Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline
Boron trifluoride (BF3) doped tetraaniline with novel structure were successfully synthesized via two step method. In the first step, emeraldine base form tetraaniline was synthesized via oxidative chemical polymerization of N-phenyl-1, 4-phenylenediamine using ammonium persulphate as oxidant. In th...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/392718 |
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| author | K. Basavaiah A. V. Prasada Rao |
| author_facet | K. Basavaiah A. V. Prasada Rao |
| author_sort | K. Basavaiah |
| collection | DOAJ |
| description | Boron trifluoride (BF3) doped tetraaniline with novel structure were successfully synthesized via two step method. In the first step, emeraldine base form tetraaniline was synthesized via oxidative chemical polymerization of N-phenyl-1, 4-phenylenediamine using ammonium persulphate as oxidant. In the second step involves control BF3 doping of tetraaniline using boron trifluoride etherate. As synthesized BF3 doped tetraaniline have been well characterized by UV-Visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction patterns (XRD), and scanning electron microscopy (SEM) and thermogravimetry. Thermogravimetry studies revealed that the BF3 doping improved the thermal stability of tetraaniline. |
| format | Article |
| id | doaj-art-ed440a239e424d8da9203f02240fbaaf |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-ed440a239e424d8da9203f02240fbaaf2025-02-03T01:28:45ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01931085109010.1155/2012/392718Synthesis and Characterization of a Novel Class of Lewis Acid Doped TetraanilineK. Basavaiah0A. V. Prasada Rao1Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam-530003, IndiaDepartment of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam-530003, IndiaBoron trifluoride (BF3) doped tetraaniline with novel structure were successfully synthesized via two step method. In the first step, emeraldine base form tetraaniline was synthesized via oxidative chemical polymerization of N-phenyl-1, 4-phenylenediamine using ammonium persulphate as oxidant. In the second step involves control BF3 doping of tetraaniline using boron trifluoride etherate. As synthesized BF3 doped tetraaniline have been well characterized by UV-Visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction patterns (XRD), and scanning electron microscopy (SEM) and thermogravimetry. Thermogravimetry studies revealed that the BF3 doping improved the thermal stability of tetraaniline.http://dx.doi.org/10.1155/2012/392718 |
| spellingShingle | K. Basavaiah A. V. Prasada Rao Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline E-Journal of Chemistry |
| title | Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline |
| title_full | Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline |
| title_fullStr | Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline |
| title_full_unstemmed | Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline |
| title_short | Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline |
| title_sort | synthesis and characterization of a novel class of lewis acid doped tetraaniline |
| url | http://dx.doi.org/10.1155/2012/392718 |
| work_keys_str_mv | AT kbasavaiah synthesisandcharacterizationofanovelclassoflewisaciddopedtetraaniline AT avprasadarao synthesisandcharacterizationofanovelclassoflewisaciddopedtetraaniline |