Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental Conditions

Indoxacarb is a broad-spectrum insecticide and widely used in agriculture. The dissipations and residues of indoxacarb were researched at three different field sites in Beijing, Hunan, and Zhejiang provinces in China. Analytical methods for determining the residue of indoxacarb in paddy water, paddy...

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Main Authors: Ying-Hong Li, Xiang-Yun Wang, Wei Hua, Hu Zhang
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Journal of Analytical Methods in Chemistry
Online Access:http://dx.doi.org/10.1155/2020/8874759
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author Ying-Hong Li
Xiang-Yun Wang
Wei Hua
Hu Zhang
author_facet Ying-Hong Li
Xiang-Yun Wang
Wei Hua
Hu Zhang
author_sort Ying-Hong Li
collection DOAJ
description Indoxacarb is a broad-spectrum insecticide and widely used in agriculture. The dissipations and residues of indoxacarb were researched at three different field sites in Beijing, Hunan, and Zhejiang provinces in China. Analytical methods for determining the residue of indoxacarb in paddy water, paddy soil, rice straw, rice hull, and brown rice were described. Indoxacarb residues were extracted from samples, cleaned up by solid phase extraction, and determined by high-performance liquid chromatography coupled with tandem mass spectrometry in the selected ion monitoring mode. The recoveries in paddy water, paddy soil, rice straw, rice hull, and brown rice matrices at three spiking levels ranged from 79.7% to 98.3%, respectively. The field and environmental conditions would affect the dissipations and residues of indoxacarb. The time to dissipate 50% of indoxacarb in paddy water, paddy soil, and rice straw was less than 9 days. The terminal residues obtained from Beijing at preharvest interval of 14 and 21 days were higher than the maximum limit of European Union. Therefore, a dosage of 24 g a. i. ha−1 at 28 days preharvest interval with 3 spraying times was recommended. Such accumulation of measured data is necessary to provide guidance for the proper and safe use of this pesticide.
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series Journal of Analytical Methods in Chemistry
spelling doaj-art-e90f25b16c8241cba1705d5e4e461cba2025-02-03T05:51:15ZengWileyJournal of Analytical Methods in Chemistry2090-88652090-88732020-01-01202010.1155/2020/88747598874759Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental ConditionsYing-Hong Li0Xiang-Yun Wang1Wei Hua2Hu Zhang3Zhejiang Institute for Food and Drug Control, NMPA Key Laboratory for Testing and Warning of Pharmceutical Microbiology, Hangzhou 310052, ChinaAgricultural Ministry Key Laboratory for Pesticide Residue Detection, Zhejiang Province Key Laboratory for Food Safety, Institute of Quality and Standard for Agro-products, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, ChinaSipcam Crop Science (Wuxi) Co Ltd., Wuxi, ChinaAgricultural Ministry Key Laboratory for Pesticide Residue Detection, Zhejiang Province Key Laboratory for Food Safety, Institute of Quality and Standard for Agro-products, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, ChinaIndoxacarb is a broad-spectrum insecticide and widely used in agriculture. The dissipations and residues of indoxacarb were researched at three different field sites in Beijing, Hunan, and Zhejiang provinces in China. Analytical methods for determining the residue of indoxacarb in paddy water, paddy soil, rice straw, rice hull, and brown rice were described. Indoxacarb residues were extracted from samples, cleaned up by solid phase extraction, and determined by high-performance liquid chromatography coupled with tandem mass spectrometry in the selected ion monitoring mode. The recoveries in paddy water, paddy soil, rice straw, rice hull, and brown rice matrices at three spiking levels ranged from 79.7% to 98.3%, respectively. The field and environmental conditions would affect the dissipations and residues of indoxacarb. The time to dissipate 50% of indoxacarb in paddy water, paddy soil, and rice straw was less than 9 days. The terminal residues obtained from Beijing at preharvest interval of 14 and 21 days were higher than the maximum limit of European Union. Therefore, a dosage of 24 g a. i. ha−1 at 28 days preharvest interval with 3 spraying times was recommended. Such accumulation of measured data is necessary to provide guidance for the proper and safe use of this pesticide.http://dx.doi.org/10.1155/2020/8874759
spellingShingle Ying-Hong Li
Xiang-Yun Wang
Wei Hua
Hu Zhang
Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental Conditions
Journal of Analytical Methods in Chemistry
title Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental Conditions
title_full Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental Conditions
title_fullStr Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental Conditions
title_full_unstemmed Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental Conditions
title_short Studies on Dissipations and Residues of Indoxacarb under Different Field and Environmental Conditions
title_sort studies on dissipations and residues of indoxacarb under different field and environmental conditions
url http://dx.doi.org/10.1155/2020/8874759
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AT xiangyunwang studiesondissipationsandresiduesofindoxacarbunderdifferentfieldandenvironmentalconditions
AT weihua studiesondissipationsandresiduesofindoxacarbunderdifferentfieldandenvironmentalconditions
AT huzhang studiesondissipationsandresiduesofindoxacarbunderdifferentfieldandenvironmentalconditions