Lithium Ferrite as the Cathode of the Electrochemical Power Sources: the Perspectives of Sol-gel Synthesis Method

Synthesis of highly dispersed systems of lithium-ferrite oxide spinel, obtained by the low-temperature sol-gel method, with the subsequent auto combustion and the comparison of these systems’ characteristics with the analogous ones of the conventional ceramic method are performed. It is shown that t...

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Main Authors: O.M. Uhorchuk, V.V. Uhorchuk, M.V. Karpets, L.S. Kaykan, B.Ja. Deputat, A.M. Boychuk, M.I. Hasyuk
Format: Article
Language:English
Published: Sumy State University 2015-06-01
Series:Журнал нано- та електронної фізики
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Online Access:http://jnep.sumdu.edu.ua/download/numbers/2015/2/articles/jnep_2015_V7_02012.pdf
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author O.M. Uhorchuk
V.V. Uhorchuk
M.V. Karpets
L.S. Kaykan
B.Ja. Deputat
A.M. Boychuk
M.I. Hasyuk
author_facet O.M. Uhorchuk
V.V. Uhorchuk
M.V. Karpets
L.S. Kaykan
B.Ja. Deputat
A.M. Boychuk
M.I. Hasyuk
author_sort O.M. Uhorchuk
collection DOAJ
description Synthesis of highly dispersed systems of lithium-ferrite oxide spinel, obtained by the low-temperature sol-gel method, with the subsequent auto combustion and the comparison of these systems’ characteristics with the analogous ones of the conventional ceramic method are performed. It is shown that the systems synthesized by solid-phase and sol-gel methods are the single phase structures with the space group P4332. The sol-gel method of auto combustion made it possible to increase the size of crystallites in more than 4 times and the specific area of the surface in 20 times. Obtained by sol-gel method lithium pentaferrit is suggested to be used as the cathode of lithium power sources.
format Article
id doaj-art-e4c931cdd2d14b8da2f8b4f290a0fa66
institution Kabale University
issn 2077-6772
language English
publishDate 2015-06-01
publisher Sumy State University
record_format Article
series Журнал нано- та електронної фізики
spelling doaj-art-e4c931cdd2d14b8da2f8b4f290a0fa662025-08-20T03:25:11ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722015-06-017202012-102012-7Lithium Ferrite as the Cathode of the Electrochemical Power Sources: the Perspectives of Sol-gel Synthesis MethodO.M. Uhorchuk0V.V. Uhorchuk1M.V. Karpets2L.S. Kaykan3B.Ja. Deputat4A.M. Boychuk5M.I. Hasyuk6The Prycarpathian  National University after Vasyl Stefanyk, 57, Shevchenko Str., 76025 Ivano-Frankivsk, UkraineThe Institute of Metal and Physics after H.V. Kurdyumov NAS of Ukraine, 36, Academician Vernadsky Boulevard, 03680 Kyiv, UkraineThe Institute of materials after I.M. Franchevych  NAS of Ukraine, 3, Academician Krzhyzhanovsky Str., 03680 Kyiv, UkraineThe Institute of Metal and Physics after H.V. Kurdyumov NAS of Ukraine, 36, Academician Vernadsky Boulevard, 03680 Kyiv, UkraineIvano-Frankivsk National Technical University of Oil and Gas, 15, Karpatska Str., 76018 Ivano-Frankivsk, UkraineThe Prycarpathian  National University after Vasyl Stefanyk, 57, Shevchenko Str., 76025 Ivano-Frankivsk, UkraineThe Prycarpathian  National University after Vasyl Stefanyk, 57, Shevchenko Str., 76025 Ivano-Frankivsk, UkraineSynthesis of highly dispersed systems of lithium-ferrite oxide spinel, obtained by the low-temperature sol-gel method, with the subsequent auto combustion and the comparison of these systems’ characteristics with the analogous ones of the conventional ceramic method are performed. It is shown that the systems synthesized by solid-phase and sol-gel methods are the single phase structures with the space group P4332. The sol-gel method of auto combustion made it possible to increase the size of crystallites in more than 4 times and the specific area of the surface in 20 times. Obtained by sol-gel method lithium pentaferrit is suggested to be used as the cathode of lithium power sources.http://jnep.sumdu.edu.ua/download/numbers/2015/2/articles/jnep_2015_V7_02012.pdfNanoparticlesSpinelSol-gel methodMössbauer spectroscopyDiffusion of lithium ion
spellingShingle O.M. Uhorchuk
V.V. Uhorchuk
M.V. Karpets
L.S. Kaykan
B.Ja. Deputat
A.M. Boychuk
M.I. Hasyuk
Lithium Ferrite as the Cathode of the Electrochemical Power Sources: the Perspectives of Sol-gel Synthesis Method
Журнал нано- та електронної фізики
Nanoparticles
Spinel
Sol-gel method
Mössbauer spectroscopy
Diffusion of lithium ion
title Lithium Ferrite as the Cathode of the Electrochemical Power Sources: the Perspectives of Sol-gel Synthesis Method
title_full Lithium Ferrite as the Cathode of the Electrochemical Power Sources: the Perspectives of Sol-gel Synthesis Method
title_fullStr Lithium Ferrite as the Cathode of the Electrochemical Power Sources: the Perspectives of Sol-gel Synthesis Method
title_full_unstemmed Lithium Ferrite as the Cathode of the Electrochemical Power Sources: the Perspectives of Sol-gel Synthesis Method
title_short Lithium Ferrite as the Cathode of the Electrochemical Power Sources: the Perspectives of Sol-gel Synthesis Method
title_sort lithium ferrite as the cathode of the electrochemical power sources the perspectives of sol gel synthesis method
topic Nanoparticles
Spinel
Sol-gel method
Mössbauer spectroscopy
Diffusion of lithium ion
url http://jnep.sumdu.edu.ua/download/numbers/2015/2/articles/jnep_2015_V7_02012.pdf
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