Thermal Decomposition Kinetics of Labile Chromium Complex with Benzoic Acid

Complex [CrO2 (C7H5O2) C2H5OH) (H2O)2] was prepared by using benzoic acid. Its spectral characterization was done by using Elemental analysis (C and H), Inductively coupled plasma optical emission spectroscopy (ICP - OES), Ultraviolet - visible (UV-Vis) spectroscopy, Fourier transform infrared (FTIR...

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Bibliographic Details
Main Authors: M. K. Mishra, N. M. Misra
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/215012
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Summary:Complex [CrO2 (C7H5O2) C2H5OH) (H2O)2] was prepared by using benzoic acid. Its spectral characterization was done by using Elemental analysis (C and H), Inductively coupled plasma optical emission spectroscopy (ICP - OES), Ultraviolet - visible (UV-Vis) spectroscopy, Fourier transform infrared (FTIR) spectroscopy and Fast Atomic Bombardment (FAB) Mass spectrometry. Whereas thermal decomposition was investigated by differential scanning calorimetric (DSC). The low value of activation energy of exothermic change indicated lability of complex.
ISSN:0973-4945
2090-9810