23naphthalocyaninethinfilms |