Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide
Microporous polyurethanes (MPU) were modified by adding 0.25%–1.25 wt% of reduced graphene oxide (RGO). The materials were prepared without solvent via in situ polymerization. From a technological point of view, it is very important to obtain functional materials by using reacting compounds only. Th...
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Wiley
2016-01-01
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Series: | International Journal of Polymer Science |
Online Access: | http://dx.doi.org/10.1155/2016/8070327 |
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author | Michał Strankowski Damian Włodarczyk Łukasz Piszczyk Justyna Strankowska |
author_facet | Michał Strankowski Damian Włodarczyk Łukasz Piszczyk Justyna Strankowska |
author_sort | Michał Strankowski |
collection | DOAJ |
description | Microporous polyurethanes (MPU) were modified by adding 0.25%–1.25 wt% of reduced graphene oxide (RGO). The materials were prepared without solvent via in situ polymerization. From a technological point of view, it is very important to obtain functional materials by using reacting compounds only. The thermal characteristics of obtained MPU were investigated using TGA, DSC, and DMA techniques. In comparison to nonmodified microporous polyurethane, the thermal stability and mechanical properties of the modified systems have significantly improved. The temperature corresponding to the maximum degradation rate (Tmax) for nanocomposites containing 1% and 1.25 wt% of RGO was 51°C higher than that observed for pure microporous PU system. The increase of tensile strength was also observed for matrix with the addition of 0.5 wt% RGO nanofiller. |
format | Article |
id | doaj-art-ec0fc0dab73d47648d8b9a8cc671de09 |
institution | Kabale University |
issn | 1687-9422 1687-9430 |
language | English |
publishDate | 2016-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Polymer Science |
spelling | doaj-art-ec0fc0dab73d47648d8b9a8cc671de092025-02-03T05:52:10ZengWileyInternational Journal of Polymer Science1687-94221687-94302016-01-01201610.1155/2016/80703278070327Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene OxideMichał Strankowski0Damian Włodarczyk1Łukasz Piszczyk2Justyna Strankowska3Department of Polymer Technology, Chemical Faculty, Gdańsk University of Technology, G. Narutowicza 11/12, 80-233 Gdańsk, PolandDepartment of Polymer Technology, Chemical Faculty, Gdańsk University of Technology, G. Narutowicza 11/12, 80-233 Gdańsk, PolandDepartment of Polymer Technology, Chemical Faculty, Gdańsk University of Technology, G. Narutowicza 11/12, 80-233 Gdańsk, PolandInstitute of Experimental Physics, Faculty of Mathematics, Physics and Informatics, University of Gdańsk, W. Stwosza 57, 80-308 Gdańsk, PolandMicroporous polyurethanes (MPU) were modified by adding 0.25%–1.25 wt% of reduced graphene oxide (RGO). The materials were prepared without solvent via in situ polymerization. From a technological point of view, it is very important to obtain functional materials by using reacting compounds only. The thermal characteristics of obtained MPU were investigated using TGA, DSC, and DMA techniques. In comparison to nonmodified microporous polyurethane, the thermal stability and mechanical properties of the modified systems have significantly improved. The temperature corresponding to the maximum degradation rate (Tmax) for nanocomposites containing 1% and 1.25 wt% of RGO was 51°C higher than that observed for pure microporous PU system. The increase of tensile strength was also observed for matrix with the addition of 0.5 wt% RGO nanofiller.http://dx.doi.org/10.1155/2016/8070327 |
spellingShingle | Michał Strankowski Damian Włodarczyk Łukasz Piszczyk Justyna Strankowska Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide International Journal of Polymer Science |
title | Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide |
title_full | Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide |
title_fullStr | Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide |
title_full_unstemmed | Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide |
title_short | Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide |
title_sort | thermal and mechanical properties of microporous polyurethanes modified with reduced graphene oxide |
url | http://dx.doi.org/10.1155/2016/8070327 |
work_keys_str_mv | AT michałstrankowski thermalandmechanicalpropertiesofmicroporouspolyurethanesmodifiedwithreducedgrapheneoxide AT damianwłodarczyk thermalandmechanicalpropertiesofmicroporouspolyurethanesmodifiedwithreducedgrapheneoxide AT łukaszpiszczyk thermalandmechanicalpropertiesofmicroporouspolyurethanesmodifiedwithreducedgrapheneoxide AT justynastrankowska thermalandmechanicalpropertiesofmicroporouspolyurethanesmodifiedwithreducedgrapheneoxide |