Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring with NCIMs (Nano–Crystallite Insertion–Materials)
A new family of insertion-compound electrodes, so called NCIMs (Nano-Crystallite-Insertion-Materials) has been proposed: the major requirement is that the electrode materials have to be polycrystalline with a crystallite and particle size as small as possible (the accepted definition being that many...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
1995-01-01
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| Series: | Active and Passive Electronic Components |
| Online Access: | http://dx.doi.org/10.1155/1995/86802 |
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| author | S. D. Han N. Treuil G. Campet J. Portier C. Delmas J. C. Lassègues A. Pierre |
| author_facet | S. D. Han N. Treuil G. Campet J. Portier C. Delmas J. C. Lassègues A. Pierre |
| author_sort | S. D. Han |
| collection | DOAJ |
| description | A new family of insertion-compound electrodes, so called NCIMs (Nano-Crystallite-Insertion-Materials) has been proposed: the major requirement is that the electrode materials have to be polycrystalline with a crystallite and particle size as small as possible (the accepted definition being that many
crystallites make a particle). Indeed, by minimizing the size of the crystallites, the formation of defects
is favored, particularly at the crystallite surface, acting as reversible (de)grafting sites of Li+. Also, the
cation-anion bonding is weakened not only in the grain boundary region but also within the crystallite
close to its surface: then the electrochemical insertion of Li+ takes place through easy bonding
rearrangements. |
| format | Article |
| id | doaj-art-eaa58641d38a41898e557e866d030531 |
| institution | Kabale University |
| issn | 0882-7516 1563-5031 |
| language | English |
| publishDate | 1995-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Active and Passive Electronic Components |
| spelling | doaj-art-eaa58641d38a41898e557e866d0305312025-02-03T01:31:49ZengWileyActive and Passive Electronic Components0882-75161563-50311995-01-01181697210.1155/1995/86802Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring with NCIMs (Nano–Crystallite Insertion–Materials)S. D. Han0N. Treuil1G. Campet2J. Portier3C. Delmas4J. C. Lassègues5A. Pierre6Laboratoire de Chimie du Solide du CNRS , 351 cours de la Libération, Talence 33405, FranceLaboratoire de Chimie du Solide du CNRS , 351 cours de la Libération, Talence 33405, FranceLaboratoire de Chimie du Solide du CNRS , 351 cours de la Libération, Talence 33405, FranceLaboratoire de Chimie du Solide du CNRS , 351 cours de la Libération, Talence 33405, FranceLaboratoire de Chimie du Solide du CNRS , 351 cours de la Libération, Talence 33405, FranceLaboratoire de Spectroscopie Moléculaire et Cristalline du CNRS , 351 cours de la Libération, Talence 33405, FranceDepartment of Mining-Metallurgical and Petroleum Engineering , University of Alberta-Edmonton-Alberta, T6G-2G6, CanadaA new family of insertion-compound electrodes, so called NCIMs (Nano-Crystallite-Insertion-Materials) has been proposed: the major requirement is that the electrode materials have to be polycrystalline with a crystallite and particle size as small as possible (the accepted definition being that many crystallites make a particle). Indeed, by minimizing the size of the crystallites, the formation of defects is favored, particularly at the crystallite surface, acting as reversible (de)grafting sites of Li+. Also, the cation-anion bonding is weakened not only in the grain boundary region but also within the crystallite close to its surface: then the electrochemical insertion of Li+ takes place through easy bonding rearrangements.http://dx.doi.org/10.1155/1995/86802 |
| spellingShingle | S. D. Han N. Treuil G. Campet J. Portier C. Delmas J. C. Lassègues A. Pierre Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring with NCIMs (Nano–Crystallite Insertion–Materials) Active and Passive Electronic Components |
| title | Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring with NCIMs
(Nano–Crystallite
Insertion–Materials) |
| title_full | Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring with NCIMs
(Nano–Crystallite
Insertion–Materials) |
| title_fullStr | Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring with NCIMs
(Nano–Crystallite
Insertion–Materials) |
| title_full_unstemmed | Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring with NCIMs
(Nano–Crystallite
Insertion–Materials) |
| title_short | Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring with NCIMs
(Nano–Crystallite
Insertion–Materials) |
| title_sort | mechanisms of the reversible electrochemical insertion of lithium occurring with ncims nano crystallite insertion materials |
| url | http://dx.doi.org/10.1155/1995/86802 |
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