Layer-by-Layer Self-Assembled Graphene Multilayer Films via Covalent Bonds for Supercapacitor Electrodes
To maximize the utilization of its single-atom thin nature, a facile scheme to fabricate graphene multilayer films via a layer-by-layer self-assembled process was presented. The structure of multilayer films was constructed by covalently bonding graphene oxide (GO) using p-phenylenediamine (PPD) as...
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| Format: | Article |
| Language: | English |
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Wiley
2015-05-01
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| Series: | Nanomaterials and Nanotechnology |
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| Online Access: | http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/layer-by-layer-self-assembled-graphene-multilayer-films-via-covalent-bonds-for-supercapacitor-electr |
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| _version_ | 1832546703565127680 |
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| author | Xianbin Liu Na Wen Xiaoli Wang Yuying Zheng |
| author_facet | Xianbin Liu Na Wen Xiaoli Wang Yuying Zheng |
| author_sort | Xianbin Liu |
| collection | DOAJ |
| description | To maximize the utilization of its single-atom thin nature, a facile scheme to fabricate graphene multilayer films via a layer-by-layer self-assembled process was presented. The structure of multilayer films was constructed by covalently bonding graphene oxide (GO) using p-phenylenediamine (PPD) as a covalent cross-linking agent. The assembly process was confirmed to be repeatable and the structure was stable. With the π-π conjugated structure and a large number of spaces in the framework, the graphene multi‐ layer films exhibited excellent electrochemical perform‐ ance. The uniform ultrathin electrode exhibited a capacitance of 41.71 μF/cm2 at a discharge current of 0.1 μA/cm2, and displayed excellent stability of 88.9 % after 1000 charge-discharge cycles. |
| format | Article |
| id | doaj-art-e6a83f52badc4544987138e6cd44ddfc |
| institution | Kabale University |
| issn | 1847-9804 |
| language | English |
| publishDate | 2015-05-01 |
| publisher | Wiley |
| record_format | Article |
| series | Nanomaterials and Nanotechnology |
| spelling | doaj-art-e6a83f52badc4544987138e6cd44ddfc2025-02-03T06:47:35ZengWileyNanomaterials and Nanotechnology1847-98042015-05-01514http://dx.doi.org/10.5772/6059648418Layer-by-Layer Self-Assembled Graphene Multilayer Films via Covalent Bonds for Supercapacitor ElectrodesXianbin LiuNa WenXiaoli WangYuying ZhengTo maximize the utilization of its single-atom thin nature, a facile scheme to fabricate graphene multilayer films via a layer-by-layer self-assembled process was presented. The structure of multilayer films was constructed by covalently bonding graphene oxide (GO) using p-phenylenediamine (PPD) as a covalent cross-linking agent. The assembly process was confirmed to be repeatable and the structure was stable. With the π-π conjugated structure and a large number of spaces in the framework, the graphene multi‐ layer films exhibited excellent electrochemical perform‐ ance. The uniform ultrathin electrode exhibited a capacitance of 41.71 μF/cm2 at a discharge current of 0.1 μA/cm2, and displayed excellent stability of 88.9 % after 1000 charge-discharge cycles.http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/layer-by-layer-self-assembled-graphene-multilayer-films-via-covalent-bonds-for-supercapacitor-electrlayer-by-layer self-assemblycovalent bondgraphenecarbon materialsenergy storage and conversion |
| spellingShingle | Xianbin Liu Na Wen Xiaoli Wang Yuying Zheng Layer-by-Layer Self-Assembled Graphene Multilayer Films via Covalent Bonds for Supercapacitor Electrodes Nanomaterials and Nanotechnology layer-by-layer self-assembly covalent bond graphene carbon materials energy storage and conversion |
| title | Layer-by-Layer Self-Assembled Graphene Multilayer Films via Covalent Bonds for Supercapacitor Electrodes |
| title_full | Layer-by-Layer Self-Assembled Graphene Multilayer Films via Covalent Bonds for Supercapacitor Electrodes |
| title_fullStr | Layer-by-Layer Self-Assembled Graphene Multilayer Films via Covalent Bonds for Supercapacitor Electrodes |
| title_full_unstemmed | Layer-by-Layer Self-Assembled Graphene Multilayer Films via Covalent Bonds for Supercapacitor Electrodes |
| title_short | Layer-by-Layer Self-Assembled Graphene Multilayer Films via Covalent Bonds for Supercapacitor Electrodes |
| title_sort | layer by layer self assembled graphene multilayer films via covalent bonds for supercapacitor electrodes |
| topic | layer-by-layer self-assembly covalent bond graphene carbon materials energy storage and conversion |
| url | http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/layer-by-layer-self-assembled-graphene-multilayer-films-via-covalent-bonds-for-supercapacitor-electr |
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