Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide
In this study, bio-based poly(lactic acid) (PLA)/polycaprolactone (PCL) blends and PLA/PCL/silicon carbide (SiC) composites were prepared using a solution blending method. The surface of the SiC whiskers was modified using a silane coupling agent. The effects of the PCL and SiC contents on the flexu...
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2018-01-01
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Series: | Advances in Materials Science and Engineering |
Online Access: | http://dx.doi.org/10.1155/2018/6537621 |
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author | Jie Chen Tian-Yi Zhang Fan-Long Jin Soo-Jin Park |
author_facet | Jie Chen Tian-Yi Zhang Fan-Long Jin Soo-Jin Park |
author_sort | Jie Chen |
collection | DOAJ |
description | In this study, bio-based poly(lactic acid) (PLA)/polycaprolactone (PCL) blends and PLA/PCL/silicon carbide (SiC) composites were prepared using a solution blending method. The surface of the SiC whiskers was modified using a silane coupling agent. The effects of the PCL and SiC contents on the flexural properties, fracture toughness, morphology of PLA/PCL blends, and PLA/PCL/SiC composites were investigated using several techniques. Both the fracture toughness and flexural strength of PLA increased by the introduction of PCL and were further improved by the formation of SiC whiskers. Fracture surfaces were observed by scanning electron microscopy, which showed that the use of PCL as a reinforcing agent induces plastic deformation in the PLA/PCL blends. The SiC whiskers absorbed external energy because of their good interfacial adhesion with the PLA matrix and through SiC-PLA debonding in the PLA/PCL/SiC composites. |
format | Article |
id | doaj-art-e44d7b69ccca4100b5ab90c6cf477e00 |
institution | Kabale University |
issn | 1687-8434 1687-8442 |
language | English |
publishDate | 2018-01-01 |
publisher | Wiley |
record_format | Article |
series | Advances in Materials Science and Engineering |
spelling | doaj-art-e44d7b69ccca4100b5ab90c6cf477e002025-02-03T06:00:44ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/65376216537621Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon CarbideJie Chen0Tian-Yi Zhang1Fan-Long Jin2Soo-Jin Park3Department of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City 132022, ChinaKey Laboratory of Ministry of Education for Enhancing Oil and Gas Recovery Ratio, Northeast Petroleum University, Daqing 163318, ChinaDepartment of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City 132022, ChinaDepartment of Chemistry, Inha University, Nam-gu, Incheon 402-751, Republic of KoreaIn this study, bio-based poly(lactic acid) (PLA)/polycaprolactone (PCL) blends and PLA/PCL/silicon carbide (SiC) composites were prepared using a solution blending method. The surface of the SiC whiskers was modified using a silane coupling agent. The effects of the PCL and SiC contents on the flexural properties, fracture toughness, morphology of PLA/PCL blends, and PLA/PCL/SiC composites were investigated using several techniques. Both the fracture toughness and flexural strength of PLA increased by the introduction of PCL and were further improved by the formation of SiC whiskers. Fracture surfaces were observed by scanning electron microscopy, which showed that the use of PCL as a reinforcing agent induces plastic deformation in the PLA/PCL blends. The SiC whiskers absorbed external energy because of their good interfacial adhesion with the PLA matrix and through SiC-PLA debonding in the PLA/PCL/SiC composites.http://dx.doi.org/10.1155/2018/6537621 |
spellingShingle | Jie Chen Tian-Yi Zhang Fan-Long Jin Soo-Jin Park Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide Advances in Materials Science and Engineering |
title | Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide |
title_full | Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide |
title_fullStr | Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide |
title_full_unstemmed | Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide |
title_short | Fracture Toughness Improvement of Poly(lactic acid) Reinforced with Poly(ε-caprolactone) and Surface-Modified Silicon Carbide |
title_sort | fracture toughness improvement of poly lactic acid reinforced with poly ε caprolactone and surface modified silicon carbide |
url | http://dx.doi.org/10.1155/2018/6537621 |
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