Spatial Distribution of Tropospheric Ozone in National Parks of California: Interpretation of Passive-Sampler Data

The National Park Service (NPS) has tested and used passive ozone samplers for several years to get baseline values for parks and to determine the spatial variability within parks. Experience has shown that the Ogawa passive samplers can provide ±10% accuracy when used with a quality assurance progr...

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Main Author: John D. Ray
Format: Article
Language:English
Published: Wiley 2001-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1100/tsw.2001.83
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author John D. Ray
author_facet John D. Ray
author_sort John D. Ray
collection DOAJ
description The National Park Service (NPS) has tested and used passive ozone samplers for several years to get baseline values for parks and to determine the spatial variability within parks. Experience has shown that the Ogawa passive samplers can provide ±10% accuracy when used with a quality assurance program consisting of blanks, duplicates, collocated instrumentation, and a standard operating procedure that carefully guides site operators. Although the passive device does not meet EPA criteria as a certified method (mainly, that hourly values be measured), it does provide seasonal summed values of ozone. The seasonal ozone concentrations from the passive devices can be compared to other monitoring to determine baseline values, trends, and spatial variations. This point is illustrated with some kriged interpolation maps of ozone statistics. Passive ozone samplers were used to get elevational gradients and spatial distributions of ozone within a park. This was done in varying degrees at Mount Rainier, Olympic, Sequoia–Kings Canyon, Yosemite, Joshua Tree, Rocky Mountain, and Great Smoky Mountains national parks. The ozone has been found to vary by factors of 2 and 3 within a park when average ozone is compared between locations. Specific examples of the spatial distributions of ozone in three parks within California are given using interpolation maps. Positive aspects and limitations of the passive sampling approach are presented.
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spelling doaj-art-ed20e554f75d4d4c89bfc7615114d7d82025-02-03T01:02:05ZengWileyThe Scientific World Journal1537-744X2001-01-01148349710.1100/tsw.2001.83Spatial Distribution of Tropospheric Ozone in National Parks of California: Interpretation of Passive-Sampler DataJohn D. Ray0National Park Service, Air Resources Division, 12795 W. Alameda Parkway, P.O. Box 25287, Denver, CO 80225-0287, USAThe National Park Service (NPS) has tested and used passive ozone samplers for several years to get baseline values for parks and to determine the spatial variability within parks. Experience has shown that the Ogawa passive samplers can provide ±10% accuracy when used with a quality assurance program consisting of blanks, duplicates, collocated instrumentation, and a standard operating procedure that carefully guides site operators. Although the passive device does not meet EPA criteria as a certified method (mainly, that hourly values be measured), it does provide seasonal summed values of ozone. The seasonal ozone concentrations from the passive devices can be compared to other monitoring to determine baseline values, trends, and spatial variations. This point is illustrated with some kriged interpolation maps of ozone statistics. Passive ozone samplers were used to get elevational gradients and spatial distributions of ozone within a park. This was done in varying degrees at Mount Rainier, Olympic, Sequoia–Kings Canyon, Yosemite, Joshua Tree, Rocky Mountain, and Great Smoky Mountains national parks. The ozone has been found to vary by factors of 2 and 3 within a park when average ozone is compared between locations. Specific examples of the spatial distributions of ozone in three parks within California are given using interpolation maps. Positive aspects and limitations of the passive sampling approach are presented.http://dx.doi.org/10.1100/tsw.2001.83
spellingShingle John D. Ray
Spatial Distribution of Tropospheric Ozone in National Parks of California: Interpretation of Passive-Sampler Data
The Scientific World Journal
title Spatial Distribution of Tropospheric Ozone in National Parks of California: Interpretation of Passive-Sampler Data
title_full Spatial Distribution of Tropospheric Ozone in National Parks of California: Interpretation of Passive-Sampler Data
title_fullStr Spatial Distribution of Tropospheric Ozone in National Parks of California: Interpretation of Passive-Sampler Data
title_full_unstemmed Spatial Distribution of Tropospheric Ozone in National Parks of California: Interpretation of Passive-Sampler Data
title_short Spatial Distribution of Tropospheric Ozone in National Parks of California: Interpretation of Passive-Sampler Data
title_sort spatial distribution of tropospheric ozone in national parks of california interpretation of passive sampler data
url http://dx.doi.org/10.1100/tsw.2001.83
work_keys_str_mv AT johndray spatialdistributionoftroposphericozoneinnationalparksofcaliforniainterpretationofpassivesamplerdata