Preparation and Study of Some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) Complexes Containing Heterocyclic Nitrogen Donor Ligands
This paper presents a new mixed-ligand complexes with the general formula [M(BT)(BI)2X2] where BT=benzotriazole, BI=benzimidazole, X=SCN and M=Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II). The reaction was carried out by using the appropriate molar ratios of metal:ligand (1:1:2:2) (M:BT:BI:X) a...
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2010/793261 |
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| author | Shayma A. Shaker |
| author_facet | Shayma A. Shaker |
| author_sort | Shayma A. Shaker |
| collection | DOAJ |
| description | This paper presents a new mixed-ligand complexes with the general formula [M(BT)(BI)2X2] where BT=benzotriazole, BI=benzimidazole, X=SCN and M=Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II). The reaction was carried out by using the appropriate molar ratios of metal:ligand (1:1:2:2) (M:BT:BI:X) as required. The resulting products were found to be solids, not soluble in water and in ordinary organic solvents but highly soluble in DMSO. These complexes have been studied by UV-visible, IR and (1H, 13C) NMR spectra, molar conductivity, elemental analysis of C, H, N, determination of metal and magnetic susceptibility. The result suggests that the benzimidazoleas as a monodentate was coordinated with the metal ions through the N atom. Nevertheless, the benzotriazole as bidentate was coordinated with the metal ions through the N2 and N3 atoms. SCN was coordinated with the metal ions through the nitogen atom. |
| format | Article |
| id | doaj-art-ee97c4687e324553a686314c4fa09103 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-ee97c4687e324553a686314c4fa091032025-02-03T05:58:34ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-01741598160410.1155/2010/793261Preparation and Study of Some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) Complexes Containing Heterocyclic Nitrogen Donor LigandsShayma A. Shaker0Department of Engineering Sciences and Mathematics, Universiti Tenaga Nasional, 43009 Kajang, Selangor, MalaysiaThis paper presents a new mixed-ligand complexes with the general formula [M(BT)(BI)2X2] where BT=benzotriazole, BI=benzimidazole, X=SCN and M=Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II). The reaction was carried out by using the appropriate molar ratios of metal:ligand (1:1:2:2) (M:BT:BI:X) as required. The resulting products were found to be solids, not soluble in water and in ordinary organic solvents but highly soluble in DMSO. These complexes have been studied by UV-visible, IR and (1H, 13C) NMR spectra, molar conductivity, elemental analysis of C, H, N, determination of metal and magnetic susceptibility. The result suggests that the benzimidazoleas as a monodentate was coordinated with the metal ions through the N atom. Nevertheless, the benzotriazole as bidentate was coordinated with the metal ions through the N2 and N3 atoms. SCN was coordinated with the metal ions through the nitogen atom.http://dx.doi.org/10.1155/2010/793261 |
| spellingShingle | Shayma A. Shaker Preparation and Study of Some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) Complexes Containing Heterocyclic Nitrogen Donor Ligands E-Journal of Chemistry |
| title | Preparation and Study of Some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) Complexes Containing Heterocyclic Nitrogen Donor Ligands |
| title_full | Preparation and Study of Some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) Complexes Containing Heterocyclic Nitrogen Donor Ligands |
| title_fullStr | Preparation and Study of Some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) Complexes Containing Heterocyclic Nitrogen Donor Ligands |
| title_full_unstemmed | Preparation and Study of Some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) Complexes Containing Heterocyclic Nitrogen Donor Ligands |
| title_short | Preparation and Study of Some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) Complexes Containing Heterocyclic Nitrogen Donor Ligands |
| title_sort | preparation and study of some mn ii co ii ni ii cu ii cd ii and pb ii complexes containing heterocyclic nitrogen donor ligands |
| url | http://dx.doi.org/10.1155/2010/793261 |
| work_keys_str_mv | AT shaymaashaker preparationandstudyofsomemniicoiiniiicuiicdiiandpbiicomplexescontainingheterocyclicnitrogendonorligands |