Aqueous Nanofluid as a Two-Phase Coolant for PWR
Density fluctuations in liquid water consist of two topological kinds of instant molecular clusters. The dense ones have helical hydrogen bonds and the nondense ones are tetrahedral clusters with ice-like hydrogen bonds of water molecules. Helical ordering of protons in the dense water clusters can...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | Science and Technology of Nuclear Installations |
| Online Access: | http://dx.doi.org/10.1155/2012/214381 |
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| author | Pavel N. Alekseev Yury M. Semchenkov Alexander L. Shimkevich |
| author_facet | Pavel N. Alekseev Yury M. Semchenkov Alexander L. Shimkevich |
| author_sort | Pavel N. Alekseev |
| collection | DOAJ |
| description | Density fluctuations in liquid water consist of two topological kinds of instant molecular clusters. The dense ones have helical hydrogen bonds and the nondense ones are tetrahedral clusters with ice-like hydrogen bonds of water molecules. Helical ordering of protons in the dense water clusters can participate in coherent vibrations. The ramified interface of such incompatible structural elements induces clustering impurities in any aqueous solution. These additives can enhance a heat transfer of water as a two-phase coolant for PWR due to natural forming of nanoparticles with a thermal conductivity higher than water. The aqueous nanofluid as a new condensed matter has a great potential for cooling applications. It is a mixture of liquid water and dispersed phase of extremely fine quasi-solid particles usually less than 50 nm in size with the high thermal conductivity. An alternative approach is the formation of gaseous (oxygen or hydrogen) nanoparticles in density fluctuations of water. It is possible to obtain stable nanobubbles that can considerably exceed the molecular solubility of oxygen (hydrogen) in water. Such a nanofluid can convert the liquid water in the nonstoichiometric state and change its reduction-oxidation (RedOx) potential similarly to adding oxidants (or antioxidants) for applying 2D water chemistry to aqueous coolant. |
| format | Article |
| id | doaj-art-e5f2c939d1874687af094ba110b900bb |
| institution | Kabale University |
| issn | 1687-6075 1687-6083 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Science and Technology of Nuclear Installations |
| spelling | doaj-art-e5f2c939d1874687af094ba110b900bb2025-02-03T01:20:45ZengWileyScience and Technology of Nuclear Installations1687-60751687-60832012-01-01201210.1155/2012/214381214381Aqueous Nanofluid as a Two-Phase Coolant for PWRPavel N. Alekseev0Yury M. Semchenkov1Alexander L. Shimkevich2NRC “Kurchatov Institute”, 1 Kurchatov Square, Moscow 123182, RussiaNRC “Kurchatov Institute”, 1 Kurchatov Square, Moscow 123182, RussiaNRC “Kurchatov Institute”, 1 Kurchatov Square, Moscow 123182, RussiaDensity fluctuations in liquid water consist of two topological kinds of instant molecular clusters. The dense ones have helical hydrogen bonds and the nondense ones are tetrahedral clusters with ice-like hydrogen bonds of water molecules. Helical ordering of protons in the dense water clusters can participate in coherent vibrations. The ramified interface of such incompatible structural elements induces clustering impurities in any aqueous solution. These additives can enhance a heat transfer of water as a two-phase coolant for PWR due to natural forming of nanoparticles with a thermal conductivity higher than water. The aqueous nanofluid as a new condensed matter has a great potential for cooling applications. It is a mixture of liquid water and dispersed phase of extremely fine quasi-solid particles usually less than 50 nm in size with the high thermal conductivity. An alternative approach is the formation of gaseous (oxygen or hydrogen) nanoparticles in density fluctuations of water. It is possible to obtain stable nanobubbles that can considerably exceed the molecular solubility of oxygen (hydrogen) in water. Such a nanofluid can convert the liquid water in the nonstoichiometric state and change its reduction-oxidation (RedOx) potential similarly to adding oxidants (or antioxidants) for applying 2D water chemistry to aqueous coolant.http://dx.doi.org/10.1155/2012/214381 |
| spellingShingle | Pavel N. Alekseev Yury M. Semchenkov Alexander L. Shimkevich Aqueous Nanofluid as a Two-Phase Coolant for PWR Science and Technology of Nuclear Installations |
| title | Aqueous Nanofluid as a Two-Phase Coolant for PWR |
| title_full | Aqueous Nanofluid as a Two-Phase Coolant for PWR |
| title_fullStr | Aqueous Nanofluid as a Two-Phase Coolant for PWR |
| title_full_unstemmed | Aqueous Nanofluid as a Two-Phase Coolant for PWR |
| title_short | Aqueous Nanofluid as a Two-Phase Coolant for PWR |
| title_sort | aqueous nanofluid as a two phase coolant for pwr |
| url | http://dx.doi.org/10.1155/2012/214381 |
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