A New Transformation Method of the T<sub>2</sub> Spectrum Based on Ordered Clustering—A Case Study on the Pore-Throat Utilization Rule of Supercritical CO<sub>2</sub> Flooding in Low Permeability Cores

Nuclear magnetic resonance (NMR) and high-pressure mercury injection (HPMI) have been widely used as common characterization methods of pore-throat. It is generally believed that there is a power function relationship between transverse relaxation time (T<sub>2</sub>) and pore-throat rad...

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Main Authors: Yanchun Su, Chunhua Zhao, Xianjie Li, Xiujun Wang, Jian Zhang, Bo Huang, Xiaofeng Tian, Mingxi Liu, Kaoping Song
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/2/730
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Summary:Nuclear magnetic resonance (NMR) and high-pressure mercury injection (HPMI) have been widely used as common characterization methods of pore-throat. It is generally believed that there is a power function relationship between transverse relaxation time (T<sub>2</sub>) and pore-throat radius (r), but the segmentation process of the pore-throat interval is subjective, which affects the conversion accuracy. In this paper, ordered clustering is used to improve the existing segmentation method of the pore-throat interval, eliminate the subjectivity in the segmentation process, and obtain a more accurate distribution curve of the pore-throat. For the three kinds of cores with ordinary-low permeability (K > 1 mD), ultra-low permeability (0.1 mD < K < 1 mD), and super-low permeability (K < 0.1 mD), the pore-throat distribution curves of the cores were obtained by using the improved T<sub>2</sub> conversion method. Then, the oil and gas two-phase displacement experiment was carried out to investigate the degree of recovery and cumulative gas–oil ratio changes during the displacement process. Finally, the converted T<sub>2</sub> spectrum was used to quantify the utilization of different pore sizes. The improved T<sub>2</sub> conversion method not only has better accuracy but also is not limited by the pore-throat distribution types (such as unimodal, bimodal, and multi-modal, etc.) and is suitable for any core with measured HPMI pore-throat distribution and an NMR T<sub>2</sub> spectrum. Combined with the results of core displacement and the degree of pore-throat utilization, it is found that the potential of miscible flooding to improve the recovery degree is in the order of ordinary-low permeability core (18–22%), ultra-low permeability core (25–29%), and super-low permeability core (8–12%). The utilization degree of immiscible flooding to the <10 nm pore-throat is low (up to 35%), while miscible flooding can effectively use the <3.7 nm pore-throat (up to 73%). The development effect of supercritical CO<sub>2</sub> flooding on K < 0.1 mD reservoirs is not good, the seepage resistance of CO<sub>2</sub> is large, the miscible flooding makes it difficult to improve the recovery degree, and the utilization effect of pore-throat is poor.
ISSN:2076-3417