Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber Composites

This work investigates the effect of hydrothermal aging on the properties of polypropylene/alfa fiber composites. Hydrothermal aging was induced in an environmental testing chamber at 65°C and 75% relative humidity (RH) over a 1000 h period. At the beginning (t=0 h), the results showed that Young’s...

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Main Authors: Noura Hamour, Amar Boukerrou, Hocine Djidjelli, Jean-Eudes Maigret, Johnny Beaugrand
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2015/451691
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author Noura Hamour
Amar Boukerrou
Hocine Djidjelli
Jean-Eudes Maigret
Johnny Beaugrand
author_facet Noura Hamour
Amar Boukerrou
Hocine Djidjelli
Jean-Eudes Maigret
Johnny Beaugrand
author_sort Noura Hamour
collection DOAJ
description This work investigates the effect of hydrothermal aging on the properties of polypropylene/alfa fiber composites. Hydrothermal aging was induced in an environmental testing chamber at 65°C and 75% relative humidity (RH) over a 1000 h period. At the beginning (t=0 h), the results showed that Young’s moduli of the untreated alfa fibers and the acetylation-treated fibers increased by 21% and 36%, respectively, compared with the virgin polypropylene (PP). Additionally, Young’s moduli decreased by 7% for the compatibilized composites composed of maleic anhydride grafted polypropylene (MAPP). After 1000 h of aging, Young’s moduli decreased by 36% for untreated alfa fibers and 29% for the acetylation-treated alfa fibers and the compatibilized composites. Significant degradation was observed in the untreated alfa fiber samples. The Fourier transformed infrared (FTIR) allows us to distinguish the characteristic absorption bands of the main chemical functions present in the composite material before and after aging. The thermal properties showed that the thermal stability and the degree of crystallinity of the composites decreased after hydrothermal aging; this result was corroborated by the dynamical mechanical analysis (DMA) results.
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institution Kabale University
issn 1687-9422
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language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-f492343ba21242b5bec30a2c9b1c1b222025-02-03T05:47:12ZengWileyInternational Journal of Polymer Science1687-94221687-94302015-01-01201510.1155/2015/451691451691Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber CompositesNoura Hamour0Amar Boukerrou1Hocine Djidjelli2Jean-Eudes Maigret3Johnny Beaugrand4Laboratoire des Matériaux Polymères Avancés (LMPA), Faculté de Technologie, Université Abderrahmane Mira, 06000 Bejaia, AlgeriaLaboratoire des Matériaux Polymères Avancés (LMPA), Faculté de Technologie, Université Abderrahmane Mira, 06000 Bejaia, AlgeriaLaboratoire des Matériaux Polymères Avancés (LMPA), Faculté de Technologie, Université Abderrahmane Mira, 06000 Bejaia, AlgeriaINRA, UMR614 Fractionnement des AgroRessources et Environnement, 51100 Reims, FranceINRA, UMR614 Fractionnement des AgroRessources et Environnement, 51100 Reims, FranceThis work investigates the effect of hydrothermal aging on the properties of polypropylene/alfa fiber composites. Hydrothermal aging was induced in an environmental testing chamber at 65°C and 75% relative humidity (RH) over a 1000 h period. At the beginning (t=0 h), the results showed that Young’s moduli of the untreated alfa fibers and the acetylation-treated fibers increased by 21% and 36%, respectively, compared with the virgin polypropylene (PP). Additionally, Young’s moduli decreased by 7% for the compatibilized composites composed of maleic anhydride grafted polypropylene (MAPP). After 1000 h of aging, Young’s moduli decreased by 36% for untreated alfa fibers and 29% for the acetylation-treated alfa fibers and the compatibilized composites. Significant degradation was observed in the untreated alfa fiber samples. The Fourier transformed infrared (FTIR) allows us to distinguish the characteristic absorption bands of the main chemical functions present in the composite material before and after aging. The thermal properties showed that the thermal stability and the degree of crystallinity of the composites decreased after hydrothermal aging; this result was corroborated by the dynamical mechanical analysis (DMA) results.http://dx.doi.org/10.1155/2015/451691
spellingShingle Noura Hamour
Amar Boukerrou
Hocine Djidjelli
Jean-Eudes Maigret
Johnny Beaugrand
Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber Composites
International Journal of Polymer Science
title Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber Composites
title_full Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber Composites
title_fullStr Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber Composites
title_full_unstemmed Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber Composites
title_short Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber Composites
title_sort effects of mapp compatibilization and acetylation treatment followed by hydrothermal aging on polypropylene alfa fiber composites
url http://dx.doi.org/10.1155/2015/451691
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