Effect of the Addition of Essential Oils and Functional Extracts of Clove on Physicochemical Properties of Chitosan-Based Films

Mechanical and barrier properties of chitosan films prepared with essential oils of clove and functional extract were studied. The films made with functional extracts (esters E6 and E7) presented the significant increment of extensibility compared with the untreated chitosan films. In the case of pu...

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Main Authors: Paola Reyes-Chaparro, Nestor Gutierrez-Mendez, Erika Salas-Muñoz, Juan Guillermo Ayala-Soto, David Chavez-Flores, León Hernández-Ochoa
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2015/714254
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author Paola Reyes-Chaparro
Nestor Gutierrez-Mendez
Erika Salas-Muñoz
Juan Guillermo Ayala-Soto
David Chavez-Flores
León Hernández-Ochoa
author_facet Paola Reyes-Chaparro
Nestor Gutierrez-Mendez
Erika Salas-Muñoz
Juan Guillermo Ayala-Soto
David Chavez-Flores
León Hernández-Ochoa
author_sort Paola Reyes-Chaparro
collection DOAJ
description Mechanical and barrier properties of chitosan films prepared with essential oils of clove and functional extract were studied. The films made with functional extracts (esters E6 and E7) presented the significant increment of extensibility compared with the untreated chitosan films. In the case of punction test, the films made with the esters E6 and E7 resisted more the applied strength before tearing up compared with the chitosan control film (without any treatment). Thermogravimetric analysis values were determined for the chitosan control film and chitosan film treated with clove essential oil obtaining 112.17°C and 176.73°C, respectively. Atomic force microscopy (AFM) was used to determine their morphology by analyzing their surfaces and phase arrangement; AFM was also used to observe the porosity in chitosan-based antimicrobial films and the chitosan films incorporating functional extracts. The water vapour permeability (WVP) data showed that incorporating the functional extract to the formulation of films has a positive effect on water vapour barrier properties. In general, the incorporation of essential oils and functional extract of clove at 20% in chitosan films caused microstructural changes that were dependent on the different affinity of components.
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institution Kabale University
issn 1687-9422
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language English
publishDate 2015-01-01
publisher Wiley
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series International Journal of Polymer Science
spelling doaj-art-f610ab2eaac64bef98adb1ff8089b4762025-02-03T01:23:21ZengWileyInternational Journal of Polymer Science1687-94221687-94302015-01-01201510.1155/2015/714254714254Effect of the Addition of Essential Oils and Functional Extracts of Clove on Physicochemical Properties of Chitosan-Based FilmsPaola Reyes-Chaparro0Nestor Gutierrez-Mendez1Erika Salas-Muñoz2Juan Guillermo Ayala-Soto3David Chavez-Flores4León Hernández-Ochoa5Facultad de Ciencias Químicas, Universidad Autónoma de Chihuahua, Campus Universitario No. 2, Apartado Postal 669, 31125 Chihuahua, CHIH, MexicoFacultad de Ciencias Químicas, Universidad Autónoma de Chihuahua, Campus Universitario No. 2, Apartado Postal 669, 31125 Chihuahua, CHIH, MexicoFacultad de Ciencias Químicas, Universidad Autónoma de Chihuahua, Campus Universitario No. 2, Apartado Postal 669, 31125 Chihuahua, CHIH, MexicoFacultad de Ciencias Químicas, Universidad Autónoma de Chihuahua, Campus Universitario No. 2, Apartado Postal 669, 31125 Chihuahua, CHIH, MexicoFacultad de Ciencias Químicas, Universidad Autónoma de Chihuahua, Campus Universitario No. 2, Apartado Postal 669, 31125 Chihuahua, CHIH, MexicoFacultad de Ciencias Químicas, Universidad Autónoma de Chihuahua, Campus Universitario No. 2, Apartado Postal 669, 31125 Chihuahua, CHIH, MexicoMechanical and barrier properties of chitosan films prepared with essential oils of clove and functional extract were studied. The films made with functional extracts (esters E6 and E7) presented the significant increment of extensibility compared with the untreated chitosan films. In the case of punction test, the films made with the esters E6 and E7 resisted more the applied strength before tearing up compared with the chitosan control film (without any treatment). Thermogravimetric analysis values were determined for the chitosan control film and chitosan film treated with clove essential oil obtaining 112.17°C and 176.73°C, respectively. Atomic force microscopy (AFM) was used to determine their morphology by analyzing their surfaces and phase arrangement; AFM was also used to observe the porosity in chitosan-based antimicrobial films and the chitosan films incorporating functional extracts. The water vapour permeability (WVP) data showed that incorporating the functional extract to the formulation of films has a positive effect on water vapour barrier properties. In general, the incorporation of essential oils and functional extract of clove at 20% in chitosan films caused microstructural changes that were dependent on the different affinity of components.http://dx.doi.org/10.1155/2015/714254
spellingShingle Paola Reyes-Chaparro
Nestor Gutierrez-Mendez
Erika Salas-Muñoz
Juan Guillermo Ayala-Soto
David Chavez-Flores
León Hernández-Ochoa
Effect of the Addition of Essential Oils and Functional Extracts of Clove on Physicochemical Properties of Chitosan-Based Films
International Journal of Polymer Science
title Effect of the Addition of Essential Oils and Functional Extracts of Clove on Physicochemical Properties of Chitosan-Based Films
title_full Effect of the Addition of Essential Oils and Functional Extracts of Clove on Physicochemical Properties of Chitosan-Based Films
title_fullStr Effect of the Addition of Essential Oils and Functional Extracts of Clove on Physicochemical Properties of Chitosan-Based Films
title_full_unstemmed Effect of the Addition of Essential Oils and Functional Extracts of Clove on Physicochemical Properties of Chitosan-Based Films
title_short Effect of the Addition of Essential Oils and Functional Extracts of Clove on Physicochemical Properties of Chitosan-Based Films
title_sort effect of the addition of essential oils and functional extracts of clove on physicochemical properties of chitosan based films
url http://dx.doi.org/10.1155/2015/714254
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