Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious Materials

The agglomeration of nano-CaCO3 (NC) is the largest bottleneck in applications in cementitious materials. If nano-CaCO3 modifies the surface of micron-scale limestone powder (LS), then it will form nano-CaCO3/limestone composite particles (NC/LS). It is known that micron-scale limestone is easily di...

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Main Authors: Huashan Yang, Yujun Che
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2018/5732352
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author Huashan Yang
Yujun Che
author_facet Huashan Yang
Yujun Che
author_sort Huashan Yang
collection DOAJ
description The agglomeration of nano-CaCO3 (NC) is the largest bottleneck in applications in cementitious materials. If nano-CaCO3 modifies the surface of micron-scale limestone powder (LS), then it will form nano-CaCO3/limestone composite particles (NC/LS). It is known that micron-scale limestone is easily dispersed, and the “dispersion” of NC is governed by that of LS. Therefore, the dispersion of nano-CaCO3 can be improved by the NC/LS in cementitious materials. In this work, the preparation of NC/LS was carried out in a three-necked flask using the Ca(OH)2-H2O-CO2 reaction system. The morphology of NC/LS was observed by a field emission scanning electron microscope (FE-SEM). The effects of NC/LS on the hydration products and pore structure of cementitious materials are proposed. 5% NC/LS was added into cement paste and mortar, and the mechanical properties of the specimens were measured at a certain age. Differential scanning calorimetry (DSC), thermal gravimetric analysis (TG), and backscattered electron imaging (BSE) were conducted on the specimens to investigate the hydration products and pore structure. The properties of specimens with NC/LS were compared to that of control specimens (without NC/LS). The results revealed that NC/LS reduced the porosity and improved the mechanical properties of the cementitious materials.
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spelling doaj-art-f5f03a21aaff411c9f5b3d86871e58a22025-02-03T01:26:16ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/57323525732352Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious MaterialsHuashan Yang0Yujun Che1School of Materials and Architecture Engineering, Guizhou Normal University, Guiyang 550025, ChinaSchool of Materials and Architecture Engineering, Guizhou Normal University, Guiyang 550025, ChinaThe agglomeration of nano-CaCO3 (NC) is the largest bottleneck in applications in cementitious materials. If nano-CaCO3 modifies the surface of micron-scale limestone powder (LS), then it will form nano-CaCO3/limestone composite particles (NC/LS). It is known that micron-scale limestone is easily dispersed, and the “dispersion” of NC is governed by that of LS. Therefore, the dispersion of nano-CaCO3 can be improved by the NC/LS in cementitious materials. In this work, the preparation of NC/LS was carried out in a three-necked flask using the Ca(OH)2-H2O-CO2 reaction system. The morphology of NC/LS was observed by a field emission scanning electron microscope (FE-SEM). The effects of NC/LS on the hydration products and pore structure of cementitious materials are proposed. 5% NC/LS was added into cement paste and mortar, and the mechanical properties of the specimens were measured at a certain age. Differential scanning calorimetry (DSC), thermal gravimetric analysis (TG), and backscattered electron imaging (BSE) were conducted on the specimens to investigate the hydration products and pore structure. The properties of specimens with NC/LS were compared to that of control specimens (without NC/LS). The results revealed that NC/LS reduced the porosity and improved the mechanical properties of the cementitious materials.http://dx.doi.org/10.1155/2018/5732352
spellingShingle Huashan Yang
Yujun Che
Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious Materials
Advances in Materials Science and Engineering
title Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious Materials
title_full Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious Materials
title_fullStr Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious Materials
title_full_unstemmed Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious Materials
title_short Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious Materials
title_sort effects of nano caco3 limestone composite particles on the hydration products and pore structure of cementitious materials
url http://dx.doi.org/10.1155/2018/5732352
work_keys_str_mv AT huashanyang effectsofnanocaco3limestonecompositeparticlesonthehydrationproductsandporestructureofcementitiousmaterials
AT yujunche effectsofnanocaco3limestonecompositeparticlesonthehydrationproductsandporestructureofcementitiousmaterials