Study on the Adsorption Kinetics of Acid Red 3B on Expanded Graphite

Expanded graphite (EG) is a kind of important adsorbent for organic compound such as oil and dyes. We have investigated the adsorption kinetics characteristics of this adsorbent for dye. EG was prepared with 50 mesh crude graphite through chemical oxidation intercalation of potassium permanganate an...

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Main Authors: Xiu-yan Pang, Fei Gong
Format: Article
Language:English
Published: Wiley 2008-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2008/786025
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author Xiu-yan Pang
Fei Gong
author_facet Xiu-yan Pang
Fei Gong
author_sort Xiu-yan Pang
collection DOAJ
description Expanded graphite (EG) is a kind of important adsorbent for organic compound such as oil and dyes. We have investigated the adsorption kinetics characteristics of this adsorbent for dye. EG was prepared with 50 mesh crude graphite through chemical oxidation intercalation of potassium permanganate and vitriol, and dye of acid red 3B was used as model sorbate. We have studied the adsorption kinetic models and rate-limiting step of the process. Adsorption rate and activation energy of the adsorption process were calculated. Kinetic studies show that the kinetic data are well described by the pseudo second-order kinetic model. The equilibrium adsorbance increases with the increase of the initial acid red 3B concentration. Initial adsorption rate increases with the increase of the initial dye concentration and temperature. Adsorption process of acid red 3B on EG has small activation energy. Internal diffusion appears to be the rate-limiting step for the adsorption process.
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institution Kabale University
issn 0973-4945
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language English
publishDate 2008-01-01
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series E-Journal of Chemistry
spelling doaj-art-e9c32da89b494a38b03cf68b379976de2025-02-03T05:51:43ZengWileyE-Journal of Chemistry0973-49452090-98102008-01-015480280910.1155/2008/786025Study on the Adsorption Kinetics of Acid Red 3B on Expanded GraphiteXiu-yan Pang0Fei Gong1College of Chemistry and Environmental Science, Hebei University, Baoding, 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Baoding, 071002, ChinaExpanded graphite (EG) is a kind of important adsorbent for organic compound such as oil and dyes. We have investigated the adsorption kinetics characteristics of this adsorbent for dye. EG was prepared with 50 mesh crude graphite through chemical oxidation intercalation of potassium permanganate and vitriol, and dye of acid red 3B was used as model sorbate. We have studied the adsorption kinetic models and rate-limiting step of the process. Adsorption rate and activation energy of the adsorption process were calculated. Kinetic studies show that the kinetic data are well described by the pseudo second-order kinetic model. The equilibrium adsorbance increases with the increase of the initial acid red 3B concentration. Initial adsorption rate increases with the increase of the initial dye concentration and temperature. Adsorption process of acid red 3B on EG has small activation energy. Internal diffusion appears to be the rate-limiting step for the adsorption process.http://dx.doi.org/10.1155/2008/786025
spellingShingle Xiu-yan Pang
Fei Gong
Study on the Adsorption Kinetics of Acid Red 3B on Expanded Graphite
E-Journal of Chemistry
title Study on the Adsorption Kinetics of Acid Red 3B on Expanded Graphite
title_full Study on the Adsorption Kinetics of Acid Red 3B on Expanded Graphite
title_fullStr Study on the Adsorption Kinetics of Acid Red 3B on Expanded Graphite
title_full_unstemmed Study on the Adsorption Kinetics of Acid Red 3B on Expanded Graphite
title_short Study on the Adsorption Kinetics of Acid Red 3B on Expanded Graphite
title_sort study on the adsorption kinetics of acid red 3b on expanded graphite
url http://dx.doi.org/10.1155/2008/786025
work_keys_str_mv AT xiuyanpang studyontheadsorptionkineticsofacidred3bonexpandedgraphite
AT feigong studyontheadsorptionkineticsofacidred3bonexpandedgraphite