Applying different techniques for evaluating the resistance to moisture of electrospun PVA nanofibers

Poly (Vinyl Alcohol) (PVA) is used to produce nanofibers with electrospinning for several applications related to the non-toxicity of the material, however, the application in air filtration in hindered by the high hydrophilicity of the material, which requires the crosslinking with additives. In t...

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Main Authors: Alessandro Estarque de Oliveira, Mônica Lopes Aguiar, Vádila Giovana Guerra
Format: Article
Language:English
Published: Universidade Federal de Viçosa (UFV) 2021-08-01
Series:The Journal of Engineering and Exact Sciences
Subjects:
Online Access:https://periodicos.ufv.br/jcec/article/view/12938
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author Alessandro Estarque de Oliveira
Mônica Lopes Aguiar
Vádila Giovana Guerra
author_facet Alessandro Estarque de Oliveira
Mônica Lopes Aguiar
Vádila Giovana Guerra
author_sort Alessandro Estarque de Oliveira
collection DOAJ
description Poly (Vinyl Alcohol) (PVA) is used to produce nanofibers with electrospinning for several applications related to the non-toxicity of the material, however, the application in air filtration in hindered by the high hydrophilicity of the material, which requires the crosslinking with additives. In this work, different techniques were assessed to verify the moisture resistance of PVA nanofibers crosslinked with citric acid. The mass loss did not reveal significant structural modification of the filter media due to the relatively low mass of the nanofibers in comparison to the mass of the substrate, proving the poor applicability of this technique for this process. The measurement of the water contact angle was not suitable for the experimental circumstances as well. A methodology was then purposed, measuring the pressure drop before and after the flow of clean air stream (~15.0 cm s-1) through the filter media with different contents of water (49, 68, and 90% R.H.) to verify the humidity resistance of the fibers over time (zero to 60 min). The samples were resistant to humidity and no significant structural changes occurred in the fibers after the process in accordance with analysis of scanning electron microscopy images. For the two lowest humidities, variation of the pressure drop was equal to approximately zero after 60 min while it achieved 4.1% for 90% R.H. This methodology proved to be suitable for air filtration application.
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institution Kabale University
issn 2527-1075
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publishDate 2021-08-01
publisher Universidade Federal de Viçosa (UFV)
record_format Article
series The Journal of Engineering and Exact Sciences
spelling doaj-art-f6a64ace8ac942e4911fcefa2e67b7dc2025-02-02T19:56:57ZengUniversidade Federal de Viçosa (UFV)The Journal of Engineering and Exact Sciences2527-10752021-08-017310.18540/jcecvl7iss3pp12938-01-10eApplying different techniques for evaluating the resistance to moisture of electrospun PVA nanofibersAlessandro Estarque de Oliveira0Mônica Lopes Aguiar1Vádila Giovana Guerra2Universidade Federal de São CarlosUniversidade Federal de São CarlosUniversidade Federal de São Carlos Poly (Vinyl Alcohol) (PVA) is used to produce nanofibers with electrospinning for several applications related to the non-toxicity of the material, however, the application in air filtration in hindered by the high hydrophilicity of the material, which requires the crosslinking with additives. In this work, different techniques were assessed to verify the moisture resistance of PVA nanofibers crosslinked with citric acid. The mass loss did not reveal significant structural modification of the filter media due to the relatively low mass of the nanofibers in comparison to the mass of the substrate, proving the poor applicability of this technique for this process. The measurement of the water contact angle was not suitable for the experimental circumstances as well. A methodology was then purposed, measuring the pressure drop before and after the flow of clean air stream (~15.0 cm s-1) through the filter media with different contents of water (49, 68, and 90% R.H.) to verify the humidity resistance of the fibers over time (zero to 60 min). The samples were resistant to humidity and no significant structural changes occurred in the fibers after the process in accordance with analysis of scanning electron microscopy images. For the two lowest humidities, variation of the pressure drop was equal to approximately zero after 60 min while it achieved 4.1% for 90% R.H. This methodology proved to be suitable for air filtration application. https://periodicos.ufv.br/jcec/article/view/12938NanofibersElectrospinningHydrophilicity
spellingShingle Alessandro Estarque de Oliveira
Mônica Lopes Aguiar
Vádila Giovana Guerra
Applying different techniques for evaluating the resistance to moisture of electrospun PVA nanofibers
The Journal of Engineering and Exact Sciences
Nanofibers
Electrospinning
Hydrophilicity
title Applying different techniques for evaluating the resistance to moisture of electrospun PVA nanofibers
title_full Applying different techniques for evaluating the resistance to moisture of electrospun PVA nanofibers
title_fullStr Applying different techniques for evaluating the resistance to moisture of electrospun PVA nanofibers
title_full_unstemmed Applying different techniques for evaluating the resistance to moisture of electrospun PVA nanofibers
title_short Applying different techniques for evaluating the resistance to moisture of electrospun PVA nanofibers
title_sort applying different techniques for evaluating the resistance to moisture of electrospun pva nanofibers
topic Nanofibers
Electrospinning
Hydrophilicity
url https://periodicos.ufv.br/jcec/article/view/12938
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AT vadilagiovanaguerra applyingdifferenttechniquesforevaluatingtheresistancetomoistureofelectrospunpvananofibers