Metallocomplex catalysis in oxidation processes. Kinetics and mechanisms.

Metallocomplex catalysis in oxidation processes. Kinetics and mechanisms.

Ways of increasing catalytic activity of complexes of transition metals towards oxidation of alkylarenes with molecular oxygen, described in the literature within last 10-15 years, are reviewed. Attention is focused on the original method of controlling the catalytic activity of complexes of M(acac)...

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Bibliographic Details
Main Authors: L. I. Matienko, L. A. Mosolova, G. E. Zaikov
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2009-12-01
Series:Тонкие химические технологии
Subjects:
homogeneous catalysis, oxidation, alkylarenes, hydroperoxides, molecular oxygen, ni(ii) - fe(ii,iii) acetylacetonates, hmpa, dmf, mst (m=na, li, k), quaternary ammonium salts, macrocyclic polyethers, phoh, low concentration of h2o (~10-3 mol/l).
Online Access:https://www.finechem-mirea.ru/jour/article/view/1031
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