Kinetic Modeling Study of the Industrial Sulfur Recovery Process for Operating Condition Optimization

Sulfur recovery from acid gas (H2S and CO2), which is contained in fresh natural gas, can bring many economic and environmental benefits, and this topic has been studied for years. Finding an optimal operating condition for the factory is of much importance. In this paper, we built a reactor network...

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Main Authors: Shan Huang, Zhaohui Teng, Lisheng Zhang, Qulan Zhou, Na Li
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2020/4156216
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author Shan Huang
Zhaohui Teng
Lisheng Zhang
Qulan Zhou
Na Li
author_facet Shan Huang
Zhaohui Teng
Lisheng Zhang
Qulan Zhou
Na Li
author_sort Shan Huang
collection DOAJ
description Sulfur recovery from acid gas (H2S and CO2), which is contained in fresh natural gas, can bring many economic and environmental benefits, and this topic has been studied for years. Finding an optimal operating condition for the factory is of much importance. In this paper, we built a reactor network analysis model with a detailed mechanism to describe and calculate the process in the sulfur recovery unit. This detailed mechanism included 94 species and 615 elementary reactions. Our model has a more accurate residence time than other existing models. This simulation model was verified with industrial data, and the calculation result was highly consistent with the industrial data and more accurate than other approaches. Then, we used this reactor network analysis model to study the effect of the excess air coefficient, the thermal reactor temperature, and the temperature of cooling water on the sulfur recovery efficiency of a real device in the Puguang gas field. The result showed the excess air coefficient and thermal reactor temperature had a clear impact on sulfur recovery efficiency. After analysis, we got the optimum condition parameters for this device. At last, these parameters were tested in the real sulfur recovery device, and the result was reasonable. Our research provides a way to improve the sulfur recovery process in the industry, and it can be helpful to reduce pollution emissions and improve economic performance.
format Article
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institution Kabale University
issn 2090-9063
2090-9071
language English
publishDate 2020-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-f6a3a9ce7a4742c088692cb561c3b9162025-02-03T01:26:57ZengWileyJournal of Chemistry2090-90632090-90712020-01-01202010.1155/2020/41562164156216Kinetic Modeling Study of the Industrial Sulfur Recovery Process for Operating Condition OptimizationShan Huang0Zhaohui Teng1Lisheng Zhang2Qulan Zhou3Na Li4State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, ChinaState Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, ChinaNatural Gas Purification Plant of Puguang Gasfield, Dazhou 636150, ChinaState Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, ChinaState Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, ChinaSulfur recovery from acid gas (H2S and CO2), which is contained in fresh natural gas, can bring many economic and environmental benefits, and this topic has been studied for years. Finding an optimal operating condition for the factory is of much importance. In this paper, we built a reactor network analysis model with a detailed mechanism to describe and calculate the process in the sulfur recovery unit. This detailed mechanism included 94 species and 615 elementary reactions. Our model has a more accurate residence time than other existing models. This simulation model was verified with industrial data, and the calculation result was highly consistent with the industrial data and more accurate than other approaches. Then, we used this reactor network analysis model to study the effect of the excess air coefficient, the thermal reactor temperature, and the temperature of cooling water on the sulfur recovery efficiency of a real device in the Puguang gas field. The result showed the excess air coefficient and thermal reactor temperature had a clear impact on sulfur recovery efficiency. After analysis, we got the optimum condition parameters for this device. At last, these parameters were tested in the real sulfur recovery device, and the result was reasonable. Our research provides a way to improve the sulfur recovery process in the industry, and it can be helpful to reduce pollution emissions and improve economic performance.http://dx.doi.org/10.1155/2020/4156216
spellingShingle Shan Huang
Zhaohui Teng
Lisheng Zhang
Qulan Zhou
Na Li
Kinetic Modeling Study of the Industrial Sulfur Recovery Process for Operating Condition Optimization
Journal of Chemistry
title Kinetic Modeling Study of the Industrial Sulfur Recovery Process for Operating Condition Optimization
title_full Kinetic Modeling Study of the Industrial Sulfur Recovery Process for Operating Condition Optimization
title_fullStr Kinetic Modeling Study of the Industrial Sulfur Recovery Process for Operating Condition Optimization
title_full_unstemmed Kinetic Modeling Study of the Industrial Sulfur Recovery Process for Operating Condition Optimization
title_short Kinetic Modeling Study of the Industrial Sulfur Recovery Process for Operating Condition Optimization
title_sort kinetic modeling study of the industrial sulfur recovery process for operating condition optimization
url http://dx.doi.org/10.1155/2020/4156216
work_keys_str_mv AT shanhuang kineticmodelingstudyoftheindustrialsulfurrecoveryprocessforoperatingconditionoptimization
AT zhaohuiteng kineticmodelingstudyoftheindustrialsulfurrecoveryprocessforoperatingconditionoptimization
AT lishengzhang kineticmodelingstudyoftheindustrialsulfurrecoveryprocessforoperatingconditionoptimization
AT qulanzhou kineticmodelingstudyoftheindustrialsulfurrecoveryprocessforoperatingconditionoptimization
AT nali kineticmodelingstudyoftheindustrialsulfurrecoveryprocessforoperatingconditionoptimization