Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture
A new microporous porphyrin-based imide linked polymer, PyP, was synthesized in an m-cresol/isoquinoline mixture between a porphyrin and a naphthalene tetra-carboxylic dianhydride. The resultant amorphous polymer demonstrates a moderate surface area (SBET = 428 m2 g−1) and CO2 adsorption ability (3....
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| Format: | Article |
| Language: | English |
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Wiley
2015-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2015/281616 |
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| _version_ | 1832561811278266368 |
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| author | Venkata S. Pavan K. Neti Jun Wang Shuguang Deng Luis Echegoyen |
| author_facet | Venkata S. Pavan K. Neti Jun Wang Shuguang Deng Luis Echegoyen |
| author_sort | Venkata S. Pavan K. Neti |
| collection | DOAJ |
| description | A new microporous porphyrin-based imide linked polymer, PyP, was synthesized in an m-cresol/isoquinoline mixture between a porphyrin and a naphthalene tetra-carboxylic dianhydride. The resultant amorphous polymer demonstrates a moderate surface area (SBET = 428 m2 g−1) and CO2 adsorption ability (3.5 wt%) and a CO2/CH4 selectivity of 5.6 at 273 K/1 bar. |
| format | Article |
| id | doaj-art-e9fc40cc2d604323b8d712122309f27e |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2015-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-e9fc40cc2d604323b8d712122309f27e2025-02-03T01:24:19ZengWileyJournal of Chemistry2090-90632090-90712015-01-01201510.1155/2015/281616281616Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 CaptureVenkata S. Pavan K. Neti0Jun Wang1Shuguang Deng2Luis Echegoyen3Department of Chemistry, University of Texas at El Paso, El Paso, TX 79968, USADepartment of Chemical Engineering, New Mexico State University, Las Cruces, NM 88003, USADepartment of Chemical Engineering, New Mexico State University, Las Cruces, NM 88003, USADepartment of Chemistry, University of Texas at El Paso, El Paso, TX 79968, USAA new microporous porphyrin-based imide linked polymer, PyP, was synthesized in an m-cresol/isoquinoline mixture between a porphyrin and a naphthalene tetra-carboxylic dianhydride. The resultant amorphous polymer demonstrates a moderate surface area (SBET = 428 m2 g−1) and CO2 adsorption ability (3.5 wt%) and a CO2/CH4 selectivity of 5.6 at 273 K/1 bar.http://dx.doi.org/10.1155/2015/281616 |
| spellingShingle | Venkata S. Pavan K. Neti Jun Wang Shuguang Deng Luis Echegoyen Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture Journal of Chemistry |
| title | Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture |
| title_full | Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture |
| title_fullStr | Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture |
| title_full_unstemmed | Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture |
| title_short | Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture |
| title_sort | synthesis of a polyimide porous porphyrin polymer for selective co2 capture |
| url | http://dx.doi.org/10.1155/2015/281616 |
| work_keys_str_mv | AT venkataspavankneti synthesisofapolyimideporousporphyrinpolymerforselectiveco2capture AT junwang synthesisofapolyimideporousporphyrinpolymerforselectiveco2capture AT shuguangdeng synthesisofapolyimideporousporphyrinpolymerforselectiveco2capture AT luisechegoyen synthesisofapolyimideporousporphyrinpolymerforselectiveco2capture |