HAUTE EFFICACITÉ D'ADSORPTION DU COLORANT BASIQUE (CRISTAL VIOLET) SUR LA MONTMORILLONITE ALGÉRIENNE HIGH EFFICIENCY ADSORPTION PERFORMANCE OF BASIC DYE (CRYSTAL VIOLET) ONTO ALGERIAN MONTMORILLONITE
The Algerian montmorillonite clay in raw and purified form was evaluated as adsorbent for Crystal Violet (CV) cationic dye. The experimental results show that, the adsorption was pH independent when the adsorption capacity of CV dye was unchanged for large initial pH. The pseudo-second-order kineti...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2024-03-01
|
| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| Subjects: | |
| Online Access: | https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202401&vol=1&aid=5623 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849467470548566020 |
|---|---|
| author | NAZIHA LADJAL SMAIL TERCHI HADI DEBIH |
| author_facet | NAZIHA LADJAL SMAIL TERCHI HADI DEBIH |
| author_sort | NAZIHA LADJAL |
| collection | DOAJ |
| description | The Algerian montmorillonite clay in raw and purified form was evaluated as adsorbent for Crystal Violet (CV) cationic dye. The experimental results show that, the adsorption was pH independent when the adsorption capacity
of CV dye was unchanged for large initial pH. The pseudo-second-order kinetic
model provided the best fit to the experimental data for the adsorption of dye by both clays. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Dubinin-Radushkevich isotherm models. The best fit of experimental data was obtained by the Langmuir isotherm model. The maximum adsorption capacity of the raw clay calculated by the Langmuir isotherm model is 330 mg·g-1 at 20 °C. It is increased in fractionated sodic clay sample (381 mg·g-1). The effect of temperature on the adsorption of crystal violet was investigated. The results show that the enthalpy of adsorption of CV is negative signifying that the process is exothermic.
Physisorption is the prevailing mechanism for dye adsorption. Negative value of
entropy shows an ordering of the adsorbed dye at the surface of adsorbent
throughout the adsorption process. The negative value of ΔG° indicates the
spontaneity of adsorption process. The increase in ΔG° value when the temperature was increased indicate a decrease in feasibility and spontaneity of adsorption at higher temperatures which confirm the physisorption nature of crystal violet. |
| format | Article |
| id | doaj-art-e6eddb219abf4d2999ee7d882bc9ddb1 |
| institution | Kabale University |
| issn | 1582-540X |
| language | English |
| publishDate | 2024-03-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-e6eddb219abf4d2999ee7d882bc9ddb12025-08-20T03:26:11ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2024-03-01251001018HAUTE EFFICACITÉ D'ADSORPTION DU COLORANT BASIQUE (CRISTAL VIOLET) SUR LA MONTMORILLONITE ALGÉRIENNE HIGH EFFICIENCY ADSORPTION PERFORMANCE OF BASIC DYE (CRYSTAL VIOLET) ONTO ALGERIAN MONTMORILLONITENAZIHA LADJAL 0 SMAIL TERCHI 1HADI DEBIH 2École Normale Supérieure de Bou-Saada, M’Sila, AlgérieUniversité Mohamed Boudiaf de M’Sila, Faculté des Sciences, Laboratoire Matériaux et Energies Renouvelables. B.P. 166, Ichbilia, M’Sila, 28000, Algérie AND Université Mohamed Boudiaf de M’Sila, Faculté des Sciences, Département de Chimie, B.P. 166, Ichbilia, M’Sila, 28000, AlgérieUniversité Mohamed Boudiaf de M’Sila, Faculté des Sciences et Technologie, Laboratoire de Valorisation des Matériaux et Mécanique des Structures, B.P. 166, Ichbilia, M’Sila, 28000, AlgérieThe Algerian montmorillonite clay in raw and purified form was evaluated as adsorbent for Crystal Violet (CV) cationic dye. The experimental results show that, the adsorption was pH independent when the adsorption capacity of CV dye was unchanged for large initial pH. The pseudo-second-order kinetic model provided the best fit to the experimental data for the adsorption of dye by both clays. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Dubinin-Radushkevich isotherm models. The best fit of experimental data was obtained by the Langmuir isotherm model. The maximum adsorption capacity of the raw clay calculated by the Langmuir isotherm model is 330 mg·g-1 at 20 °C. It is increased in fractionated sodic clay sample (381 mg·g-1). The effect of temperature on the adsorption of crystal violet was investigated. The results show that the enthalpy of adsorption of CV is negative signifying that the process is exothermic. Physisorption is the prevailing mechanism for dye adsorption. Negative value of entropy shows an ordering of the adsorbed dye at the surface of adsorbent throughout the adsorption process. The negative value of ΔG° indicates the spontaneity of adsorption process. The increase in ΔG° value when the temperature was increased indicate a decrease in feasibility and spontaneity of adsorption at higher temperatures which confirm the physisorption nature of crystal violet.https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202401&vol=1&aid=5623adsorptioncationic dyesefficiencymontmorillonitethermodynamic study |
| spellingShingle | NAZIHA LADJAL SMAIL TERCHI HADI DEBIH HAUTE EFFICACITÉ D'ADSORPTION DU COLORANT BASIQUE (CRISTAL VIOLET) SUR LA MONTMORILLONITE ALGÉRIENNE HIGH EFFICIENCY ADSORPTION PERFORMANCE OF BASIC DYE (CRYSTAL VIOLET) ONTO ALGERIAN MONTMORILLONITE Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry adsorption cationic dyes efficiency montmorillonite thermodynamic study |
| title | HAUTE EFFICACITÉ D'ADSORPTION DU COLORANT BASIQUE (CRISTAL VIOLET) SUR LA MONTMORILLONITE ALGÉRIENNE HIGH EFFICIENCY ADSORPTION PERFORMANCE OF BASIC DYE (CRYSTAL VIOLET) ONTO ALGERIAN MONTMORILLONITE |
| title_full | HAUTE EFFICACITÉ D'ADSORPTION DU COLORANT BASIQUE (CRISTAL VIOLET) SUR LA MONTMORILLONITE ALGÉRIENNE HIGH EFFICIENCY ADSORPTION PERFORMANCE OF BASIC DYE (CRYSTAL VIOLET) ONTO ALGERIAN MONTMORILLONITE |
| title_fullStr | HAUTE EFFICACITÉ D'ADSORPTION DU COLORANT BASIQUE (CRISTAL VIOLET) SUR LA MONTMORILLONITE ALGÉRIENNE HIGH EFFICIENCY ADSORPTION PERFORMANCE OF BASIC DYE (CRYSTAL VIOLET) ONTO ALGERIAN MONTMORILLONITE |
| title_full_unstemmed | HAUTE EFFICACITÉ D'ADSORPTION DU COLORANT BASIQUE (CRISTAL VIOLET) SUR LA MONTMORILLONITE ALGÉRIENNE HIGH EFFICIENCY ADSORPTION PERFORMANCE OF BASIC DYE (CRYSTAL VIOLET) ONTO ALGERIAN MONTMORILLONITE |
| title_short | HAUTE EFFICACITÉ D'ADSORPTION DU COLORANT BASIQUE (CRISTAL VIOLET) SUR LA MONTMORILLONITE ALGÉRIENNE HIGH EFFICIENCY ADSORPTION PERFORMANCE OF BASIC DYE (CRYSTAL VIOLET) ONTO ALGERIAN MONTMORILLONITE |
| title_sort | haute efficacite d adsorption du colorant basique cristal violet sur la montmorillonite algerienne high efficiency adsorption performance of basic dye crystal violet onto algerian montmorillonite |
| topic | adsorption cationic dyes efficiency montmorillonite thermodynamic study |
| url | https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202401&vol=1&aid=5623 |
| work_keys_str_mv | AT nazihaladjal hauteefficacitedadsorptionducolorantbasiquecristalvioletsurlamontmorillonitealgeriennehighefficiencyadsorptionperformanceofbasicdyecrystalvioletontoalgerianmontmorillonite AT smailterchi hauteefficacitedadsorptionducolorantbasiquecristalvioletsurlamontmorillonitealgeriennehighefficiencyadsorptionperformanceofbasicdyecrystalvioletontoalgerianmontmorillonite AT hadidebih hauteefficacitedadsorptionducolorantbasiquecristalvioletsurlamontmorillonitealgeriennehighefficiencyadsorptionperformanceofbasicdyecrystalvioletontoalgerianmontmorillonite |