Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic Acid
Complex [CrO2 (C7H5O2) C2H5OH) (H2O)2] was prepared by using benzoic acid. Its spectral characterization was done by using Elemental analysis (C and H), Inductively coupled plasma optical emission spectroscopy (ICP - OES), Ultraviolet - visible (UV-Vis) spectroscopy, Fourier transform infrared (FTIR...
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Wiley
2011-01-01
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Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2011/215012 |
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author | M. K. Mishra N. M. Misra |
author_facet | M. K. Mishra N. M. Misra |
author_sort | M. K. Mishra |
collection | DOAJ |
description | Complex [CrO2 (C7H5O2) C2H5OH) (H2O)2] was prepared by using benzoic acid. Its spectral characterization was done by using Elemental analysis (C and H), Inductively coupled plasma optical emission spectroscopy (ICP - OES), Ultraviolet - visible (UV-Vis) spectroscopy, Fourier transform infrared (FTIR) spectroscopy and Fast Atomic Bombardment (FAB) Mass spectrometry. Whereas thermal decomposition was investigated by differential scanning calorimetric (DSC). The low value of activation energy of exothermic change indicated lability of complex. |
format | Article |
id | doaj-art-eeebb9e533ea4dbda1f10ec174e1c2c7 |
institution | Kabale University |
issn | 0973-4945 2090-9810 |
language | English |
publishDate | 2011-01-01 |
publisher | Wiley |
record_format | Article |
series | E-Journal of Chemistry |
spelling | doaj-art-eeebb9e533ea4dbda1f10ec174e1c2c72025-02-03T01:23:47ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018251351610.1155/2011/215012Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic AcidM. K. Mishra0N. M. Misra1Department of Chemistry B.I.T., Sindri, Dhanbad, IndiaDepartment of Applied Chemistry ISM, Dhanbad, IndiaComplex [CrO2 (C7H5O2) C2H5OH) (H2O)2] was prepared by using benzoic acid. Its spectral characterization was done by using Elemental analysis (C and H), Inductively coupled plasma optical emission spectroscopy (ICP - OES), Ultraviolet - visible (UV-Vis) spectroscopy, Fourier transform infrared (FTIR) spectroscopy and Fast Atomic Bombardment (FAB) Mass spectrometry. Whereas thermal decomposition was investigated by differential scanning calorimetric (DSC). The low value of activation energy of exothermic change indicated lability of complex.http://dx.doi.org/10.1155/2011/215012 |
spellingShingle | M. K. Mishra N. M. Misra Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic Acid E-Journal of Chemistry |
title | Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic Acid |
title_full | Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic Acid |
title_fullStr | Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic Acid |
title_full_unstemmed | Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic Acid |
title_short | Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic Acid |
title_sort | thermal decomposition kinetics of labile chromium complex with benzoic acid |
url | http://dx.doi.org/10.1155/2011/215012 |
work_keys_str_mv | AT mkmishra thermaldecompositionkineticsoflabilechromiumcomplexwithbenzoicacid AT nmmisra thermaldecompositionkineticsoflabilechromiumcomplexwithbenzoicacid |