Application of chromato-mass spectrometry to determine the acid composition of transformer oil
This article presents the results of a study of the acid composition of transformer oil from high-voltage transformers that have been in operation for more than 30 years. The acid composition of oils is studied using a new technique based on a highly sensitive and highly selective analysis meth...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Omsk State Technical University, Federal State Autonoumos Educational Institution of Higher Education
2023-02-01
|
| Series: | Омский научный вестник |
| Subjects: | |
| Online Access: | https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2023/%E2%84%961%20(185)%20(%D0%9E%D0%9D%D0%92)/109-113%20%20%D0%9B%D1%8E%D1%82%D0%B8%D0%BA%D0%BE%D0%B2%D0%B0%20%D0%9C.%20%D0%9D.,%20%D0%9A%D0%BE%D1%80%D0%BE%D0%B1%D0%B5%D0%B9%D0%BD%D0%B8%D0%BA%D0%BE%D0%B2%20%D0%A1.%20%D0%9C.,%20%D0%A0%D0%B8%D0%B4%D0%B5%D0%BB%D1%8C%20%D0%90.%20%D0%92.%20.pdf |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832568949498183680 |
|---|---|
| author | M. N. Lyutikova S. M. Korobeynikov A. V. Ridel |
| author_facet | M. N. Lyutikova S. M. Korobeynikov A. V. Ridel |
| author_sort | M. N. Lyutikova |
| collection | DOAJ |
| description | This article presents the results of a study of the acid
composition of transformer oil from high-voltage
transformers that have been in operation for more than
30 years. The acid composition of oils is studied using
a new technique based on a highly sensitive and highly
selective analysis method — chromato-mass spectrometry.
The technique makes it possible to determine the acid
composition of the insulating oil in the context of low
molecular weight acids (LMA), high molecular weight
acids (HMA) and phenolic compounds (PC). The structure
of some compounds identified in oil is given. It has
been established that during oil aging, among the acid
compounds, the following are predominantly formed:
HMA (60–95 %) > PC (3–16 %) > LMA (1–6 %). As
part of the research, it is found that the share of the most
dangerous low molecular weight acids in the total amount
of acidic compounds is no more than 12 %. The rest of the
acidity of the oil is due to the presence of macromolecular
and phenolic compounds, which do not adversely
affect the insulating properties of oil and paper in the
detected concentrations, and some of them (compounds
of a phenolic nature), on the contrary, even improve the
stability against oxidation. These extended tests of oil
samples from operating high-voltage equipment are of
practical value in preventive diagnostics of the condition
of its insulation. |
| format | Article |
| id | doaj-art-eafc15aea8664079aa7bd4f1ed459c03 |
| institution | Kabale University |
| issn | 1813-8225 2541-7541 |
| language | English |
| publishDate | 2023-02-01 |
| publisher | Omsk State Technical University, Federal State Autonoumos Educational Institution of Higher Education |
| record_format | Article |
| series | Омский научный вестник |
| spelling | doaj-art-eafc15aea8664079aa7bd4f1ed459c032025-02-02T23:55:34ZengOmsk State Technical University, Federal State Autonoumos Educational Institution of Higher EducationОмский научный вестник1813-82252541-75412023-02-011 (185)10911310.25206/1813-8225-2023-185-109-113Application of chromato-mass spectrometry to determine the acid composition of transformer oilM. N. Lyutikova0https://orcid.org/0000-0002-0824-9025S. M. Korobeynikov1https://orcid.org/0000-0001-7581-5042A. V. Ridel2https://orcid.org/0000-0002-5385-2237Novosibirsk State Technical UniversityNovosibirsk State Technical UniversityNovosibirsk State Technical UniversityThis article presents the results of a study of the acid composition of transformer oil from high-voltage transformers that have been in operation for more than 30 years. The acid composition of oils is studied using a new technique based on a highly sensitive and highly selective analysis method — chromato-mass spectrometry. The technique makes it possible to determine the acid composition of the insulating oil in the context of low molecular weight acids (LMA), high molecular weight acids (HMA) and phenolic compounds (PC). The structure of some compounds identified in oil is given. It has been established that during oil aging, among the acid compounds, the following are predominantly formed: HMA (60–95 %) > PC (3–16 %) > LMA (1–6 %). As part of the research, it is found that the share of the most dangerous low molecular weight acids in the total amount of acidic compounds is no more than 12 %. The rest of the acidity of the oil is due to the presence of macromolecular and phenolic compounds, which do not adversely affect the insulating properties of oil and paper in the detected concentrations, and some of them (compounds of a phenolic nature), on the contrary, even improve the stability against oxidation. These extended tests of oil samples from operating high-voltage equipment are of practical value in preventive diagnostics of the condition of its insulation. https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2023/%E2%84%961%20(185)%20(%D0%9E%D0%9D%D0%92)/109-113%20%20%D0%9B%D1%8E%D1%82%D0%B8%D0%BA%D0%BE%D0%B2%D0%B0%20%D0%9C.%20%D0%9D.,%20%D0%9A%D0%BE%D1%80%D0%BE%D0%B1%D0%B5%D0%B9%D0%BD%D0%B8%D0%BA%D0%BE%D0%B2%20%D0%A1.%20%D0%9C.,%20%D0%A0%D0%B8%D0%B4%D0%B5%D0%BB%D1%8C%20%D0%90.%20%D0%92.%20.pdfpetroleum-based insulating oilacid compositiongas chromatography-mass spectrometryhigh-voltage transformer |
| spellingShingle | M. N. Lyutikova S. M. Korobeynikov A. V. Ridel Application of chromato-mass spectrometry to determine the acid composition of transformer oil Омский научный вестник petroleum-based insulating oil acid composition gas chromatography-mass spectrometry high-voltage transformer |
| title | Application of chromato-mass spectrometry to determine the acid composition of transformer oil |
| title_full | Application of chromato-mass spectrometry to determine the acid composition of transformer oil |
| title_fullStr | Application of chromato-mass spectrometry to determine the acid composition of transformer oil |
| title_full_unstemmed | Application of chromato-mass spectrometry to determine the acid composition of transformer oil |
| title_short | Application of chromato-mass spectrometry to determine the acid composition of transformer oil |
| title_sort | application of chromato mass spectrometry to determine the acid composition of transformer oil |
| topic | petroleum-based insulating oil acid composition gas chromatography-mass spectrometry high-voltage transformer |
| url | https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2023/%E2%84%961%20(185)%20(%D0%9E%D0%9D%D0%92)/109-113%20%20%D0%9B%D1%8E%D1%82%D0%B8%D0%BA%D0%BE%D0%B2%D0%B0%20%D0%9C.%20%D0%9D.,%20%D0%9A%D0%BE%D1%80%D0%BE%D0%B1%D0%B5%D0%B9%D0%BD%D0%B8%D0%BA%D0%BE%D0%B2%20%D0%A1.%20%D0%9C.,%20%D0%A0%D0%B8%D0%B4%D0%B5%D0%BB%D1%8C%20%D0%90.%20%D0%92.%20.pdf |
| work_keys_str_mv | AT mnlyutikova applicationofchromatomassspectrometrytodeterminetheacidcompositionoftransformeroil AT smkorobeynikov applicationofchromatomassspectrometrytodeterminetheacidcompositionoftransformeroil AT avridel applicationofchromatomassspectrometrytodeterminetheacidcompositionoftransformeroil |