Comparison of Catalysts Preyssler and Silica-Supported Nano Preyssler in the Synthesis of Acetyl Salicylic Acid

The extensive demand for cleaner environment is forcing chemical industry to use less hazardous materials. In this regard, heteropolyacids attracted considerable amount of interest due to the less toxic behavior in addition of possessing higher acidity. Heteropoly acids have been used as catalysts f...

Full description

Saved in:
Bibliographic Details
Main Authors: H. Nazari, A. Ahmadpour, F. F. Bamoharram, M. M. Heravi, N. Eslami
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/892861
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832558214063849472
author H. Nazari
A. Ahmadpour
F. F. Bamoharram
M. M. Heravi
N. Eslami
author_facet H. Nazari
A. Ahmadpour
F. F. Bamoharram
M. M. Heravi
N. Eslami
author_sort H. Nazari
collection DOAJ
description The extensive demand for cleaner environment is forcing chemical industry to use less hazardous materials. In this regard, heteropolyacids attracted considerable amount of interest due to the less toxic behavior in addition of possessing higher acidity. Heteropoly acids have been used as catalysts for the reaction of salicylic acid with acetic anhydride. The performance of different forms of heteropoly acids in the presence of acetic anhydride as acetylating agent for acetylation of salicylic acid was compared. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable.
format Article
id doaj-art-ed6c0209918941cea2f99f676aa15ff9
institution Kabale University
issn 0973-4945
2090-9810
language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series E-Journal of Chemistry
spelling doaj-art-ed6c0209918941cea2f99f676aa15ff92025-02-03T01:32:56ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-019127227610.1155/2012/892861Comparison of Catalysts Preyssler and Silica-Supported Nano Preyssler in the Synthesis of Acetyl Salicylic AcidH. Nazari0A. Ahmadpour1F. F. Bamoharram2M. M. Heravi3N. Eslami4Department of Chemical Engineering, Ferdowsi University of Mashhad, IranDepartment of Chemical Engineering, Ferdowsi University of Mashhad, IranDepartment of Chemistry, School of Sciences, Islamic Azad University-Mashhad Branch, Mashhad, IranDepartment of Chemistry, School of Sciences, Alzahra University, Tehran, IranDepartment of Chemical Engineering, Ferdowsi University of Mashhad, IranThe extensive demand for cleaner environment is forcing chemical industry to use less hazardous materials. In this regard, heteropolyacids attracted considerable amount of interest due to the less toxic behavior in addition of possessing higher acidity. Heteropoly acids have been used as catalysts for the reaction of salicylic acid with acetic anhydride. The performance of different forms of heteropoly acids in the presence of acetic anhydride as acetylating agent for acetylation of salicylic acid was compared. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable.http://dx.doi.org/10.1155/2012/892861
spellingShingle H. Nazari
A. Ahmadpour
F. F. Bamoharram
M. M. Heravi
N. Eslami
Comparison of Catalysts Preyssler and Silica-Supported Nano Preyssler in the Synthesis of Acetyl Salicylic Acid
E-Journal of Chemistry
title Comparison of Catalysts Preyssler and Silica-Supported Nano Preyssler in the Synthesis of Acetyl Salicylic Acid
title_full Comparison of Catalysts Preyssler and Silica-Supported Nano Preyssler in the Synthesis of Acetyl Salicylic Acid
title_fullStr Comparison of Catalysts Preyssler and Silica-Supported Nano Preyssler in the Synthesis of Acetyl Salicylic Acid
title_full_unstemmed Comparison of Catalysts Preyssler and Silica-Supported Nano Preyssler in the Synthesis of Acetyl Salicylic Acid
title_short Comparison of Catalysts Preyssler and Silica-Supported Nano Preyssler in the Synthesis of Acetyl Salicylic Acid
title_sort comparison of catalysts preyssler and silica supported nano preyssler in the synthesis of acetyl salicylic acid
url http://dx.doi.org/10.1155/2012/892861
work_keys_str_mv AT hnazari comparisonofcatalystspreysslerandsilicasupportednanopreysslerinthesynthesisofacetylsalicylicacid
AT aahmadpour comparisonofcatalystspreysslerandsilicasupportednanopreysslerinthesynthesisofacetylsalicylicacid
AT ffbamoharram comparisonofcatalystspreysslerandsilicasupportednanopreysslerinthesynthesisofacetylsalicylicacid
AT mmheravi comparisonofcatalystspreysslerandsilicasupportednanopreysslerinthesynthesisofacetylsalicylicacid
AT neslami comparisonofcatalystspreysslerandsilicasupportednanopreysslerinthesynthesisofacetylsalicylicacid