Surface Organic Modification of TiO2 Powder and Relevant Characterization

Surface organic modification was conducted to TiO2 with modifiers to improve the dispersity and comparability of pigment TiO2 in application system by adjusting particle surface characteristics. Then, modification effects were characterized according to the changes in wetting contact angle and activ...

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Main Authors: Hong Zhou, Sijia Sun, Hao Ding
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2017/9562612
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author Hong Zhou
Sijia Sun
Hao Ding
author_facet Hong Zhou
Sijia Sun
Hao Ding
author_sort Hong Zhou
collection DOAJ
description Surface organic modification was conducted to TiO2 with modifiers to improve the dispersity and comparability of pigment TiO2 in application system by adjusting particle surface characteristics. Then, modification effects were characterized according to the changes in wetting contact angle and activation index of TiO2 before and after modification. Moreover, the modification mechanisms of sodium stearate and sodium oleate were studied by analyzing the characteristics of TiO2 surface functional groups in modification system and effects of modifiers. The results showed that, after being wet-processed with sodium stearate and sodium oleate, TiO2 could turn from surface hydrophilic to inductive hydrophobic with controllable degree. The wetting contact angle of modified TiO2 increased from 7° to 125.6° and 121.3°, respectively. The dispersity of TiO2 in organic medium was stronger than that in inorganic medium. The modifiers formed absorption with chemical property on TiO2 particle surface, so the inductive hydrophobicity of surface was stable.
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spelling doaj-art-f82be9d366114467b4a2bdb33fd06c092025-02-03T05:59:32ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422017-01-01201710.1155/2017/95626129562612Surface Organic Modification of TiO2 Powder and Relevant CharacterizationHong Zhou0Sijia Sun1Hao Ding2Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, ChinaBeijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, ChinaBeijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, ChinaSurface organic modification was conducted to TiO2 with modifiers to improve the dispersity and comparability of pigment TiO2 in application system by adjusting particle surface characteristics. Then, modification effects were characterized according to the changes in wetting contact angle and activation index of TiO2 before and after modification. Moreover, the modification mechanisms of sodium stearate and sodium oleate were studied by analyzing the characteristics of TiO2 surface functional groups in modification system and effects of modifiers. The results showed that, after being wet-processed with sodium stearate and sodium oleate, TiO2 could turn from surface hydrophilic to inductive hydrophobic with controllable degree. The wetting contact angle of modified TiO2 increased from 7° to 125.6° and 121.3°, respectively. The dispersity of TiO2 in organic medium was stronger than that in inorganic medium. The modifiers formed absorption with chemical property on TiO2 particle surface, so the inductive hydrophobicity of surface was stable.http://dx.doi.org/10.1155/2017/9562612
spellingShingle Hong Zhou
Sijia Sun
Hao Ding
Surface Organic Modification of TiO2 Powder and Relevant Characterization
Advances in Materials Science and Engineering
title Surface Organic Modification of TiO2 Powder and Relevant Characterization
title_full Surface Organic Modification of TiO2 Powder and Relevant Characterization
title_fullStr Surface Organic Modification of TiO2 Powder and Relevant Characterization
title_full_unstemmed Surface Organic Modification of TiO2 Powder and Relevant Characterization
title_short Surface Organic Modification of TiO2 Powder and Relevant Characterization
title_sort surface organic modification of tio2 powder and relevant characterization
url http://dx.doi.org/10.1155/2017/9562612
work_keys_str_mv AT hongzhou surfaceorganicmodificationoftio2powderandrelevantcharacterization
AT sijiasun surfaceorganicmodificationoftio2powderandrelevantcharacterization
AT haoding surfaceorganicmodificationoftio2powderandrelevantcharacterization