Digital light processing three-dimensional printing with acrylic–titanium composite powders for multiscale porous scaffolds

Porous metals fabricated via three-dimensional (3D) printing have attracted extensive attention in many fields owing to their open pores and customization potential. However, dense internal structures produced by the powder bed fusion technique fails to meet the feature of porous materials in scenar...

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Main Authors: Guangbin Zhao, Yanlong Wu, Bochen Li, Hang Tian, Bo Li, Xiao Li, Xu Chen, Tao Zhou, Yaning Wang, Yichao Gong, Dingchang Hou, Yaxiong Liu, Xuewen Zong, Bingheng Lu
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:International Journal of Extreme Manufacturing
Subjects:
Online Access:https://doi.org/10.1088/2631-7990/ada979
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author Guangbin Zhao
Yanlong Wu
Bochen Li
Hang Tian
Bo Li
Xiao Li
Xu Chen
Tao Zhou
Yaning Wang
Yichao Gong
Dingchang Hou
Yaxiong Liu
Xuewen Zong
Bingheng Lu
author_facet Guangbin Zhao
Yanlong Wu
Bochen Li
Hang Tian
Bo Li
Xiao Li
Xu Chen
Tao Zhou
Yaning Wang
Yichao Gong
Dingchang Hou
Yaxiong Liu
Xuewen Zong
Bingheng Lu
author_sort Guangbin Zhao
collection DOAJ
description Porous metals fabricated via three-dimensional (3D) printing have attracted extensive attention in many fields owing to their open pores and customization potential. However, dense internal structures produced by the powder bed fusion technique fails to meet the feature of porous materials in scenarios that demand large specific surface areas. Herein, we propose a strategy for 3D printing of titanium scaffolds featuring multiscale porous internal structures via powder modification and digital light processing (DLP). After modification, the titanium powders were composited with acrylic resin and maintained spherical shapes. Compared with the raw powder slurries, the modified powder slurries exhibited higher stability and preferable curing characteristics, and the depth sensitivity of the modified powder slurries with 45 vol% solid loading increased by approximately 72%. Green scaffolds were subsequently printed from the slurries with a solid loading reaching 45 vol% via DLP 3D printing. The scaffolds had macropores (pore diameters of approximately 1 mm) and internal open micropores (pore diameters of approximately 5.7–13.0 μ m) after sintering. Additionally, these small-featured (approximately 320 μ m) scaffolds retained sufficient compressive strength ((70.01 ± 3.53) MPa) even with high porosity (approximately 73.95%). This work can facilitate the fabrication of multiscale porous metal scaffolds with high solid loading slurries, offering potential for applications requiring high specific surface area ratios.
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series International Journal of Extreme Manufacturing
spelling doaj-art-e64ea9d8f9754cc78be9761b00ce4f952025-02-05T13:32:53ZengIOP PublishingInternational Journal of Extreme Manufacturing2631-79902025-01-017303500310.1088/2631-7990/ada979Digital light processing three-dimensional printing with acrylic–titanium composite powders for multiscale porous scaffoldsGuangbin Zhao0Yanlong Wu1Bochen Li2Hang Tian3Bo Li4Xiao Li5https://orcid.org/0000-0002-1200-8590Xu Chen6Tao Zhou7Yaning Wang8Yichao Gong9Dingchang Hou10Yaxiong Liu11https://orcid.org/0000-0002-6418-4756Xuewen Zong12Bingheng Lu13State Key Laboratory for Manufacturing System Engineering, School of Mechanical Engineering, Xi’an Jiaotong University , Xi’an 710054, People’s Republic of ChinaSchool of Mechatronic Engineering and Automation, Foshan University , Foshan 528000, People’s Republic of China; Ji Hua Laboratory , Foshan 528200, People’s Republic of ChinaSchool of Materials Science and Engineering, Xi’an University of Technology , Xi’an 710048, People’s Republic of ChinaCollege of Mechanical Engineering, Xi’an University of Science and Technology , Xi’an 710054, People’s Republic of ChinaState Key Laboratory for Manufacturing System Engineering, School of Mechanical Engineering, Xi’an Jiaotong University , Xi’an 710054, People’s Republic of ChinaState Key Laboratory for Manufacturing System Engineering, School of Mechanical Engineering, Xi’an Jiaotong University , Xi’an 710054, People’s Republic of ChinaSchool of Mechatronic Engineering and Automation, Foshan University , Foshan 528000, People’s Republic of China; Ji Hua Laboratory , Foshan 528200, People’s Republic of ChinaState Key Laboratory for Manufacturing System Engineering, School of Mechanical Engineering, Xi’an Jiaotong University , Xi’an 710054, People’s Republic of ChinaMechanical Engineering College, Xi’an Shiyou University , Xi’an 710065, People’s Republic of ChinaSchool of Materials Science and Engineering, Xi’an University of Technology , Xi’an 710048, People’s Republic of ChinaState Key Laboratory for Manufacturing System Engineering, School of Mechanical Engineering, Xi’an Jiaotong University , Xi’an 710054, People’s Republic of ChinaSchool of Mechatronic Engineering and Automation, Foshan University , Foshan 528000, People’s Republic of China; Ji Hua Laboratory , Foshan 528200, People’s Republic of ChinaCollege of Mechanical Engineering, Xi’an University of Science and Technology , Xi’an 710054, People’s Republic of ChinaState Key Laboratory for Manufacturing System Engineering, School of Mechanical Engineering, Xi’an Jiaotong University , Xi’an 710054, People’s Republic of ChinaPorous metals fabricated via three-dimensional (3D) printing have attracted extensive attention in many fields owing to their open pores and customization potential. However, dense internal structures produced by the powder bed fusion technique fails to meet the feature of porous materials in scenarios that demand large specific surface areas. Herein, we propose a strategy for 3D printing of titanium scaffolds featuring multiscale porous internal structures via powder modification and digital light processing (DLP). After modification, the titanium powders were composited with acrylic resin and maintained spherical shapes. Compared with the raw powder slurries, the modified powder slurries exhibited higher stability and preferable curing characteristics, and the depth sensitivity of the modified powder slurries with 45 vol% solid loading increased by approximately 72%. Green scaffolds were subsequently printed from the slurries with a solid loading reaching 45 vol% via DLP 3D printing. The scaffolds had macropores (pore diameters of approximately 1 mm) and internal open micropores (pore diameters of approximately 5.7–13.0 μ m) after sintering. Additionally, these small-featured (approximately 320 μ m) scaffolds retained sufficient compressive strength ((70.01 ± 3.53) MPa) even with high porosity (approximately 73.95%). This work can facilitate the fabrication of multiscale porous metal scaffolds with high solid loading slurries, offering potential for applications requiring high specific surface area ratios.https://doi.org/10.1088/2631-7990/ada979multiscale porous metaltitanium scaffoldspowder modification3D printingsintering
spellingShingle Guangbin Zhao
Yanlong Wu
Bochen Li
Hang Tian
Bo Li
Xiao Li
Xu Chen
Tao Zhou
Yaning Wang
Yichao Gong
Dingchang Hou
Yaxiong Liu
Xuewen Zong
Bingheng Lu
Digital light processing three-dimensional printing with acrylic–titanium composite powders for multiscale porous scaffolds
International Journal of Extreme Manufacturing
multiscale porous metal
titanium scaffolds
powder modification
3D printing
sintering
title Digital light processing three-dimensional printing with acrylic–titanium composite powders for multiscale porous scaffolds
title_full Digital light processing three-dimensional printing with acrylic–titanium composite powders for multiscale porous scaffolds
title_fullStr Digital light processing three-dimensional printing with acrylic–titanium composite powders for multiscale porous scaffolds
title_full_unstemmed Digital light processing three-dimensional printing with acrylic–titanium composite powders for multiscale porous scaffolds
title_short Digital light processing three-dimensional printing with acrylic–titanium composite powders for multiscale porous scaffolds
title_sort digital light processing three dimensional printing with acrylic titanium composite powders for multiscale porous scaffolds
topic multiscale porous metal
titanium scaffolds
powder modification
3D printing
sintering
url https://doi.org/10.1088/2631-7990/ada979
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