Micro-scale corrosion behaviours of the Fe-based amorphous alloy coating in alkaline solutions in three-dimensions

Despite extensive research on the corrosion of the Fe-based amorphous alloy coatings (AACs) has been carried out, yet, regarding the corrosion morphology of the Fe-based AACs in NaOH solution, the current findings only indicate the existence of localized corrosion, without clarifying the occurrence...

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Main Authors: Yiliyaer Hairule, Dandan Liang, Tiantian Chen, Yongming Zhang, Xianshun Wei, Qing Chen, Wen Li, Bo Chen
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425002224
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author Yiliyaer Hairule
Dandan Liang
Tiantian Chen
Yongming Zhang
Xianshun Wei
Qing Chen
Wen Li
Bo Chen
author_facet Yiliyaer Hairule
Dandan Liang
Tiantian Chen
Yongming Zhang
Xianshun Wei
Qing Chen
Wen Li
Bo Chen
author_sort Yiliyaer Hairule
collection DOAJ
description Despite extensive research on the corrosion of the Fe-based amorphous alloy coatings (AACs) has been carried out, yet, regarding the corrosion morphology of the Fe-based AACs in NaOH solution, the current findings only indicate the existence of localized corrosion, without clarifying the occurrence and mechanism of pitting corrosion. This work investigated the corrosion behaviours of the Fe-based AACs in NaOH solutions through three-dimensional (3D) structure and morphology analysis cooperating with electrochemical testing. The work widens the pitting corrosion mechanism of the AACs. The results show that the Fe-based AACs in NaOH solution have an obvious secondary passivation phenomenon, and serious pitting corrosion occurs. As the concentrations of the NaOH solutions increase, the corrosion resistance of AACs gradually decreases. Additionally, the corrosion rates of the AACs are calculated directly based on the (pore) volume changes before and after corrosion treatments through X-ray micro-computed tomography (X-ray micro-CT) measurements, which provides a new method for the corrosion rate calculation.
format Article
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institution Kabale University
issn 2238-7854
language English
publishDate 2025-03-01
publisher Elsevier
record_format Article
series Journal of Materials Research and Technology
spelling doaj-art-e5221e9c199a498faa93cbc83637e9fa2025-02-06T05:11:55ZengElsevierJournal of Materials Research and Technology2238-78542025-03-013529842993Micro-scale corrosion behaviours of the Fe-based amorphous alloy coating in alkaline solutions in three-dimensionsYiliyaer Hairule0Dandan Liang1Tiantian Chen2Yongming Zhang3Xianshun Wei4Qing Chen5Wen Li6Bo Chen7Key Laboratory of Advanced Civil Engineering Materials (Ministry of Education), School of Materials Science and Engineering, Tongji University, Shanghai, 201804, ChinaShanghai Engineering Research Center of Physical Vapor Deposition (PVD) Superhard Coating and Equipment, Shanghai Institute of Technology, Shanghai, 201418, ChinaKey Laboratory of Advanced Civil Engineering Materials (Ministry of Education), School of Materials Science and Engineering, Tongji University, Shanghai, 201804, ChinaKey Laboratory of Advanced Civil Engineering Materials (Ministry of Education), School of Materials Science and Engineering, Tongji University, Shanghai, 201804, ChinaKey Laboratory of Advanced Civil Engineering Materials (Ministry of Education), School of Materials Science and Engineering, Tongji University, Shanghai, 201804, ChinaKey Laboratory of Advanced Civil Engineering Materials (Ministry of Education), School of Materials Science and Engineering, Tongji University, Shanghai, 201804, China; Corresponding author.Key Laboratory of Advanced Civil Engineering Materials (Ministry of Education), School of Materials Science and Engineering, Tongji University, Shanghai, 201804, China; Corresponding author.Key Laboratory of Advanced Civil Engineering Materials (Ministry of Education), School of Materials Science and Engineering, Tongji University, Shanghai, 201804, China; Corresponding author.Despite extensive research on the corrosion of the Fe-based amorphous alloy coatings (AACs) has been carried out, yet, regarding the corrosion morphology of the Fe-based AACs in NaOH solution, the current findings only indicate the existence of localized corrosion, without clarifying the occurrence and mechanism of pitting corrosion. This work investigated the corrosion behaviours of the Fe-based AACs in NaOH solutions through three-dimensional (3D) structure and morphology analysis cooperating with electrochemical testing. The work widens the pitting corrosion mechanism of the AACs. The results show that the Fe-based AACs in NaOH solution have an obvious secondary passivation phenomenon, and serious pitting corrosion occurs. As the concentrations of the NaOH solutions increase, the corrosion resistance of AACs gradually decreases. Additionally, the corrosion rates of the AACs are calculated directly based on the (pore) volume changes before and after corrosion treatments through X-ray micro-computed tomography (X-ray micro-CT) measurements, which provides a new method for the corrosion rate calculation.http://www.sciencedirect.com/science/article/pii/S2238785425002224Fe-based amorphous alloy coatingX-ray micro-computed tomography (X-ray micro-CT)Three-dimensional analysisPitting corrosion
spellingShingle Yiliyaer Hairule
Dandan Liang
Tiantian Chen
Yongming Zhang
Xianshun Wei
Qing Chen
Wen Li
Bo Chen
Micro-scale corrosion behaviours of the Fe-based amorphous alloy coating in alkaline solutions in three-dimensions
Journal of Materials Research and Technology
Fe-based amorphous alloy coating
X-ray micro-computed tomography (X-ray micro-CT)
Three-dimensional analysis
Pitting corrosion
title Micro-scale corrosion behaviours of the Fe-based amorphous alloy coating in alkaline solutions in three-dimensions
title_full Micro-scale corrosion behaviours of the Fe-based amorphous alloy coating in alkaline solutions in three-dimensions
title_fullStr Micro-scale corrosion behaviours of the Fe-based amorphous alloy coating in alkaline solutions in three-dimensions
title_full_unstemmed Micro-scale corrosion behaviours of the Fe-based amorphous alloy coating in alkaline solutions in three-dimensions
title_short Micro-scale corrosion behaviours of the Fe-based amorphous alloy coating in alkaline solutions in three-dimensions
title_sort micro scale corrosion behaviours of the fe based amorphous alloy coating in alkaline solutions in three dimensions
topic Fe-based amorphous alloy coating
X-ray micro-computed tomography (X-ray micro-CT)
Three-dimensional analysis
Pitting corrosion
url http://www.sciencedirect.com/science/article/pii/S2238785425002224
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