Unexpected temperature dependence of 1H paramagnetic shift in MAS NMR of nickelocene

Unexpected temperature dependence of 1H paramagnetic shift in MAS NMR of nickelocene

This work revisits the temperature dependence of 1H paramagnetic shift in nickelocene as a potential nuclear magnetic resonance (NMR) thermometer under fast magic angle spinning (MAS) rate. Surprisingly, an abnormal temperature dependence of 1H paramagnetic shift has been observed. In addition to a...

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Bibliographic Details
Main Authors: Xinbiao Jiang, Jiefan Liu, Xiaobing Lou, Bingwen Hu, Ming Shen
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2024-11-01
Series:Magnetic Resonance Letters
Subjects:
Solid-state NMR
NMR thermometer
Paramagnetic NMR
Paramagnetic shift
Online Access:http://www.sciencedirect.com/science/article/pii/S2772516224000263
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