Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide

In this study, bio-based poly(lactic acid) (PLA)/polycaprolactone (PCL) blends and PLA/PCL/silicon carbide (SiC) composites were prepared using a solution blending method. The surface of the SiC whiskers was modified using a silane coupling agent. The effects of the PCL and SiC contents on the flexu...

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Main Authors: Jie Chen, Tian-Yi Zhang, Fan-Long Jin, Soo-Jin Park
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2018/6537621
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author Jie Chen
Tian-Yi Zhang
Fan-Long Jin
Soo-Jin Park
author_facet Jie Chen
Tian-Yi Zhang
Fan-Long Jin
Soo-Jin Park
author_sort Jie Chen
collection DOAJ
description In this study, bio-based poly(lactic acid) (PLA)/polycaprolactone (PCL) blends and PLA/PCL/silicon carbide (SiC) composites were prepared using a solution blending method. The surface of the SiC whiskers was modified using a silane coupling agent. The effects of the PCL and SiC contents on the flexural properties, fracture toughness, morphology of PLA/PCL blends, and PLA/PCL/SiC composites were investigated using several techniques. Both the fracture toughness and flexural strength of PLA increased by the introduction of PCL and were further improved by the formation of SiC whiskers. Fracture surfaces were observed by scanning electron microscopy, which showed that the use of PCL as a reinforcing agent induces plastic deformation in the PLA/PCL blends. The SiC whiskers absorbed external energy because of their good interfacial adhesion with the PLA matrix and through SiC-PLA debonding in the PLA/PCL/SiC composites.
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institution Kabale University
issn 1687-8434
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language English
publishDate 2018-01-01
publisher Wiley
record_format Article
series Advances in Materials Science and Engineering
spelling doaj-art-e44d7b69ccca4100b5ab90c6cf477e002025-02-03T06:00:44ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/65376216537621Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon CarbideJie Chen0Tian-Yi Zhang1Fan-Long Jin2Soo-Jin Park3Department of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City 132022, ChinaKey Laboratory of Ministry of Education for Enhancing Oil and Gas Recovery Ratio, Northeast Petroleum University, Daqing 163318, ChinaDepartment of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City 132022, ChinaDepartment of Chemistry, Inha University, Nam-gu, Incheon 402-751, Republic of KoreaIn this study, bio-based poly(lactic acid) (PLA)/polycaprolactone (PCL) blends and PLA/PCL/silicon carbide (SiC) composites were prepared using a solution blending method. The surface of the SiC whiskers was modified using a silane coupling agent. The effects of the PCL and SiC contents on the flexural properties, fracture toughness, morphology of PLA/PCL blends, and PLA/PCL/SiC composites were investigated using several techniques. Both the fracture toughness and flexural strength of PLA increased by the introduction of PCL and were further improved by the formation of SiC whiskers. Fracture surfaces were observed by scanning electron microscopy, which showed that the use of PCL as a reinforcing agent induces plastic deformation in the PLA/PCL blends. The SiC whiskers absorbed external energy because of their good interfacial adhesion with the PLA matrix and through SiC-PLA debonding in the PLA/PCL/SiC composites.http://dx.doi.org/10.1155/2018/6537621
spellingShingle Jie Chen
Tian-Yi Zhang
Fan-Long Jin
Soo-Jin Park
Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide
Advances in Materials Science and Engineering
title Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide
title_full Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide
title_fullStr Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide
title_full_unstemmed Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide
title_short Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide
title_sort fracture toughness improvement of poly lactic acid reinforced with poly ε caprolactone and surface modified silicon carbide
url http://dx.doi.org/10.1155/2018/6537621
work_keys_str_mv AT jiechen fracturetoughnessimprovementofpolylacticacidreinforcedwithpolyecaprolactoneandsurfacemodifiedsiliconcarbide
AT tianyizhang fracturetoughnessimprovementofpolylacticacidreinforcedwithpolyecaprolactoneandsurfacemodifiedsiliconcarbide
AT fanlongjin fracturetoughnessimprovementofpolylacticacidreinforcedwithpolyecaprolactoneandsurfacemodifiedsiliconcarbide
AT soojinpark fracturetoughnessimprovementofpolylacticacidreinforcedwithpolyecaprolactoneandsurfacemodifiedsiliconcarbide