A Comprehensive Model and Experimental Investigation of Venting Dynamics and Mass Loss in Lithium-Ion Batteries Under a Thermal Runaway

Thermal runaway (TR) has become a critical safety concern with the widespread use of lithium-ion batteries (LIBs) as an energy storage solution to meet the growing global energy demand. This issue has become a significant barrier to the expansion of LIB technologies. Addressing the urgent need for s...

Full description

Saved in:
Bibliographic Details
Main Authors: Ai Chen, Resul Sahin, Marco Ströbel, Thomas Kottke, Stefan Hecker, Alexander Fill
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Batteries
Subjects:
Online Access:https://www.mdpi.com/2313-0105/11/3/96
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Thermal runaway (TR) has become a critical safety concern with the widespread use of lithium-ion batteries (LIBs) as an energy storage solution to meet the growing global energy demand. This issue has become a significant barrier to the expansion of LIB technologies. Addressing the urgent need for safer LIBs, this study developed a comprehensive model to simulate TR in cylindrical 18650 nickel cobalt manganese (NMC) LIBs. By incorporating experiments with LG<sup>®</sup>-INR18650-MJ1 cells, the model specifically aimed to accurately predict critical TR parameters, including temperature evolution, internal pressure changes, venting phases, and mass loss dynamics. The simulation closely correlated with experimental outcomes, particularly in replicating double venting mechanisms, gas generation, and the characteristics of mass loss observed during TR events. This study confirmed the feasibility of assuming proportional relationships between gas generation and the cell capacity and between the mass loss from solid particle ejection and the total mass loss, thereby simplifying the modeling of both gas generation and mass loss behaviors in LIBs under TR. Conclusively, the findings advanced the understanding of TR mechanisms in LIBs, providing a solid foundation for future research aimed at mitigating risks and promoting the safe integration of LIBs into sustainable energy solutions.
ISSN:2313-0105