Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens

The magnetite (Fe3O4) nanoparticles (0.5 wt%) of size less than 20 nm doped in p-n-alkyl benzoic acids where n varies from heptyl (7) to nonyl (9) are prepared and the presence of Fe+3 is confirmed through UV-Visible spectrophotometer. Textural and phase transition temperature studies are carried o...

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Main Authors: S. Sreehari Sastry, S. Salma Begum, T. Vindhya Kumari, V. R. K. Murthy, Sie Tiong Ha
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/878049
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author S. Sreehari Sastry
S. Salma Begum
T. Vindhya Kumari
V. R. K. Murthy
Sie Tiong Ha
author_facet S. Sreehari Sastry
S. Salma Begum
T. Vindhya Kumari
V. R. K. Murthy
Sie Tiong Ha
author_sort S. Sreehari Sastry
collection DOAJ
description The magnetite (Fe3O4) nanoparticles (0.5 wt%) of size less than 20 nm doped in p-n-alkyl benzoic acids where n varies from heptyl (7) to nonyl (9) are prepared and the presence of Fe+3 is confirmed through UV-Visible spectrophotometer. Textural and phase transition temperature studies are carried out using polarizing optical microscopy on pure and nano doped p-n-alkyl benzoic acids. These results are further confirmed by DSC at a scan rate of 5ºC/min and dielectric studies. Dielectric studies are carried out, in which the variation of dielectric constant, loss and the conductivity are analyzed with respect to temperatures and frequencies. Increment of relaxation times for nano doped heptyl and nonyl benzoic acids are observed which implies that the dielectric nature is strengthened for the nano doped mesogens. The preference of nano doped p-n-alkyl benzoic acids is discussed.
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institution Kabale University
issn 0973-4945
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publishDate 2012-01-01
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series E-Journal of Chemistry
spelling doaj-art-e2dfc950d24c411c95170822c9196e292025-02-03T06:06:36ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01942462247110.1155/2012/878049Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid MesogensS. Sreehari Sastry0S. Salma Begum1T. Vindhya Kumari2V. R. K. Murthy3Sie Tiong Ha4Physics Department, Acharya Nagarjuna University, Nagarjunanagar-522 510, IndiaPhysics Department, Indian Institute of Technology, Chennai-600 036, IndiaPhysics Department, Indian Institute of Technology, Chennai-600 036, IndiaPhysics Department, Indian Institute of Technology, Chennai-600 036, IndiaDepartment of Chemical Science, Universiti Tunku Abdul Rahman, Jalan University, Bandar Barat, Kampar 31900, Perak, MalaysiaThe magnetite (Fe3O4) nanoparticles (0.5 wt%) of size less than 20 nm doped in p-n-alkyl benzoic acids where n varies from heptyl (7) to nonyl (9) are prepared and the presence of Fe+3 is confirmed through UV-Visible spectrophotometer. Textural and phase transition temperature studies are carried out using polarizing optical microscopy on pure and nano doped p-n-alkyl benzoic acids. These results are further confirmed by DSC at a scan rate of 5ºC/min and dielectric studies. Dielectric studies are carried out, in which the variation of dielectric constant, loss and the conductivity are analyzed with respect to temperatures and frequencies. Increment of relaxation times for nano doped heptyl and nonyl benzoic acids are observed which implies that the dielectric nature is strengthened for the nano doped mesogens. The preference of nano doped p-n-alkyl benzoic acids is discussed.http://dx.doi.org/10.1155/2012/878049
spellingShingle S. Sreehari Sastry
S. Salma Begum
T. Vindhya Kumari
V. R. K. Murthy
Sie Tiong Ha
Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens
E-Journal of Chemistry
title Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens
title_full Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens
title_fullStr Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens
title_full_unstemmed Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens
title_short Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens
title_sort effect of magnetite nano particles on p n alkyl benzoic acid mesogens
url http://dx.doi.org/10.1155/2012/878049
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