Surface Morphology and Optical Studies of Non-aqueous Bi2S3 Thin Films
A high purity, amorphous Bi2S3 thin film composed of loosely packed nanometer-sized spherical grains has been successfully deposited onto ITO substrate at room temperature from non-aqueous bismuth nitrate and sodium thiosulphate solution using a simple, inexpensive, reproducible, and environmentally...
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| Main Author: | |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2007-02-01
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| Series: | International Journal of Electrochemical Science |
| Subjects: | |
| Online Access: | http://www.electrochemsci.org/papers/vol2/2020141.pdf |
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| Summary: | A high purity, amorphous Bi2S3 thin film composed of loosely packed nanometer-sized spherical grains has been successfully deposited onto ITO substrate at room temperature from non-aqueous bismuth nitrate and sodium thiosulphate solution using a simple, inexpensive, reproducible, and environmentally friendly chemical route method. Film was characterized for structural, surface morphological, optical properties by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV-vis spectrometer, respectively. In last section, Bi2S3 film on ITO substrate was utilized in photo-electrochemical (PEC) solar cell as a working and platinum as a reference electrode in presence of 80 mW/cm2 light intensity in lithium iodide as an electrolyte. Film of non-aqueous Bi2S3 exhibits two separate direct band transitions. Existence of two separate direct transitions was firstly noted in Bi2S3 thin films and explained its possible causes. PEC analysis confirms n-type conductivity. |
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| ISSN: | 1452-3981 |