Synthesis and Characterizations of Biobased Copolymer Poly(ethylene-co-butylene 2,5-Furandicarboxylate)
Homopolymers and copolymers derived from 2,5-furandicarboxylic acid have been extensively studied for their potential in the development of sustainable plastics. This research definitely spotlighted the synthesis of poly(ethylene-co-butylene 2,5-furandicarboxylate) copolymer via the two-step melting...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2021-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2021/9104546 |
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| author | Nam Vu Trung Mai Ngoc Nguyen Anh Nguyen Thi Ngoc Ni Pham Thi Tung Tran Quang Thuy Tran Thi |
| author_facet | Nam Vu Trung Mai Ngoc Nguyen Anh Nguyen Thi Ngoc Ni Pham Thi Tung Tran Quang Thuy Tran Thi |
| author_sort | Nam Vu Trung |
| collection | DOAJ |
| description | Homopolymers and copolymers derived from 2,5-furandicarboxylic acid have been extensively studied for their potential in the development of sustainable plastics. This research definitely spotlighted the synthesis of poly(ethylene-co-butylene 2,5-furandicarboxylate) copolymer via the two-step melting polycondensation with various ethylene glycol/1,4-butanediol molar ratios. The structural characterization of the obtained biobased copolymer was carried out by ATR-FTIR and 1H NMR. The average molecular weight of the obtained copolymer was determined by the intrinsic viscosity measurements. It was found that ethylene glycol was preferentially incorporated into the copolymer structures when the molecular weight of the products was not high enough (>18000). The decomposition of two types of monomer units of the obtained copolymer was proven through the degradation two-step process by TGA measurements. |
| format | Article |
| id | doaj-art-e361c858e3484b499e145b99eed17c5e |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2021-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-e361c858e3484b499e145b99eed17c5e2025-02-03T01:25:47ZengWileyInternational Journal of Polymer Science1687-94221687-94302021-01-01202110.1155/2021/91045469104546Synthesis and Characterizations of Biobased Copolymer Poly(ethylene-co-butylene 2,5-Furandicarboxylate)Nam Vu Trung0Mai Ngoc Nguyen1Anh Nguyen Thi Ngoc2Ni Pham Thi3Tung Tran Quang4Thuy Tran Thi5School of Chemical Engineering, Hanoi University of Science and Technology, Hanoi 100000, VietnamSchool of Chemical Engineering, Hanoi University of Science and Technology, Hanoi 100000, VietnamSchool of Chemical Engineering, Hanoi University of Science and Technology, Hanoi 100000, VietnamSchool of Chemical Engineering, Hanoi University of Science and Technology, Hanoi 100000, VietnamSchool of Chemical Engineering, Hanoi University of Science and Technology, Hanoi 100000, VietnamSchool of Chemical Engineering, Hanoi University of Science and Technology, Hanoi 100000, VietnamHomopolymers and copolymers derived from 2,5-furandicarboxylic acid have been extensively studied for their potential in the development of sustainable plastics. This research definitely spotlighted the synthesis of poly(ethylene-co-butylene 2,5-furandicarboxylate) copolymer via the two-step melting polycondensation with various ethylene glycol/1,4-butanediol molar ratios. The structural characterization of the obtained biobased copolymer was carried out by ATR-FTIR and 1H NMR. The average molecular weight of the obtained copolymer was determined by the intrinsic viscosity measurements. It was found that ethylene glycol was preferentially incorporated into the copolymer structures when the molecular weight of the products was not high enough (>18000). The decomposition of two types of monomer units of the obtained copolymer was proven through the degradation two-step process by TGA measurements.http://dx.doi.org/10.1155/2021/9104546 |
| spellingShingle | Nam Vu Trung Mai Ngoc Nguyen Anh Nguyen Thi Ngoc Ni Pham Thi Tung Tran Quang Thuy Tran Thi Synthesis and Characterizations of Biobased Copolymer Poly(ethylene-co-butylene 2,5-Furandicarboxylate) International Journal of Polymer Science |
| title | Synthesis and Characterizations of Biobased Copolymer Poly(ethylene-co-butylene 2,5-Furandicarboxylate) |
| title_full | Synthesis and Characterizations of Biobased Copolymer Poly(ethylene-co-butylene 2,5-Furandicarboxylate) |
| title_fullStr | Synthesis and Characterizations of Biobased Copolymer Poly(ethylene-co-butylene 2,5-Furandicarboxylate) |
| title_full_unstemmed | Synthesis and Characterizations of Biobased Copolymer Poly(ethylene-co-butylene 2,5-Furandicarboxylate) |
| title_short | Synthesis and Characterizations of Biobased Copolymer Poly(ethylene-co-butylene 2,5-Furandicarboxylate) |
| title_sort | synthesis and characterizations of biobased copolymer poly ethylene co butylene 2 5 furandicarboxylate |
| url | http://dx.doi.org/10.1155/2021/9104546 |
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