Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method
The thermal emission of alkali metal ions from Al30-pillared montmorillonite in comparison with its natural form was studied by mass spectrometry in the temperature range 770–930 K. The measurements were carried out on a magnetic mass spectrometer MI-1201. For natural montmorillonite, the densities...
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2017-01-01
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| Series: | Journal of Analytical Methods in Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2017/4984151 |
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| author | V. B. Motalov N. S. Karasev N. L. Ovchinnikov M. F. Butman |
| author_facet | V. B. Motalov N. S. Karasev N. L. Ovchinnikov M. F. Butman |
| author_sort | V. B. Motalov |
| collection | DOAJ |
| description | The thermal emission of alkali metal ions from Al30-pillared montmorillonite in comparison with its natural form was studied by mass spectrometry in the temperature range 770–930 K. The measurements were carried out on a magnetic mass spectrometer MI-1201. For natural montmorillonite, the densities of the emission currents (j) decrease in the mass spectrum in the following sequence (T = 805 K, A/cm2): K+ (4.55 · 10−14), Cs+ (9.72 · 10−15), Rb+ (1.13 · 10−15), Na+ (1.75 · 10−16), Li+ (3.37 · 10−17). For Al30-pillared montmorillonite, thermionic emission undergoes temperature-time changes. In the low-temperature section of the investigated range (770–805 K), the value of j increases substantially for all ions in comparison with natural montmorillonite (T = 805 K, A/cm2): Cs+ (6.47 · 10−13), K+ (9.44 · 10−14), Na+ (3.34 · 10−15), Rb+ (1.77 · 10−15), and Li+ (4.59 · 10−16). A reversible anomaly is observed in the temperature range 805–832 K: with increasing temperature, the value of j of alkaline ions falls abruptly. This effect increases with increasing ionic radius of M+. After a long heating-up period, this anomaly disappears and the lnj-1/T dependence acquires a classical linear form. The results are interpreted from the point of view of the dependence of the efficiency of thermionic emission on the phase transformations of pillars. |
| format | Article |
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| institution | Kabale University |
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| language | English |
| publishDate | 2017-01-01 |
| publisher | Wiley |
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| series | Journal of Analytical Methods in Chemistry |
| spelling | doaj-art-f56ce2b4abe948f29a1b7dca4af6e1472025-02-03T05:57:27ZengWileyJournal of Analytical Methods in Chemistry2090-88652090-88732017-01-01201710.1155/2017/49841514984151Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric MethodV. B. Motalov0N. S. Karasev1N. L. Ovchinnikov2M. F. Butman3Ivanovo State University of Chemistry and Technology, Sheremetevsky Av. 7, Ivanovo 153000, RussiaIvanovo State University of Chemistry and Technology, Sheremetevsky Av. 7, Ivanovo 153000, RussiaIvanovo State University of Chemistry and Technology, Sheremetevsky Av. 7, Ivanovo 153000, RussiaIvanovo State University of Chemistry and Technology, Sheremetevsky Av. 7, Ivanovo 153000, RussiaThe thermal emission of alkali metal ions from Al30-pillared montmorillonite in comparison with its natural form was studied by mass spectrometry in the temperature range 770–930 K. The measurements were carried out on a magnetic mass spectrometer MI-1201. For natural montmorillonite, the densities of the emission currents (j) decrease in the mass spectrum in the following sequence (T = 805 K, A/cm2): K+ (4.55 · 10−14), Cs+ (9.72 · 10−15), Rb+ (1.13 · 10−15), Na+ (1.75 · 10−16), Li+ (3.37 · 10−17). For Al30-pillared montmorillonite, thermionic emission undergoes temperature-time changes. In the low-temperature section of the investigated range (770–805 K), the value of j increases substantially for all ions in comparison with natural montmorillonite (T = 805 K, A/cm2): Cs+ (6.47 · 10−13), K+ (9.44 · 10−14), Na+ (3.34 · 10−15), Rb+ (1.77 · 10−15), and Li+ (4.59 · 10−16). A reversible anomaly is observed in the temperature range 805–832 K: with increasing temperature, the value of j of alkaline ions falls abruptly. This effect increases with increasing ionic radius of M+. After a long heating-up period, this anomaly disappears and the lnj-1/T dependence acquires a classical linear form. The results are interpreted from the point of view of the dependence of the efficiency of thermionic emission on the phase transformations of pillars.http://dx.doi.org/10.1155/2017/4984151 |
| spellingShingle | V. B. Motalov N. S. Karasev N. L. Ovchinnikov M. F. Butman Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method Journal of Analytical Methods in Chemistry |
| title | Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method |
| title_full | Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method |
| title_fullStr | Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method |
| title_full_unstemmed | Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method |
| title_short | Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method |
| title_sort | thermal emission of alkali metal ions from al30 pillared montmorillonite studied by mass spectrometric method |
| url | http://dx.doi.org/10.1155/2017/4984151 |
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