Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide
The bioinorganic complex of aspartic acid and arsenic triiodide was synthesized by a solid-state reaction at room temperature. The formula of the complex is AsI3[HOOCCH2CH(NH2)COOH]2.5. The crystal structure of the complex belongs to monoclinic system with lattice parameters: a=1.0019 nm, b=1.5118 n...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/217947 |
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| author | Guo-Qing Zhong Wen-Wei Zhong Rong-Rong Jia Yu-Qing Jia |
| author_facet | Guo-Qing Zhong Wen-Wei Zhong Rong-Rong Jia Yu-Qing Jia |
| author_sort | Guo-Qing Zhong |
| collection | DOAJ |
| description | The bioinorganic complex of aspartic acid and arsenic triiodide was synthesized by a solid-state reaction at room temperature. The formula of the complex is AsI3[HOOCCH2CH(NH2)COOH]2.5. The crystal structure of the complex belongs to monoclinic system with lattice parameters: a=1.0019 nm, b=1.5118 nm, c=2.1971 nm, and β=100.28°. The infrared spectra can demonstrate the complex formation between the arsenic ion and aspartic acid, and the complex may be a dimer with bridge structure. The result of primary biological test indicates that the complex possesses better biological activity for the HL-60 cells of the leukemia than arsenic triiodide. |
| format | Article |
| id | doaj-art-f4b95a3e27af44c19bbb87cc71fc3296 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-f4b95a3e27af44c19bbb87cc71fc32962025-02-03T05:47:16ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/217947217947Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic TriiodideGuo-Qing Zhong0Wen-Wei Zhong1Rong-Rong Jia2Yu-Qing Jia3State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaCollege of Life Sciences, Sichuan University, Chengdu 610064, ChinaDepartment of Chemistry, East China University of Science and Technology, Shanghai 200237, ChinaDepartment of Chemistry, East China University of Science and Technology, Shanghai 200237, ChinaThe bioinorganic complex of aspartic acid and arsenic triiodide was synthesized by a solid-state reaction at room temperature. The formula of the complex is AsI3[HOOCCH2CH(NH2)COOH]2.5. The crystal structure of the complex belongs to monoclinic system with lattice parameters: a=1.0019 nm, b=1.5118 nm, c=2.1971 nm, and β=100.28°. The infrared spectra can demonstrate the complex formation between the arsenic ion and aspartic acid, and the complex may be a dimer with bridge structure. The result of primary biological test indicates that the complex possesses better biological activity for the HL-60 cells of the leukemia than arsenic triiodide.http://dx.doi.org/10.1155/2013/217947 |
| spellingShingle | Guo-Qing Zhong Wen-Wei Zhong Rong-Rong Jia Yu-Qing Jia Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide Journal of Chemistry |
| title | Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide |
| title_full | Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide |
| title_fullStr | Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide |
| title_full_unstemmed | Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide |
| title_short | Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide |
| title_sort | solid state synthesis characterization and biological activity of the bioinorganic complex of aspartic acid and arsenic triiodide |
| url | http://dx.doi.org/10.1155/2013/217947 |
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