A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric properties

Copper sulfides are an interesting group of materials as they are found in various stoichiometries. Covellite (CuS), digenite (Cu _1.8 S), and chalcocite (Cu _2 S) are the three major phases of copper sulfides. Synthesis of copper sulfide nanostructures via diverse techniques such as solvothermal, p...

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Main Authors: Pooja Rawat, Shubhra Kala
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:Nano Express
Subjects:
Online Access:https://doi.org/10.1088/2632-959X/ada6e7
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author Pooja Rawat
Shubhra Kala
author_facet Pooja Rawat
Shubhra Kala
author_sort Pooja Rawat
collection DOAJ
description Copper sulfides are an interesting group of materials as they are found in various stoichiometries. Covellite (CuS), digenite (Cu _1.8 S), and chalcocite (Cu _2 S) are the three major phases of copper sulfides. Synthesis of copper sulfide nanostructures via diverse techniques such as solvothermal, pyrolytic, and high-temperature precursor injection has been done for various applications, including electrochemical capacitance, lithium storage and transdermal drug delivery. Additionally, they have been found to show promising behaviour as thermoelectric materials. Thermoelectric energy generation is a fascinating method for energy generation. It is a renewable energy source which utilizes waste heat and converts it into electrical energy, hence is of high value since renewable sources of energy are the need of the hour. Thermoelectric materials are broadly classified into three types: organic, inorganic, and hybrid. Bismuth telluride (Bi _2 Te _3 ), lead telluride (PbTe), silicon-germanium (SiGe) and their alloys are some of the most widely used thermoelectric materials. However, most of these materials are toxic, expensive and its challenging to improve their figure of merit (zT). Copper sulfides have emerged as cost-effective, less toxic alternatives to traditional thermoelectric materials, and different approaches such as doping and phase regulation of copper sulfides have been found to further enhance their thermoelectric properties.
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spelling doaj-art-e615555f0a0646bda911db5912d627582025-01-27T10:35:48ZengIOP PublishingNano Express2632-959X2025-01-016101200110.1088/2632-959X/ada6e7A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric propertiesPooja Rawat0https://orcid.org/0000-0002-4739-564XShubhra Kala1https://orcid.org/0000-0001-6477-7378Department of Physics, Uttaranchal Institute of Technology, Uttaranchal University , Prem Nagar, Dehradun- 248007, Uttarakhand, IndiaDepartment of Physics, H.N.B. Garhwal (A Central) University , Srinagar Garhwal, 246174, Uttarakhand, IndiaCopper sulfides are an interesting group of materials as they are found in various stoichiometries. Covellite (CuS), digenite (Cu _1.8 S), and chalcocite (Cu _2 S) are the three major phases of copper sulfides. Synthesis of copper sulfide nanostructures via diverse techniques such as solvothermal, pyrolytic, and high-temperature precursor injection has been done for various applications, including electrochemical capacitance, lithium storage and transdermal drug delivery. Additionally, they have been found to show promising behaviour as thermoelectric materials. Thermoelectric energy generation is a fascinating method for energy generation. It is a renewable energy source which utilizes waste heat and converts it into electrical energy, hence is of high value since renewable sources of energy are the need of the hour. Thermoelectric materials are broadly classified into three types: organic, inorganic, and hybrid. Bismuth telluride (Bi _2 Te _3 ), lead telluride (PbTe), silicon-germanium (SiGe) and their alloys are some of the most widely used thermoelectric materials. However, most of these materials are toxic, expensive and its challenging to improve their figure of merit (zT). Copper sulfides have emerged as cost-effective, less toxic alternatives to traditional thermoelectric materials, and different approaches such as doping and phase regulation of copper sulfides have been found to further enhance their thermoelectric properties.https://doi.org/10.1088/2632-959X/ada6e7copper sulfidescovellitenanostructuresthermoelectric propertiesfigure of merit
spellingShingle Pooja Rawat
Shubhra Kala
A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric properties
Nano Express
copper sulfides
covellite
nanostructures
thermoelectric properties
figure of merit
title A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric properties
title_full A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric properties
title_fullStr A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric properties
title_full_unstemmed A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric properties
title_short A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric properties
title_sort concise review on the progression of copper sulfide as a potential thermoelectric material synthesis and thermoelectric properties
topic copper sulfides
covellite
nanostructures
thermoelectric properties
figure of merit
url https://doi.org/10.1088/2632-959X/ada6e7
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AT poojarawat concisereviewontheprogressionofcoppersulfideasapotentialthermoelectricmaterialsynthesisandthermoelectricproperties
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