Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle Beams

An electrochemical cell has been developed that allows for the rapid and exhaustive detection of oxygen and/or hydrogen peroxide produced during the radiolysis of aqueous solutions by alpha particle or proton beams. Short, 10–100 s, exposures were sufficient to yield steady-state electrochemical cu...

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Main Authors: J. E. Liedhegner, W. Jennings, J. Wainright
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:International Journal of Electrochemistry
Online Access:http://dx.doi.org/10.4061/2011/864126
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author J. E. Liedhegner
W. Jennings
J. Wainright
author_facet J. E. Liedhegner
W. Jennings
J. Wainright
author_sort J. E. Liedhegner
collection DOAJ
description An electrochemical cell has been developed that allows for the rapid and exhaustive detection of oxygen and/or hydrogen peroxide produced during the radiolysis of aqueous solutions by alpha particle or proton beams. Short, 10–100 s, exposures were sufficient to yield steady-state electrochemical currents proportional to the radiolysis G-factor. The use of thin SiC windows provided a robust means of separating the vacuum environment of the ion-beam accelerator from the aqueous solution at atmospheric pressure with minimal energy loss.
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series International Journal of Electrochemistry
spelling doaj-art-f4ce8c74349b4565882ba62efc06f51a2025-02-03T05:58:18ZengWileyInternational Journal of Electrochemistry2090-35372011-01-01201110.4061/2011/864126864126Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle BeamsJ. E. Liedhegner0W. Jennings1J. Wainright2Department of Chemical Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106, USADepartment of Materials Science and Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106, USADepartment of Chemical Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106, USAAn electrochemical cell has been developed that allows for the rapid and exhaustive detection of oxygen and/or hydrogen peroxide produced during the radiolysis of aqueous solutions by alpha particle or proton beams. Short, 10–100 s, exposures were sufficient to yield steady-state electrochemical currents proportional to the radiolysis G-factor. The use of thin SiC windows provided a robust means of separating the vacuum environment of the ion-beam accelerator from the aqueous solution at atmospheric pressure with minimal energy loss.http://dx.doi.org/10.4061/2011/864126
spellingShingle J. E. Liedhegner
W. Jennings
J. Wainright
Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle Beams
International Journal of Electrochemistry
title Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle Beams
title_full Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle Beams
title_fullStr Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle Beams
title_full_unstemmed Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle Beams
title_short Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle Beams
title_sort rapid electrochemical detection of radiolysis products in an aqueous solution exposed to alpha particle beams
url http://dx.doi.org/10.4061/2011/864126
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