Application of Ultraviolet Radiation to Control the Calcium Carbonate Scale Formation and Deposition on the Membranes

Scale formation on surfaces in contact with water supersaturated with calcium carbonate creates technical problems, including heat transfer hindrance, energy consumption, and equipment shutdown. Thus, nowadays, there is an increasing need for new approaches that are environmentally friendly and econ...

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Main Authors: Chanbasha Basheer, Mokhtar Rashwan, Eid Al-Mutairi, Amjad A. Shaikh, Khurram Karim Qureshi
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2020/8083705
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author Chanbasha Basheer
Mokhtar Rashwan
Eid Al-Mutairi
Amjad A. Shaikh
Khurram Karim Qureshi
author_facet Chanbasha Basheer
Mokhtar Rashwan
Eid Al-Mutairi
Amjad A. Shaikh
Khurram Karim Qureshi
author_sort Chanbasha Basheer
collection DOAJ
description Scale formation on surfaces in contact with water supersaturated with calcium carbonate creates technical problems, including heat transfer hindrance, energy consumption, and equipment shutdown. Thus, nowadays, there is an increasing need for new approaches that are environmentally friendly and economically feasible. In this work, for the first time, calcium carbonate growth was investigated using UV light exposure, and the growth rate was compared with control and commercial antiscalant. Saturated calcium carbonate samples were exposed to UV radiation; the growth rate of calcium carbonate crystals was monitored at different time intervals. Results clearly show that about 85% decrease in crystal growth rate was observed when compared to 43% after the addition of 3 mg/L of amino tris(methylene phosphonic acid) antiscalant. Calcium carbonate scale deposition on hydrophobic and hydrophilic membranes was investigated. The amount of scale deposited in the case of a UV-treated sample is insignificant when compared to control samples. Thus, the exposure of UV might help to improve the membranes’ lifetime. X-ray diffraction and scanning electron microscopy analyses revealed that UV light treatment produced mostly calcite crystals. The produced calcites are less dense and less adherent, and it can be easily removable when compared to other types of calcium carbonate phases. Thus, UV radiation is an efficient green approach for calcium carbonate scale mitigation on membrane surfaces.
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spelling doaj-art-f2a3626781da41b4ba9139b20e932c412025-02-03T06:05:31ZengWileyJournal of Chemistry2090-90712020-01-01202010.1155/2020/80837058083705Application of Ultraviolet Radiation to Control the Calcium Carbonate Scale Formation and Deposition on the MembranesChanbasha Basheer0Mokhtar Rashwan1Eid Al-Mutairi2Amjad A. Shaikh3Khurram Karim Qureshi4Department of ChemistryDepartment of ChemistryDepartment of Chemical EngineeringDepartment of Chemical EngineeringDepartment of Electrical EngineeringScale formation on surfaces in contact with water supersaturated with calcium carbonate creates technical problems, including heat transfer hindrance, energy consumption, and equipment shutdown. Thus, nowadays, there is an increasing need for new approaches that are environmentally friendly and economically feasible. In this work, for the first time, calcium carbonate growth was investigated using UV light exposure, and the growth rate was compared with control and commercial antiscalant. Saturated calcium carbonate samples were exposed to UV radiation; the growth rate of calcium carbonate crystals was monitored at different time intervals. Results clearly show that about 85% decrease in crystal growth rate was observed when compared to 43% after the addition of 3 mg/L of amino tris(methylene phosphonic acid) antiscalant. Calcium carbonate scale deposition on hydrophobic and hydrophilic membranes was investigated. The amount of scale deposited in the case of a UV-treated sample is insignificant when compared to control samples. Thus, the exposure of UV might help to improve the membranes’ lifetime. X-ray diffraction and scanning electron microscopy analyses revealed that UV light treatment produced mostly calcite crystals. The produced calcites are less dense and less adherent, and it can be easily removable when compared to other types of calcium carbonate phases. Thus, UV radiation is an efficient green approach for calcium carbonate scale mitigation on membrane surfaces.http://dx.doi.org/10.1155/2020/8083705
spellingShingle Chanbasha Basheer
Mokhtar Rashwan
Eid Al-Mutairi
Amjad A. Shaikh
Khurram Karim Qureshi
Application of Ultraviolet Radiation to Control the Calcium Carbonate Scale Formation and Deposition on the Membranes
Journal of Chemistry
title Application of Ultraviolet Radiation to Control the Calcium Carbonate Scale Formation and Deposition on the Membranes
title_full Application of Ultraviolet Radiation to Control the Calcium Carbonate Scale Formation and Deposition on the Membranes
title_fullStr Application of Ultraviolet Radiation to Control the Calcium Carbonate Scale Formation and Deposition on the Membranes
title_full_unstemmed Application of Ultraviolet Radiation to Control the Calcium Carbonate Scale Formation and Deposition on the Membranes
title_short Application of Ultraviolet Radiation to Control the Calcium Carbonate Scale Formation and Deposition on the Membranes
title_sort application of ultraviolet radiation to control the calcium carbonate scale formation and deposition on the membranes
url http://dx.doi.org/10.1155/2020/8083705
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