Thermodynamic assessment of the Al-Mo-V ternary system

Thermodynamic assessment of the Al-Mo-V ternary system was performed by means of the CALPHAD (CALculation of PHAse Diagram) approach based on the thermodynamic descriptions of three constitutive binary systems (Al-Mo, Al-V and Mo-V) as well as the experimental phase equilibria data availabl...

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Main Authors: Hu B., Yao B., Wang J., Zhao J.-R., Min F.-F., Du Y.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2017-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
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Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700005H.pdf
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author Hu B.
Yao B.
Wang J.
Zhao J.-R.
Min F.-F.
Du Y.
author_facet Hu B.
Yao B.
Wang J.
Zhao J.-R.
Min F.-F.
Du Y.
author_sort Hu B.
collection DOAJ
description Thermodynamic assessment of the Al-Mo-V ternary system was performed by means of the CALPHAD (CALculation of PHAse Diagram) approach based on the thermodynamic descriptions of three constitutive binary systems (Al-Mo, Al-V and Mo-V) as well as the experimental phase equilibria data available in the literature. The solution phases, i.e. liquid, bcc (Mo, V) and fcc (Al), were described using the substitutional solution models with the Redlich-Kister equation. The binary phases in the Al-Mo and Al-V systems with the solubilities of the third element were modeled using the sublattice models. An optimal set of thermodynamic parameters for the Al-Mo-V system was obtained. Six isothermal sections at 1200, 1000, 750, 715, 675 and 630°C and liquidus projection with isotherm were calculated. The reaction scheme for the entire Al-Mo-V system was also constructed. Comparisons between the calculated and measured phase diagrams indicated that almost all the reliable experimental information was satisfactorily accounted for by the present modeling.
format Article
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institution Kabale University
issn 1450-5339
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language English
publishDate 2017-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-e5de010f23db425cbb1921ca4b1c89042025-02-02T09:17:36ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752017-01-015329510610.2298/JMMB161110005H1450-53391700005HThermodynamic assessment of the Al-Mo-V ternary systemHu B.0Yao B.1Wang J.2Zhao J.-R.3Min F.-F.4Du Y.5Anhui University of Science and Technology, School of Materials Science and Engineering, Huainan, ChinaAnhui University of Science and Technology, School of Materials Science and Engineering, Huainan, ChinaCentral South University, State Key Laboratory of Powder Metallurgy, Changsha, ChinaShandong Academy of Sciences, Advanced Materials Institute, Shandong Key Laboratory for High Strength Lightweight Metallic Materials (HLM), Shandong Engineering Research Center for Lightweight Automobiles Magnesium Alloy, Jinan, ChinaAnhui University of Science and Technology, School of Materials Science and Engineering, Huainan, ChinaCentral South University, State Key Laboratory of Powder Metallurgy, Changsha, ChinaThermodynamic assessment of the Al-Mo-V ternary system was performed by means of the CALPHAD (CALculation of PHAse Diagram) approach based on the thermodynamic descriptions of three constitutive binary systems (Al-Mo, Al-V and Mo-V) as well as the experimental phase equilibria data available in the literature. The solution phases, i.e. liquid, bcc (Mo, V) and fcc (Al), were described using the substitutional solution models with the Redlich-Kister equation. The binary phases in the Al-Mo and Al-V systems with the solubilities of the third element were modeled using the sublattice models. An optimal set of thermodynamic parameters for the Al-Mo-V system was obtained. Six isothermal sections at 1200, 1000, 750, 715, 675 and 630°C and liquidus projection with isotherm were calculated. The reaction scheme for the entire Al-Mo-V system was also constructed. Comparisons between the calculated and measured phase diagrams indicated that almost all the reliable experimental information was satisfactorily accounted for by the present modeling.http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700005H.pdfAl-Mo-V systemCALPHAD approachisothermal sectionliquidus projection
spellingShingle Hu B.
Yao B.
Wang J.
Zhao J.-R.
Min F.-F.
Du Y.
Thermodynamic assessment of the Al-Mo-V ternary system
Journal of Mining and Metallurgy. Section B: Metallurgy
Al-Mo-V system
CALPHAD approach
isothermal section
liquidus projection
title Thermodynamic assessment of the Al-Mo-V ternary system
title_full Thermodynamic assessment of the Al-Mo-V ternary system
title_fullStr Thermodynamic assessment of the Al-Mo-V ternary system
title_full_unstemmed Thermodynamic assessment of the Al-Mo-V ternary system
title_short Thermodynamic assessment of the Al-Mo-V ternary system
title_sort thermodynamic assessment of the al mo v ternary system
topic Al-Mo-V system
CALPHAD approach
isothermal section
liquidus projection
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700005H.pdf
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AT yaob thermodynamicassessmentofthealmovternarysystem
AT wangj thermodynamicassessmentofthealmovternarysystem
AT zhaojr thermodynamicassessmentofthealmovternarysystem
AT minff thermodynamicassessmentofthealmovternarysystem
AT duy thermodynamicassessmentofthealmovternarysystem