Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media
Resorcinol–formaldehyde resin (RFR) was synthesized as a porous material characterized by specific surface area of 140 m 2 /g and pore volume of 0.59 cm 3 /g with major proportions of broad mesopores and macropores. The interfacial behavior of water at low (h = 0.05 g of water/gram of dry RFR) and h...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2014-12-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263-6174.32.10.845 |
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| author | Vladimir M. Gun'ko Vladimir V. Turov Viktor M. Bogatyrov Jadwiga Skubiszewska-Zięba Barbara Charmas |
| author_facet | Vladimir M. Gun'ko Vladimir V. Turov Viktor M. Bogatyrov Jadwiga Skubiszewska-Zięba Barbara Charmas |
| author_sort | Vladimir M. Gun'ko |
| collection | DOAJ |
| description | Resorcinol–formaldehyde resin (RFR) was synthesized as a porous material characterized by specific surface area of 140 m 2 /g and pore volume of 0.59 cm 3 /g with major proportions of broad mesopores and macropores. The interfacial behavior of water at low (h = 0.05 g of water/gram of dry RFR) and high (h = 2 g/g) hydration degrees depends on temperature and pore size filled by unfrozen water because its freezing-point depression increases in narrower pores. When water is mixed with co-adsorbates, the effects of such co-adsorbates as non-polar, weakly polar and polar organics depend on the amounts and the pore sizes. Even at a low hydration degree (h = 0.05 g/g), a portion of water can be displaced from pores by organic co-adsorbates because water has a relatively weak interaction with the RFR surface. |
| format | Article |
| id | doaj-art-ec39bc89167744adb721442ec1ecc439 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2014-12-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-ec39bc89167744adb721442ec1ecc4392025-02-03T10:08:00ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382014-12-013210.1260/0263-6174.32.10.845Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic MediaVladimir M. Gun'ko0Vladimir V. Turov1Viktor M. Bogatyrov2Jadwiga Skubiszewska-Zięba3Barbara Charmas4 Chuiko Institute of Surface Chemistry, 17 General Naumov Street, Kyiv 03164, Ukraine Chuiko Institute of Surface Chemistry, 17 General Naumov Street, Kyiv 03164, Ukraine Chuiko Institute of Surface Chemistry, 17 General Naumov Street, Kyiv 03164, Ukraine Faculty of Chemistry, Maria Curie-Skłodowska University, Lublin 20031, Poland Faculty of Chemistry, Maria Curie-Skłodowska University, Lublin 20031, PolandResorcinol–formaldehyde resin (RFR) was synthesized as a porous material characterized by specific surface area of 140 m 2 /g and pore volume of 0.59 cm 3 /g with major proportions of broad mesopores and macropores. The interfacial behavior of water at low (h = 0.05 g of water/gram of dry RFR) and high (h = 2 g/g) hydration degrees depends on temperature and pore size filled by unfrozen water because its freezing-point depression increases in narrower pores. When water is mixed with co-adsorbates, the effects of such co-adsorbates as non-polar, weakly polar and polar organics depend on the amounts and the pore sizes. Even at a low hydration degree (h = 0.05 g/g), a portion of water can be displaced from pores by organic co-adsorbates because water has a relatively weak interaction with the RFR surface.https://doi.org/10.1260/0263-6174.32.10.845 |
| spellingShingle | Vladimir M. Gun'ko Vladimir V. Turov Viktor M. Bogatyrov Jadwiga Skubiszewska-Zięba Barbara Charmas Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media Adsorption Science & Technology |
| title | Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media |
| title_full | Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media |
| title_fullStr | Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media |
| title_full_unstemmed | Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media |
| title_short | Textural Characteristics of Resorcinol—Formaldehyde Resin and Temperature Behavior of Bound Water Affected by Co-Adsorbed Trifluoroacetic Acid or Pyridine in Weakly Polar Organic Media |
| title_sort | textural characteristics of resorcinol formaldehyde resin and temperature behavior of bound water affected by co adsorbed trifluoroacetic acid or pyridine in weakly polar organic media |
| url | https://doi.org/10.1260/0263-6174.32.10.845 |
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