Highly porous activated carbon from betel palm shells as the prospective electrode for high-performance supercapacitors
This research has investigated the viability of valorizing Areca or Betel palm-shells into activated carbon, to be applied as an electrode active material in supercapacitors. The palm-shells are an agricultural waste from betel-nut production, an important economic crop in several regions around the...
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| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co., Ltd.
2025-01-01
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| Series: | Materials Science for Energy Technologies |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2589299125000035 |
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| Summary: | This research has investigated the viability of valorizing Areca or Betel palm-shells into activated carbon, to be applied as an electrode active material in supercapacitors. The palm-shells are an agricultural waste from betel-nut production, an important economic crop in several regions around the world. The conversion process mainly involves pulverization, ZnCl2-activation, and carbonization. The effect of carbonization temperatures – 500, 600, 700, and 800 °C, was studied on the properties of the activated carbon. Microstructural characterizations like BET, Raman, and XPS were carried out. All the activated samples are microporous, have a specific surface area >1,000 m2 g−1, and possess an intensity ratio of D-to-G band close to 1. More than 80 % of the atomic concentration of the samples is carbon; the C 1s bonds include C=C or sp2, C–C or sp3, C–(O,N), C=O, and O–C=O or π– π*. The activated carbon synthesized at 700 °C shows the most favorable properties for being used as the electrode in supercapacitors. Its electrochemical properties, evaluated by galvanostatic charge–discharge and cyclic voltammetry deliver the maximum specific capacitances of 144.48F·g−1 at 1 A·g−1 and 169.21F·g−1 20 mV·s−1, respectively. The supercapacitors do perform stably at long-term cycling with the capacitance retention (>98 %) and the coulombic efficiency at almost 100 % over 50,000 cycles. The betel-palm-shell carbon has a very comparable capacitive performance to other biomass-derived carbons with the respective maximum energy and powder densities of 7.63 Wh·kg−1 and 5,849.93 W·kg−1. Converting the betel-palm-shell waste, one of the common agricultural wastes in Asia, Oceania, Africa, or Latin America to activated carbon is a pathway of waste valorization as well as leads to a new business opportunity of producing carbon electrodes for an energy application of supercapacitors. This will further go towards a circular carbon economy, not only reducing the carbon footprint and other pollution caused by currently widely practiced incineration, but also creating a sustainable loop of material utilization. |
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| ISSN: | 2589-2991 |