Elucidating the Role of the Mixing Entropy in Equilibrated Nanoconfined Reactions
By introducing the concept of nanoreaction-based fluctuating mixing entropy, the challenge posed by the smallness of a closed molecular system is addressed through equilibrium statistical–mechanical averaging over fluctuating reaction extent. Based on the canonical partition function, the interplay...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-05-01
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| Series: | Entropy |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1099-4300/27/6/564 |
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